Publications
Paul Knochel: Publications (1981-2014)
- 1. Knochel, P., Seebach, D. "Nitroallylation par le Nitro-2-pivaloyloxy-3-propene. Un Reactif a2/a2" Nouv. J. Chim. 1981, 5, 75.
- 2. Knochel, P., Seebach, D. "Nitroallylation of Highly Reactive Organolithium Compunds by 2-Nitro-2-pivaloyloxy-1-1-propene (NPP)" Tetrahedron Lett. 1981, 22, 3223.
- 3. Kai Y., Knochel P., Kwiatkowski S., Dunitz J.D., Oth J.F.M., Seebach D.* and Kalinowski H.O.,"Structure, Synthesis and Properties of Some Persubstituted 1,2-Dinitroethanes.In Quest of Nitrocyclopropyl-anion Derivatives" Helv. Chim. Acta 1982, 65, 137-161.
- 4. Knochel P., Seebach D.*, "Synthesis and Reactions of Substituted Nitro-allylating Reagents" Tetrahedron Lett. 1982, 23, 3897-3900.
- 5. Knochel P., Seebach D.*, "Deshydratisierung von Nitroaldolen mit DCC: Herstellung von Nitro Olefinen unter Milden Bedingungen" Synthesis 1982, 1017-1018.
- 6. Seebach D.*, Knochel P., "2'-Nitro-2'-propen-l'-yl 2,2-Dimethylpropanoate (NPP). A Multiple Coupling Reagent" Helv. Chim. Acta, 1984, 67, 261-283.
- 7. Knochel P., Normant J. F., "Addition of Functionalized Allylic Bromides to Terminal Alkynes" Tetrahedron Lett. 1984, 25, 1475-1473.
- 8. Knochel P., Normant J. F., "The Reactivity of 3-Bromo-2-trimethylsilyl-1-propene Towards Electrophiles. A Short Synthesis of 2-Substituted-4-trimethylsilylfurans" Tetrahedron Lett. 1984, 25, 4383-4386.
- 9. Seebach D.*, Calderari G., Knochel P., "Trifluoroacetoxy-phenylselenation of Nitroolefins. Regioselective Preparation of Nitroallylic Alcohol Derivatives and Their Use as Multiple Coupling Ragents" Tetrahedron 1985, 41, 4861-4872.
- 10. Knochel P.*, Normant J. F., "3-Bromo-2-(tert-butylsulfonyl)- 1-propene. A Multi-coupling Reagent, Part 1" Tetrahedron Lett. 1985, 26, 425-428.
- 11. Auvray P., Knochel P.*, Normant J. F., "3-Bromo-2-(tert-butylsulfonyl)-1-propene. A Multi-coupling Reagent, Part 2" Tetrahedron Lett. 1985, 26, 2329-2332.
- 12. Auvray P., Knochel P.*, Normant J. F., "5-Endo-trigonal Ring Closures of Unsaturated Sulfones" Tetrahedron Lett. 1985, 26, 4455-4458.
- 13. Knochel P.*, Normant J. F., "Synthesis and Reactivity of gem-Dimetallic Organic Compounds. Part 1" Tetrahedron Lett. 1986, 27, 1039-1042.
- 14. Knochel P.*, Normant J. F., "Mixed gem-Dimetallic Organic Compounds. A New Class of Multi-coupling Reagents. Part 2" Tetrahedron Lett. 1986, 27, 1043-1046.
- 15. P. Knochel*, J. F. Normant, "Copper and Zinc Mixed gem-Dimetallic Organic Compounds" Tetrahedron Lett. 1986, 27, 4427-4430.
- 16. Knochel P.*, Normant J. F., "Reactivity of 1-Lithia-1-zincaalkenes. Part 4" Tetrahedron Lett. 1986, 27, 4431-4434.
- 17. Auvray P., Knochel P.*, Normant J. F., "An Easy Synthesis of the 2-Phenylsulfonyl-substituted Allylic Bromides and Acetates and Their Reactivity Toward Nucleophiles" Tetrahedron Lett. 1986, 27, 5095-5098.
- 18. Auvray P., Knochel P.*, Normant J. F., "An Easy Synthesis of the 2-Phenylsulfonyl-substituted Allylic Bromides and Acetates and Their Reactivity Toward Nucleophiles" Tetrahedron Lett. 1986, 27, 5095-5098.
- 19. Knochel P.*, Normant J. F., "Diastereoselective Addition of Functionalized Allylic Zinc Bromides to Alkenyl Organometallics. Part 5" Tetrahedron Lett. 1986, 27, 5727-5730.
- 20. Knochel P.*, Normant J. F., "Synthese de Dienes-1,4- Fonctionnalisés par Addition de Zinciques Allyliques Fonctionnalisés sur des Alcynes vrais et leur Cyclisation en Heterocycles ou Carbocycles" J. Organomet. Chem. 1986, 309, 1-23.
- 21. Knochel P.*, Yeh M.C.P., Berk S.C., Talbert J., "Synthesis and Reactivity Toward Acyl chlorides and Enones of the New Highly Functionalized Copper Reagents RCu(CN)ZnI" J. Org. Chem. 1988, 53, 2390-2392.
- 22. Yeh M.C.P. and Knochel P.* "2-Cyanoethylzinc iodide: A New Reagent with Reactivity Umpolung" Tetrahedron Lett. 1988, 29, 2395-2396.
- 23. Auvray P.,Knochel P.*, Normant J.F. "3-Bromo-2-t-Butysulfonyl-1-propene: A Versatile Multi-coupling Reagent Part I." Tetrahedron 1988, 44, 4495-4508.
- 24. Auvray P., Knochel P.*, Normant J.F. "3-Bromo-2-1-Butysulfonyl-1-propene: A Versatile Multi-coupling Reagent. Part II." Tetrahedron 1988, 44, 4509-4519.
- 25. Yeh M.C.P., Knochel, P., Santa, L.E. "The Reaction of the Highly Functionalized Copper Reagents RCu(CN)ZnI.BF3 with Aldehydes" Tetrahedron Lett. 1988, 29, 3887-3890.
- 26. Auvray P., Knochel P.*, Normant J. F., "Preparation and Nucleophilic Substitution of(E)-1-Bromo-2-Phenylsulfonyl-2-Alkenes and 3-Acetoxy-2-Phenylsulfonyl-1-Alkenes" Tetrahedron 1988, 44, 6095-6106.
- 27. Chen H.G.; Knochel P.*, "A New Mild Oxidation of Amines to Aldehydes and Ketones. Part II" Tetrahedron Lett. 1988, 29, 6701-6702.
- 28. Yeh M.C.P.; Knochel P.*; Butler W.M.; Berk S.C. "1,4-Additions of the Highly Functionalized Copper Reagents RCu(CN)ZnI . 2 BF3 to Trisubstituted Enones. A New BF3 Promoted Cyclization Reaction" Tetrahedron Lett. 1988, 29, 6693-6696.
- 29. Knochel P.*; Xiao C.; Yeh M. C. P. "A Mild Oxidation of 1,1- Diorganometallics to Ketones and Aldehydes. A New Stereoselective Approach to Aldol Products. Part I" Tetrahedron Lett. 1988, 29, 6697-6700.
- 30. Berk S. C.; Knochel P.*; Yeh M.C.P. "General Approach to Highly Functionalized Benzylic Organometallics of Zinc and Copper" J. Org. Chem. 1988, 53, 5789-5791.
- 31. Knochel, P.*; Jeong, N.; Rozema, M.J.; Yeh, M.C.P. "Zinc and Copper Carbenoids as Efficient and Selective a1/d1 Multicoupling Reagents. 1." J. Am. Chem. Soc. 1989, 111, 6474-6476.
- 32. Chen, H.G.; Hoechstetter, C.; Knochel, P.* "Mixed Copper, Zinc 2-Amino Benzylic Organometallics as Efficient Reagents for the Synthesis of Heterocycles" Tetrahedron Lett. 1989, 30, 4795-4798.
- 33. Yeh M.C.P.; Knochel, P.* "The Reactivity of the Highly Functionalized Copper, Zinc Reagents RCu(CN)ZnI Toward 1-Haloalkynes and Acetylenic Esters" Tetrahedron Lett. 1989, 30, 4799-4802.
- 34. Knochel, P.*; Yeh, M.C.P.; Xiao, C. "Preparation and Reactivity of Mixed Benzylic 1,1-Dimetalloalkanes" Organometallics 1989, 8, 2831-2835.
- 35. Majid, T.N.; Yeh, M.C.P.; Knochel, P.* "Synthesis and Reactivity of Open-Chain and Cyclic 2-Cyano Zinc and Copper Organometallics" Tetrahedron Lett. 1989, 30, 5069-5072.
- 36. Knochel, P.*; Chou, T.-S.; Chen, H.-G.; Yeh, M.C.P.; Rozema, M.J. "Nucleophilic Reactivity of Zinc and Copper Carbenoids. Part II" J. Org. Chem. 1989, 54, 5202-5204.
- 37. Retherford, C.; Yeh, M,C.P.; Schipor, I.; Chen, H.-G.; Knochel, P.* "The Addition of the Highly Functionalized Zinc, Copper Reagents RCu(CN)ZnI to Nitro Olefins" J. Org.Chem. 1989, 54, 5200-5202.
- 38. Berk, S.C.; Yeh, M.C.P.; Jeong, N.; Knochel, P.* "Preparation and Reactions of Functionalized Benzylic Organometallics of Zinc and Copper" Organometallics 1990, 9, 3053-3064.
- 39. Chen, H.G.; Gage, J.L.; Barrett, S.D., Knochel, P.* "SN2' Substitutions of 1,3-Dichloropropenes with the Functionalized Copper-Zinc Reagents RCu(CN)ZnX" Tetrahedron Lett. 1990, 31, 1829-1832.
- 40. Retherford, C.; Chou, T.-S.; Schelkun, R.M.; Knochel, P.* "Preparation and Reactivity of Zinc and Copper Phosphonates" Tetrahedron Lett. 1990, 31, 1833-1836.
- 41. Tucker, C.E.; Achyutha Rao, S.; Knochel, P.* "The Olefination of Functionalized Alkylidene Malonates by 1,1-Dimetalloalkanes: A New Chemo- and Stereoselective Preparation of Functionalized Olefins" J. Org. Chem. 1990, 55, 5446-5448.
- 42. Knochel, P.*, Achyutha Rao, S. "A Direct Conversion of Vinylic Organocopper Compounds to Allylic Zinc and Copper Organometallics" J. Am. Chem. Soc. 1990, 112, 6146-6148.
- 43. Chou, T.-S., Knochel, P.* "A General Preparation of Highly Functionalized Zinc and Copper Organometallics at the Alpha Position to an Oxygen" J. Org. Chem. 1990, 55, 4791-4793.
- 44. Knochel, P.* "A New Approach to Boron-Stabilized Organometallics" J. Am. Chem. Soc. 1990, 112, 7431-7433.
- 45. Majid, T.N.; Knochel, P.* "A New Preparation of Highly Functionalized Aromatic and Heteroaromatic Zinc and Copper Organometallics" Tetrahedron Lett. 1990, 31, 4413-4416.
- 46. AchyuthaRao, S.; Tucker, C. E.; Knochel, P.* "Preparation of Functionalized Zinc and Copper Organometallics Containing Sulfur Functionalities at the Alpha or Gamma Position" Tetrahedron Lett. 1990, 31, 7575-7578.
- 47. Auvray, P.; Knochel, P.; Vaissermann, J.; Normant*, J.F., "Diastereoselective Reaction of (E)-1-Bromo-2-phenylsulfonylalk-2-enes with Aldehydes in the Presence of Zinc or Chromium (II) Salts" Bull Soc. Chim. Fr. 1990, 813-823.
- 48. Yeh, M. C. P.; Chen, H. G.; Knochel, P. * "1,2-Addition of a -Unsaturatedb,aFunctionalized Zinc and Copper Organometallic (RCu(CN)ZnI) to an Aldehyde: (1H-Isoindole-1,3(2H)-dione,2-(4-hydroxy-6-phenyl-5-hexenyl),(E)-)" Org. Synth. 1991, 70, 195-203.
- 49. Retherford, C.; Knochel, P.* "Highly Stereoselective Preparation of Nitro Olefins and Nitro-Dienes by the Addition-Elimination of Copper-Zinc-Organometallics to β-Alkylthio and β-Phenylsulfonyl Nitro Olefins" Tetrahedron Lett. 1991, 32, 441-444.
- 50. AchyuthaRao, S.; Knochel, P.* "Stereospecific Preparation of Polyfunctional Olefins by the Carbometallation of Alkynes with Polyfunctional Zinc-Copper Organometallics. Stereospecific Preparation of Five-Membered Carbocycles by Intramolecular Carbocupration" J. Am. Chem. Soc. 1991, 113, 5735-5741.
- 51. Rozema, M.J.; Knochel, P.* "Selective Multiple Methylene Insertion Reactions Mediated by Iodomethylzinc Iodide: Mechanistic Considerations and Synthetic Applications" Tetrahedron Lett. 1991, 32, 1855-1858.
- 52. Janakiram Rao, C.; Knochel, P.*, "A Direct Preparation of Vinylogous Acyl Anion Equivalents" J. Org. Chem. 1991, 56, 4593-4596.
- 53. AchyuthaRao, S.; Knochel, P.*, "1, n-Heterometallic Reagents of Zinc and Copper: A New Class of Multi-coupling Reagents" J. Org. Chem. 1991, 56, 4591-4593.
- 54. Tucker, C.E.; Knochel, P.* "A Highly Stereoselective Olefination of Aldehydes Mediated by New Zinc and Zirconium 1,1-Bimetallic Reagents" J. Am. Chem. Soc. 1991, 113, 9888-9890.
- 55. Knoess, H.P.; Furlong, M.T.; Rozema, M.J.; Knochel, P.* "Preparation and Reactions of Zinc and Copper Organometallics Bearing Acidic Hydrogens" J. Org. Chem. 1991, 56, 5974-5978.
- 56. AchyuthaRao, S.; Chou, T.-S.; Schipor, I.; Knochel, P.*, "Preparation of Functionalized Zinc and Copper Organometallics Containing Sulfur Functionalities at the Alpha or Gamma Position" Symposium in print, Tetrahedron 1992, 48, 2025-2043.
- 57. Rozema, M.J.; AchyuthaRao, S.; Knochel, P.* "Preparation of Functionalized Dialkylzinc Reagents via an Iodine-Zinc Exchange Reaction. Highly Enantioselective Synthesis of Functionalized Secondary Alcohols" J. Org. Chem. 1992, 57, 1956-1958.
- 58. Tucker, C.E.; Davidson, J.; Knochel, P.* "Mild and Stereoselective Hydroborations of Functionalized Alkynes and Alkenes Using Pinacolborane" J. Org. Chem. 1992, 57, 3482-3485.
- 59. Tucker, C.E.; Majid, T.N.; Knochel, P.* "Preparation of Highly Functionalized Magnesium, Zinc and Copper Aryl and Alkenyl Organometallics via the Corresponding Organolithiums" J. Amer.Chem.Soc. 1992, 114, 3983-3985.
- 60. Belyk, K.; Rozema, M.J.; Knochel, P.* "Preparation of Polyfunctional Allenic Alcohols by the Regioselective Addition of Functionalized Propargylic Chromium (III) Organometallics to Carbonyl Compounds" J.Org.Chem. 1992, 57, 4070-4074.
- 61. Rozema, M.J.; Rajagopal, D.; Tucker, C.E.; Knochel, P.* "Preparation of Polyfunctional Diorganomercurials and their transmetallation to Diorganozincs. Application to the Preparation of Optically Active Secondary Alcohols" J. Organomet. Chem. 1992, 438, 11.
- 62. Jubert, C.; Knochel, P.* "Preparation of New Classes of Aliphatic, Allylic and Benzylic Zinc and Copper Reagents by the Insertion of Zinc Dust into Organic Halides, Phosphates and Sulfonates" J.Org.Chem. 1992, 57, 5425-5431.
- 63. Jubert, C.; Knochel, P*. "Preparation of Polyfunctional Nitro Olefins and Nitroalkanes Using the Copper-Zinc Reagents RCu(CN)ZnI" J.Org.Chem. 1992, 57, 5431-5438.
- 64. S. AchyuthaRao, P. Knochel*, "New Preparation of Butyrolactones Mediated by Iodomethylzinc Iodide" J. Am. Chem. Soc. 1992, 114, 7579-7581.
- 65. Jubert, C.; Nowotny, S.; Kornemann, D.; Antes, I.; Tucker, C. E.; Knochel, P.* "Stereodivergent Additions of Allylic Chromium (III) Reagents to Aldehydes" J. Org. Chem. 1992, 57, 6384-6386.
- 66. Venegas, P.; Cahiez, G.*; Tucker, C. E.; Majid, T. N.; Knochel, P.* "Additions of Polyfunctional and Pure (E or Z) Alkenylcoppers and Arylcopper to Alkylidenemalonates" J. Chem. Soc.; Chem. Commun. 1992, 1406-1408.
- 67. Waas, J.R.; Sidduri, A.; Knochel, P.* "Preparation and Reactions of 1,1- Zinc, Boron and, 1,1- Copper, Boron Alkenyl Bimetallics: A New Class of d1- Reagents" Tetrahedron Lett. 1992, 33, 3717-3720.
- 68. Sidduri, A.; Budrys, N.; Laine, R. M.*; Knochel, P.* "Preparation of Highly Funtionalized 3,4-Disubstituted Cyclobutene 1,2-Diones Using Functionalized Zinc-Copper Organometallics" Tetrahedron Lett. 1992, 33, 7515-7518.
- 69. Stemmler, T.; Penner-Hahn, J. E.*; Knochel, P.* "Structural Characterization of Organocopper Reagents by EXAFS Spectroscopy" J. Am. Chem. Soc. 1993, 115, 348-350.
- 70. JanikaramRao, C.; Knochel, P.*,"Preparation and Reactivity of Functionalized Alkenyl-Zinc, -Copper, and Chromium Organometallics" Tetrahedron 1993, 49, 29-48.
- 71. Knochel, P.*; Chou, T.-S.; Jubert, C.; Rajagopal, D., "Preparation of Highly Functionalized Organometallics at The Alpha Position of Oxygene or Nitrogen" J. Org.Chem. 1993, 58, 588-599.
- 72. S. AchyuthaRao; Rozema, M.J.; Knochel, P.*, "Selective Mono- and Poly- Methylene Homologations of Copper Reagents Using (Iodomethyl) zinc iodide" J. Org. Chem. 1993, 58, 2694-2713.
- 73. Rozema, M.J.; Eisenberg, C.; Lütjens, H.; Ostwald, R.; Belyk, K.; Knochel, P.* " Enantioselective Preparation of Polyfunctional Secondary Allylic Alcohols Using Functionalized Dialkylzincs Prepared by a Copper(I) Catalyzed Iodine-Zinc Exchange Reaction" Tetrahedron Lett. 1993, 34, 3115-3118.
- 74. Tucker, C.E.; Knochel, P.* "Preparation of Functionalized Z-Olefins using 1,1-Dimetalloalkanes" Synthesis 1993, 530-536.
- 75. Brieden, W., Ostwald, R., Knochel, P.* "Enantioselective Catalytic Addition of Functionalized Dialkylzinc compounds to β-Stannylated Aldehydes. A Simple Method of preparing nonracemic β- and γ-functionalized secondary alcohols" Angew.Chem. 1993, 105, 629-631.
- 76. Knochel, P.*; Brieden, W.; Eisenberg, C., Rozema, M.J. "A New Catalytic Approach of Polyfunctional Aldol Products Mediated by Zinc Organometallics" Tetrahedron Lett. 1993, 34, 5881-5884.
- 77. Stadtmüller, H.; Lentz, R.; Dörner, W., Stüdemann, T., Tucker C. E., Knochel, P.* "Palladium-Catalyzed Iodine-Zinc Exchange Reactions. A New Palladium-Mediated Intramolecular Carbozincation of Alkenes" J. Am. Chem. Soc. 1993, 115, 7027-7028.
- 78. Klement, I.; Lennick, K., Tucker, C.E., Knochel, P.*,"Preparation of Polyfunctional Nitriles by the Cyanation of Functionalized Organozinc Halides with p-Toluenesulfonyl Cyanide" Tetrahedron Lett. 1993, 34, 4623-4626.
- 79. Langer, F., Waas, J.R.; Knochel, P.* "Preparation and Reactions of New Dialkylzincs Obtained by a Boron-Zinc Transmetalation" Tetrahedron Lett. 1993, 34, 5261-5264.
- 80. Tucker, C.E.; Knochel, P.* "Cross-Coupling Between Functionalized Alkylcopper Reagents and Functionalized Alkyl Halides" J. Org. Chem. 1993, 58, 4781-4782.
- 81. Semmelhack, M. F.*; Singleton, T.; Knochel, P. "A New Approach to Indole Alkaloids Via Indole Chromium Complexes" Tetrahedron Lett. 1993, 34, 5051-5054.
- 82. Stadtmüller, H.; Tucker, C.E.; Vaupel, A.; Knochel, P.* "Stereoselective Synthesis of Polyfunctionlized Di- and Trisubstituted Cyclopentane Derivatives using a New Palladium Catalyzed Cyclization." Tetrahedron Lett. 1993, 34, 7911-7914.
- 83. Tucker, C. E., Greve, B., Klein, W., Knochel, P.* "Preparation of Polyfunctional Olefins and Allenes Using 1,1-Bimetallics of Zinc and Zirconium." Organometallics 1994, 13, 94-101.
- 84. Fürstner, A.*, Singer, R., Knochel, P.* "A convenient Preparation of Functionalized Arylzinc Compounds by the Reaction of Zinc/Silver-Graphite with Aryl Iodides." Tetrahedron Lett. 1994, 35, 1047-1050.
- 85. Rajagopal, D.; Eckhardt, M; Furlong, M. Knoess, H. P., Berger, S., Knochel, P.* "Preparation and Reactivity of Chiral Related Configurationally Stable Zinc Organometallics" Tetrahedron 1994, 50, 2415-2432.
- 86. Klement, I., Chau, K., Cahiez, G.*, Knochel, P.* "Preparation of Alkylzinc Bromides Using a New Mn/Cu catalyzed Bromine-Zinc Exchange Reaction" Tetrahedron Lett. 1994, 35, 1177-1180.
- 87. Ostwald, R.; Chavant, P.-Y., Stadtmüller, H.; Knochel, P.* "Catalytic Asymmetric Addition of Polyfunctional Dialkylzincs to β-Stannylated and β-Silylated Unsaturated Aldehydes" J. Org. Chem. 1994, 59, 4143-4153.
- 88. Langer, F.; Devasagayaraj, A.; Chavant, P.-Y.; Knochel, P.* "Preparation of New Polyfunctional Diorganozincs Using a Boron-Zinc Exchange Reaction" Synlett 1994, 410-412.
- 89. Lütjens, H.; Knochel, P.* "Enantioselective Preparation of a C3-Symmetrical Triol" Tetrahedron: Asymmetry, 1994, 5, 1161-1162.
- 90. Eisenberg, C.; Knochel, P.* "Catalytic Asymmetric Preparation of Polyfunctional Protected 1,2-Diols and Epoxides" J. Org. Chem. 1994, 59, 3760-3761.
- 91. Nowotny, S.; Vettel, S.; Knochel, P.* "Dramatic Titanium Alkoxide Effect in the Catalytic Enantioselective Addition of Dialklyzincs to Aldehydes" Tetrahedron Lett. 1994, 35, 4539-4549.
- 92. Vettel, S.; Knochel, P.* "Enantioselective Preparations of C2-Symmetrical 1,4-Diols" Tetrahedron Lett. 1994, 35, 5849-5852.
- 93. Vaupel, A.; Knochel, P.* "Stereoselective Synthesis of Substituted Tetrahydrofurans and Butyrolactones by a New Nickel Catalyzed Carbozincation" Tetrahedron Lett. 1994, 35, 8349-8352.
- 94. Marquais, S.; Cahiez, G.*; Knochel, P.* "Stereospecific Synthesis of Polyfunctional Alkenes by the Cross-Coupling of Functionalized Zinc-Copper Reagents with Alkenyl Iodides" Synlett 1994, 849-850.
- 95. Schwink, L.; Knochel, P.* "Catalytic Asymmetric Reductive Addition of Olefins to Aldehydes Mediated by Boron and Zinc Organometallics" Tetrahedron Lett. 1994, 35, 9007-9010.
- 96. Stadtmüller, H.; Greve, B.; Lennick, K.; Chair, A.; Knochel, P.* "Preparation of Secondary Alkyl and Benzylic Zinc Bromides Using Activated Zinc Metal Deposited on Titanium Oxide." Synthesis 1995, 69-72.
- 97. Vaupel, A.; Knochel, P.* "A Short Formal Synthesis of (-)-Methylenolactocin via a Nickel Catalyzed Intramolecular Carbozincation" Tetrahedron Lett. 1995, 36, 231-232.
- 98. Berninger, J.; Koert, U.*, Eisenberg-Höhl, C.; Knochel, P.* "Funktionalisierte Diorganozinkverbindungen: Schlüsselreagenzien zur Synthese von Enantiomerenreinen 2,5-Disubstituierten Cis- und Trans-Tetrahydrofuranen" Chem. Ber. 1995, 128, 1021-1028.
- 99. Nowotny, S.; Tucker, C. E.; Jubert, C.; Knochel, P.* "Chromium (II) Mediated Stereodivergent Additions of Allylic Phosphates and Halides to Aldehydes" J. Org. Chem. 1995, 60, 2762-2772.
- 100. Vettel, S.; Vaupel, A.; Knochel, P.* "A New Preparation of Diorganozincs from Olefins via a Nickel Catalyzed Hydrozincation" Tetrahedron Lett. 1995, 36, 1023-1026.
- 101. Devasagayaraj, A.; Schwink, L.; Knochel, P.* "Preparation and Reactions of Diorganozincs from Dienic Silyl Enol Ethers" J. Org. Chem. 1995, 60, 3311-3317.
- 102. Stadtmüller, H.; Knochel, P.* "Asymmetric Synthesis of (+)-Methyl Jasmonate and (-)-Methyl Curcurbate Using a New Nickel Catalyzed Carbozincation" Synlett 1995, 463-464.
- 103. Langer, F.; Knochel, P.* "New Efficient Preparation of Polyfunctional phosphines Using Zinc Organometallics" Tetrahedron Lett. 1995, 36, 4591-4594.
- 104. Stadtmüller, H.; Knochel, P.* "A New Synthesis of Functionalized Chromium Carbene Complexes Using Zinc Organometallics" Organometallics 1995, 14, 3163-3166.
- 105. Klement, I.; Lütjens, H.; Knochel, P.* "Oxidation of Zinc Organometallics Prepared by Hydrozincation or Carbozincation Using Oxygen" Tetrahedron Lett. 1995, 36, 3161-3164.
- 106. Dötz, K. H.*; Christoffers, C.; Knochel, P.* "Reaktionen von Komplexliganden LXIII. Diethylzinc-induzierte Dimerisierung von Alkinylcarbenliganden: Regioselektive Synthese eines Cyclopentenyliden-Komplexes" J. Organomet. Chem. 1995, 489, C84-C86.
- 107. Klement, I. and Knochel, P.* "Selective Oxidation of Zinc Organometallics to Hydroperoxides Using Oxygen in Perfluorohexanes" Synlett 1995, 1113-1114.
- 108. Schwink, L.; Vettel, S., Knochel, P.* "A New Approach to Chiral Cyclopentadienyl Metal Complexes" Organometallics 1995, 14, 5000-5001.
- 109. Devasagayaraj, A.; Stüdemann, T.; Knochel, P. "A New Nickel Catalyzed Cross-Coupling Reaction between Csp3-Csp3 Centers; Mechanistic and Synthetic Studies" Angew. Chem. 1995, 107, 2952-2954; Angew. Chem. Int. Ed. Engl. 1995, 34, 2723-2725.
- 110. Lütjens, H.; Nowotny, S.; Knochel, P.* "New Enantioselective Syntheses of Acetylenic Alcohols Using Functionalized Diorganozincs" Tetrahedron: Asymmetry 1995, 6, 2675-2678.
- 111. Stemmler, T. L.; Barnhart, T. M.; Penner-Hahn, J. E.*, Tucker, C. E.; Knochel, P.*, Böhme, M.; Frenking, G.* "Structural Characterization of Organocuprate reagents. EXAFS Spectroscopy and Ab Initio Calculation" J. Am. Chem. Soc. 1995, 117, 12489-12497.
- 112. Devasagayaraj, A.; Knochel, P.* "Preparation of Polyfunctional Ketones by a Cobalt (II) Mediated Carbonylation of Organozinc Reagents" Tetrahedron Lett. 1995, 36, 8411-8414.
- 113. Klement, I.; Rottländer, M.; Tucker, C. E.; Majid, T. N.; Knochel, P.*, Venegas, P.; Cahiez, G.* "Preparation of Polyfunctional Aryl and Alkenyl Zinc Halides from Functionalized Unsaturated Organolithiums and their Reactivity in Cross-Coupling and Conjugated Addition Reactions" Tetrahedron 1996, 52, 7201-7220.
- 114. Eick, H.; Knochel, P.* "The Preparation of 1,3-Dizinc Organometallics via a Boron-Zinc Exchange" Angew. Chem. 1996, 108, 229-231; Angew. Chem. Int. Ed. Engl. 1996, 35, 218-220.
- 115. Schwink, L.; Knochel, P.* "A New Practical Asymmetric Synthesis of C2-Symmetrical 1,1'-Ferrocene Diols via CBS-Reduction" Tetrahedron Lett. 1996, 37, 25-28.
- 116. Longeau, A.; Langer, F.; Knochel, P.* "Preparation and Reactions of Functionalized Chlorodiorganophine-Borane Complexes Using Organozinc Reagents" Tetrahedron Lett. 1996, 37, 2209-2212.
- 117. Stadtmüller, H.; Vaupel, A.; Tucker, C. E.; Stüdemann, T.; Knochel, P.* "Stereoselective Preparation of Polyfunctional Cyclopentane Derivatives via a Radical Nickel or Palladium Catalyzed Carbozincation" Chem. Eur. J. 1996, 2, 1204-1220.
- 118. Reddy, K.; Knochel, P.* "New Cobalt and Iron Catalyzed Reactions of Organozincs" Angew. Chem. 1996, 108, 1812-1813; Angew. Chem. Int. Ed. Engl. 1996, 35, 1700-1701.
- 119. Rottländer, M.; Palmer, N.; Knochel, P.* "Selective Pd (0)-Catalyzed Arylations Using New Electrophilic or Nucleophilic Multi-Coupling Reagents" Synlett, 1996, 573-575.
- 120. Vaupel, A.; Knochel, P.* "Stereoselective Synthesis of Heterocyclic Zinc Reagents via A Nickel Catalyzed Radical Cyclization" J. Org. Chem. 1996, 61, 5743-5753.
- 121. Vettel, S.; Vaupel, A.; Knochel, P.* "Nickel-Catalyzed Preparations of Functionalized Organozincs" J. Org. Chem. 1996, 61, 7473-7481.
- 122. Klement, I.; Knochel, P.* "Direct Oxidation of Organoboranes with Oxygen in Perfluoroalkenes" Synlett 1996 1004-1006.
- 123. Reddy, Ch. K.; Devasagayaraj, A.; Knochel, P.* "Uncatalyzed Conjugate Additions of Diorganozincs in NMP" Tetrahedron Lett. 1996, 37, 4495-4498.
- 124. Vettel, S.; Lutz, C.; Knochel, P.* "Enantioselective Synthesis of Protected α-Hydroxy Aldehydes and Related 1,2-Amino Alcohols. Applications to the Synthesis of (-)-Exo- and (-)-Endo-Brevicomin", Synlett 1996, 731-733.
- 125. Langer, F.; Schwink, L.; Devasagayaraj, A.; Chavant, P.-Y., Knochel, P.* "Preparation of Functionalized Dialkylzincs via a Boron-Zinc Exchange. Reactivity and Catalytic Asymmetric Addition to Aldehydes" J. Org. Chem. 1996, 61, 8229-8243.
- 126. Riguet, E.; Klement, I.; Reddy, K. Ch.; Cahiez, G.*; Knochel, P.* "New Mixed Metal (Mn/Cu) Catalyzed Stereoselective Cyclizations" Tetrahedron Lett. 1996, 37, 5865-5868.
- 127. Longeau, A.; Knochel, P.* "Lithiated bis Diethylaminophosphine Borane Complex as Useful Nucleophilic Phosphorus reagents" Tetrahedron Lett. 1996, 37, 6099-6102.
- 128. Stevenson, T.; Prasad, B. A. S.; Citineni, J. R.; Knochel, P. "Preparation of Zinc Organometallics Derived from Nucleosides and Nucleic Acid Bases and Pd(0) Catalyzed Coupling with Aryl Iodides" Tetrahedron Lett. 1996, 37, 8375-8378.
- 129. Püntener, K.; Schwink, L.; Knochel, P.* "New Efficient Catalysts for Enantioselective Transfer Hydrogenations" Tetrahedron Lett. 1996, 37, 8165-8168.
- 130. Stüdemann, T.; Knochel, P.* "New Nickel Catalyzed Carbozincation of Alkynes. A Short Synthesis of (Z)-Tamoxifen" Angew. Chem. 1997, 109, 132-134; Angew. Chem. Int. Ed. Engl. 1997, 36, 93-95.
- 131. Langer, F.; Püntener, K.; Stürmer, R.; Knochel, P.* "Preparation of Polyfunctional Phosphines using Zinc Organometallics" Tetrahedron: Asymmetry, 1997, 8, 715-738.
- 132. Micouin, L.; Oestreich, M.; Knochel, P.* "Stereoselective Preparation and Reactions of Secondary Cyclic Zinc Organometallics" Angew. Chem. 1997, 109, 274-276; Int. Ed. Engl. 1997, 36, 245-246.
- 133. Stüdemann, T.; Gupta, V.; Engman, L.; Knochel, P.* "Nickel Catalyzed Tellurium-Zinc Exchange Reactions. A New Preparation of Diarylzincs" Tetrahedron Lett. 1997, 38, 1005-1008.
- 134. Micouin, L.; Knochel, P.* "Iodine-Zinc Exchange Mediated by i-Pr2Zn. A New Preparation of Secondary Zinc Reagents" Synlett, 1997, 327-328.
- 135. Klement, I.; Lütjens, H.; Knochel, P. "Chemoselective Oxidation of Organozinc Reagents with Oxygen" Tetrahedron 1997, 57, 9135-9144.
- 136. Longeau, A.; Durand, S.; Spiegel, A.; Knochel, P. "Synthesis of New C2-Symmetrical Diphosphines Using Chiral Zinc Organometallics" Tetrahedron: Asymmetry 1997, 8, 987-990.
- 137. Rottländer, M.; Knochel, P. "New Multi-Coupling Benzylic Zinc Reagents for the Preparation of Flexible Aromatic Compounds" Tetrahedron Lett. 1997, 38, 1749-1752.
- 138. Schwink, L.; Knochel, P. "New Chiral Ferrocenyl Building Blocks for Asymmetric Reactions" Tetrahedron Lett. 1997, 38, 3711-3714.
- 139. Berger, S.; Langer, F.; Lutz, C.; Knochel, P.; Mobley, T. A.; Reddy, Ch. K., "Mixed -Silyl Diorganozincs; a New Class of Useful Zinc Reagents" Angew. Chem. 1997, 109, 1603-1605; Angew. Chem. Int. Ed. Engl. 1997, 36, 1496-1498.
- 140. Vettel, S.; Lutz, C.; Diefenbach; G.; Haderlein, S.; Hammerschmidt, S.; Kühlung, K.; Mofid, M.-R.; Zimmermann, T.; Knochel, P., "Catalytic Asymmetric Synthesis of Protected -Hydroxy Aldehydes and Related 1,2-Difunctional Chiral Building Blocks. An enantioselective Synthesis of (-)-exo and (-)-endo-Brevicomin" Tetrahedron: Asymmetry 1997, 8, 779-800.
- 141. Klement, I.; Lütjens, H.; Knochel, P.* "Transition Metal Catalyzed Oxidations in Perfluorinated Solvents" Angew. Chem. 1997, 109, 1605-1607; Angew. Chem. Int. Ed. Engl. 1997, 36, 1454-1456.
- 142. Prasad, A. S. B.; Stevenson, T. M.; Citineni, J. R.; Nyzam, V.; Knochel, P.*, "Preparation and Reactions of New Zincated Nitrogen-Containing Heterocycles" Tetrahedron 1997, 53, 7237-7254.
- 143. Lutz, C.; Knochel, P. "Highly Enantioselective Addition of Mixed Diorganozincs to Aldehydes" J. Org. Chem. 1997, 62, 7895-7998.
- 144. Klement, I.; Stadtmüller, H.; Knochel, P.; Cahiez, G. "Preparation and Reactivity of Functionalized Aryl and Alkenylmanganese Halides" Tetrahedron Lett. 1997, 38, 1927-1930.
- 145. Cerè, V.; De Angelis, S.; Pollicino, S.; Ricci, A.; Kishan, Ch, R., Knochel, P.; Cahiez, G. "Preparation of 2-Zinc-1,3-Dithianes and of Di(1,3-dithianyl)zinc and their Reactivity with Highly Functionalized Halides and with α,β-Unsaturated Carbonyl Compounds" Synthesis, 1997, 1174-1178.
- 146. Lütjens, H.; Wahl, G.; Sundermeyer, J.*; Knochel, P.* "New Chiral C3-Symmetric Triols as Ligands for Vanadium and Titanium Complexes" Organometallics 1997, 16, 5869-5878.
- 147. Rottländer, M.; Knochel, P.* "Multiple Cross-Coupling Reactions of Aryl and Benzylic Zinc Halides in Solid-Phase Synthesis of Polyfunctional Aromatics" Synlett 1997, 1084-1086.
- 148. Almena Perea, J. J.; Ireland, T.; Knochel, P.* "Substitution of Ferrocenyl Acetates with Organozincs. An enantioselective Preparation of Polyfunctional Chiral Ferrocenes" Tetrahedron Lett. 1997, 38, 5961-5964.
- 149. Betzemeier, B.; Knochel, P.* "Palladium Catalyzed Cross-Coupling of Organozinc Halides with Aryl Iodides in Perfluorinated Solvents" Angew. Chem. 1997, 109, 2736-2739; Angew. Chem. Int. Ed. Engl. 1997, 36, 2623-2624.
- 150. Prasad, A. S. B.; Knochel, P.* "Preparation and Reactions of 2-Zincated 2-Cyclohexen-1-one and Related Heterocycles" Tetrahedron, 1997, 53, 16711-16720.
- 151. Jones, P.; Reddy, K. C.; Knochel, P.* "Conjugate Michael-Addition with Mixed Diorganozincs" J. Chem. Soc., 1997, 3117-3118.
- 152. Stüdemann, T.; Ibrahim-Ouali, M., Knochel, P.* "A Nickel-Catalyzed Carbozincation of Aryl substituted Alkynes" Tetrahedron-Symposium 1998, 54, 1299-1316.
- 153. Rottländer, M.; Knochel, P.* "Palladium Catalyzed Cross-Coupling Reactions with Aryl Nonaflates. A Practical Alternative to Aryl Triflates" J. Org. Chem. 1998, 63, 203-208.
- 154. Lhermitte, F.; Knochel, P.* "Stereoselective Allylic C-H Activation using Tertiary Alkylboranes. A New Method for the Preparation of Cyclopentane Derivatives with three Adjacent Stereocenters" Angew. Chem. 1998, 110, 2598-2599; Angew. Chem. Int. Ed. Engl. 1998, 37, 2460-2461.
- 155. Stüdemann, T.; Ibrahim-Ouali, M.; Cahiez, G.*; Knochel, P.* "Stereoselective Nickel and Manganese Catalyzed Cyclizations of 5-Haloketones" Synlett 1998, 143-144.
- 156. Schwink, L.; Knochel, P.* "Enantioselective Preparation of C2-symmetrical Ferrocenyl Ligands for Asymmetric Catalysis" Chem. Eur. J. 1998, 4, 950-968.
- 157. Darcel, C.; Flachsmann, F.; Knochel, P.* "Stereoselective Preparation and Reactions of Configurationally Defined Mixed Acyclic Dialkylzincs" J. Chem. Soc.; Chem. Commun. 1998, 205-206.
- 158. Prasad, A. S. B.; Eick, H.; Knochel, P.* "The Preparation of 1,3-Dizincapropanes via a Boron-Zinc Transmetalation" J. Organomet. Chem. 1998, 562, 133-139.
- 159. Schwink, L.; Ireland, T.; Püntener, K.; Knochel, P. "New C2-Symmetrical Ferrocenyl Diamines as Ligands for Ruthenium Catalyzed Transfer Hydrogenation" Tetrahedron: Asymmetry 1998, 9, 1143-1163.
- 160. Schwink, L.; Knochel, P.*; Eberle, T.; Okuda, J.* "Synthesis of Chiral Bridging β-Amino-Cyclopentadienes and Their Complexation to Transition Metals" Organometallics 1998, 17, 7-9.
- 161. Jones, P.; Reddy, C. K.; Knochel, P.* "Conjugate Michael Additions with Mixed Diorganozincs" Tetrahedron, 1998, 54, 1471-1490.
- 162. Lutz, C.; Graf, C.-D.; Knochel, P.* "New Strategy for the Preparation of Nitrogen- and Phosphorus Containing Chiral Polyfunctional Secondary Alcohols" Tetrahedron 1998, 54, 10317-10328.
- 163. Boymond, L.; Rottländer, M.; Cahiez, G.*, Knochel, P.* "Preparation of Highly Functionalized Grignard Reagents via an Iodine-Magnesium Exchange Reaction. Applications to Solid Phase Synthesis" Angew. Chem. 1998, 110, 1801-1804; Angew. Chem. Int. Ed. Engl. 1998, 37, 1701-1703.
- 164. Lutz, C.; Lutz, V.; Knochel, P. "Enantioselective Synthesis of 1,2-, 1,3- and 1,4-Aminoalcohols by the Addition of Dialkylzincs to 1,2-, 1,3- and 1,4-Aminoaldehydes" Tetrahedron 1998, 54, 6385-6402.
- 165. Giovannini, R.; Stüdemann, T.; Dussin, G.; Knochel, P.* "A New Efficient Nickel-Catalyzed Cross-Coupling Between Csp3-Centers" Angew. Chem. 1998, 110, 2512-2515; Angew. Chem. Int. Ed. Engl. 1998, 37, 2387-2390.
- 166. Avedissian, H.; Bérillon, L.; Cahiez, G.*; Knochel, P.* "Cobalt Catalyzed Alkenylation of Zinc Organometallics" Tetrahedron Lett. 1998, 39, 6163-6166.
- 167. Graf, C.-D.; Malan, C.; Knochel, P.* "New Chiral Ligands with Non-stereogenic Chirotopic Centers for Asymmetric Synthesis" Angew. Chem. 1998, 110, 3215-3218; Angew. Chem. Int. Ed. Engl. 1998, 37, 3014-3016.
- 168. Betzemeier, B.; Lhermitte, F.; Knochel, P.* "Wacker Oxidation Using a Fluorous Biphasic System. A Mild Preparation of Polyfunctional Ketones" Tetrahedron Lett. 1998, 39, 6667-6670.
- 169. Bérillon, L; Wagner, R.; Knochel, P.* "Preparation and Reactions of Zincated Thymine Derivatives" J. Org. Chem. 1998, 63, 9117-9121.
- 170. Bérillon, L.; Leprêtre, A., Turck, A.; Plé, N.; Queguiner, G.;* Cahiez, G.; Knochel, P.* "Preparation of Highly Functionalized Pyridylmagnesium Reagents for the Synthesis of Polyfunctional Pyridines" Synlett 1998, 1359-1360.
- 171. Giovannini, R.; Knochel, P* "Ni (II)-Catalyzed Cross-Coupling Between Polyfunctional Arylzinc Derivatives and Primary Alkyl Iodides" J. Am. Chem. Soc. 1998, 120, 11186-11187.
- 172. Jones, P.; Millot, N.; Knochel, P.* "Masked Allylic Zinc Reagents" Chem. Commun. 1998, 2405-2406.
- 173. Jones, P.; Knochel, P. "Highly Diastereoselective Reactions Using Masked Allylic Zinc Reagents" Chem. Commun. 1998, 2407-2408.
- 174. Almena Perea, J. J.; Börner, A.; Knochel, P.* "A Versatile Approach to New Chiral C2-symmetrical Ferrocenyl Ligands: Highly Enantioselective Rh-Catalyzed Hydrogenation of α-Acetamidoacrylic Acid Derivatives" Tetrahedron Lett. 1998, 39, 8073-8076.
- 175. Boudier, A.; Flachsmann, F.; Knochel, P.* "Stereoselective Preparation of Chiral Secondary Cycloalkyl- and Alkyl-Zinc Reagents" Synlett 1998, 39, 1438-1440.
- 176. Rottländer, M.; Boymond, L., Cahiez, G.*; Knochel, P.* "Stereoselective Preparation of Functionalized Alkenylmagnesium Reagents via an Iodine-Magnesium Exchange Reaction" J. Org. Chem. 1999, 64, 1080-1081.
- 177. Dübner, F.; Knochel, P.* "Copper (I) Catalyzed Allylation of Allylic Chlorides with Diorganozincs" Angew. Chem. 1999, 111, 391-393; Angew. Chem. Int. Ed. Engl. 1999, 38, 379-381.
- 178. Giovannini, R.; Knochel, P.* "A New Efficient Nickel-Catalyzed Cross-Coupling reaction between two Csp3-Centers" J. Org. Chem. 1999, 64, 3544-3553.
- 179. Lutz, C.; Jones, P.; Knochel, P.* "Neopentyl- and Neophyl-Groups: New Non-Transferable Groups for Organocopper and Organozinc Chemistry" Synthesis, 1999, 312-316.
- 180. Jones, P.; Knochel, P.* "Preparation and Reactions of New Masked Allylic Organozinc Reagents" J. Org. Chem. 1999, 64, 186-195.
- 181. Boudier, A.; Knochel, P.* "Palladium Catalyzed Stereoselective Cross-Couplings and Acylations of Chiral Secondary Diorganozincs" Tetrahedron Lett. 1999, 40, 687-690.
- 182. Ireland, T.; Almena, J. J.; Knochel, P.* "Synthesis and Stereoselective Reactions of New Stable Ferrocenyllithium Derivatives. An Umpolung of the Ferrocene Reactivity" Angew. Chem. 1999, 111, 1560-1562; Angew. Chem. Int. Ed. Engl. 1999, 38, 1457-1460.
- 183. Graf, C.-D.; Knochel, P.* "Asymmetric Hydroboration with New Chiral Monoalkylboranes bearing a Non-Stereogenic, Chirotopic Center" Tetrahedron 1999, 55, 8801-8814.
- 184. Rottländer, M.; Knochel, P.* "Synthesis of 2,4-Disubstituted 2,5-Dihydrofurans and 1-Substituted 1,3-Dihydroisobenzofurans via an Iodine-Magnesium Exchange Reaction" J. Comb. Chem. 1999, 1, 181-183.
- 185. Almena Perea, J. J.; Lotz, M.; Knochel, P.* "Synthesis and Application of C2-Symmetrical Ferrocenyl Diamino Diphosphine as Ligands for Enantioselective Rh-Catalyzed Preparation of Chiral α-Aminoacids" Tetrahedron: Asymmetry 1999, 10, 375-384.
- 186. Betzemeier, B.; Lhermitte, F.; Knochel, P.* "A Selenium Catalyzed Epoxidation of Perfluorinated Solvents with Hydrogen Peroxide" Synlett 1999, 489-491.
- 187. Laaziri, H.; Bromm, L. O.; Lhermitte, F.; Gschwind, R.; Knochel, P. "A New Highly Stereoselective Rearrangement of Acyclic Tertiary Organoboranes. An Example of Highly Stereoselective Remote C-H Activation" J. Am. Chem. Soc. 1999, 121, 6940-6941.
- 188. Tzalis, D.; Knochel, P.* "Cesium Hydroxide: A Superior Base for the Catalytic Alkynylation of Aldehydes and Ketones and Catalytic Alkenylation of Nitriles" Angew. Chem. 1999, 111, 1547-1549.; Angew. Chem. Int. Ed. Engl. 1999, 38, 1463-1465.
- 189. Demay, S.; Harms K.; Knochel, P.* "Stereoselective Preparation of Phosphine Oxides via a 2,3-Sigmatropic Shift of Allylic Diphenylphosphinites" Tetrahedron Lett. 1999, 40, 4981-4984.
- 190. Tzalis, D.; Knochel, P.* "Ru-Centered Coordination Complexes as a New Phase Transfer Catalyst for Alkylation of Enolates and Michael-Additions" Tetrahedron Lett. 1999, 40, 3685-3688.
- 191. Graf, C.-D.; Malan, C.; Harms, K.; Knochel, P.* "New Chiral Ligands bearing a Non-Stereogenic Chirotopic Center Lithiated N,N-Dialkylureas as Chiral Bases and Sterically Crowded Phosphines for Asymmetric Catalysis" J. Org. Chem. 1999, 64, 5581-5588.
- 192. Varchi, G.; Ricci, A.; Cahiez, G.; Knochel, P.* "Copper Catalyzed Conjugate Addition of Highly Functionalized Arylmagnesium Compounds to Enones" Tetrahedron; Symposium, 2000, 56, 2727-2731.
- 193. Tzalis, D.; Koradin, C; Knochel, P.* "Cesium Hydroxide Catalyzed Addition of Alcohols and Amine Derivatives to Alkynes and Styrene" Tetrahedron Lett. 1999, 40, 6193-6195.
- 194. Millot, N.; Knochel, P.* "Preparation and Stereoselective Addition of new Highly Stereoselective Addition of new Highly Substituted Allylic Zinc Reagents. A new Zinc-Ene Reaction" Tetrahedron Lett. 1999, 40, 7779-7782.
- 195. Lotz, M.; Ireland, T.; Almena, J. J.; Knochel, P.* "Stereoselective Substitution of a-Aminoalkylferrocenes with Diorganozincs. A fast Synthesis of New Chiral FERRIPHOS-Ligands for Asymmetric Catalysis" Tetrahedron Asymmetry 1999, 10, 1839-1842.
- 196. Ireland, T.; Großheimann, G.; Knochel, P.* "New Aminoferrocenyl Diphosphines as Ligands for Asymmetric Hydrogenation of Functionalized Double Bonds" Angew. Chem. 1999, 111, 3397-3400; Angew. Chem. Int. Ed. Engl. 1999, 21, 3212-3215.
- 197. Betzemeier, B.; Knochel, P.* "Perfluorinated Solvents - a Novel Reaction Medium in Organic Chemistry" in Topics of Current Chemistry: New Solvent Systems, Springer Verlag 1999.
- 198. Abarbri, M.; Dehmel, F.; Knochel, P.* "The Bromine-Magnesium Exchange as a General Tool for the Preparation of Polyfunctional Aryl and Heteroaryl Magnesium Reagents" Tetrahedron Lett. 1999, 40, 7449-7453.
- 199. Piber, M.; Jensen, A. E.; Rottländer, M.; Knochel, P.* "New Efficient Nickel and Palladium Catalyzed Cross-Coupling Reactions Mediated by Tetrabutylammonium Iodide" Org. Lett. 1999, 1, 1324-1326.
- 200. Abarbri, M.; Knochel, P.* "Preparation and Reactions of Magnesiated Uracil Derivatives" Synlett 1999, 1577-1578.
- 201. Avolio, S.; Malan, C.; Marek, I.; Knochel, P. "Preparation and Reactions of Functionalized Magnesium Carbenoids" Synlett 1999, 1820-1822.
- 202. Dehmel, F.; Abarbri, M.; Knochel, P*. "Preparation of new Magnesiated Functionalized Imidazoles and Antipyrines via an Iodine-Magnesium Exchange" Synlett 1999, 345-346.
- 203. Riese, U.; Faza, N.; Massa, W.; Harms, K.; Breyhan, T.; Knochel, P.*; Ensling, J.; Ksenofontov, V.; Gütlich, P.; Dehnicke, K. "Phosphoraneiminato Complexes of Manganese and Cobalt with Heterocubane Structure" Z. Anorg. Allg. Chem., 1999, 625, 1494-1499.
- 204. Aufauvre, L.; Knochel, P.*; Marek, I.; "A new approach towards the synthesis of sp3 1,1-diiodoalkanes" J. Chem. Soc. Chem. Commun. 1999, 2207-2208.
- 205. Boudier, A.; Darcel, C.; Flachsmann, F; Micouin, L.; Oestreich, M.; Knochel, P.* "Stereoselective preparation and Reactions of Configurationally Defined Dialkylincs" Chem. Eur. J. 2000, 6, 2748-2761.
- 206. Lotz, M.; Ireland, T.; Tappe, K.; Knochel, P.* "Preparation of New Chiral Borane-Protected P,N-Ferrocenyl Ligands via a Methoxy Directed ortho-Lithiation" Chirality 2000, 12, 389-395.
- 207. Rodriguez, A.; Koradin, K.; Dohle, W.; Knochel, P.* "Versatile Indole Synthesis by a 5-Endo Dig Cyclization mediated by Potassium or Cesium Base" Angew. Chem. Int. Ed. 2000, 39, 2488-2490.
- 208. Boudier, A.; Hupe, E.; Knochel, P.* "Highly Diastereoselective Synthesis of Monocyclic and Bicyclic Secondary Diorganozincs with Defined Configuration" Angew. Chem. Int. Ed. 2000, 39, 2294-2297.
- 209. Abarbri, M.; Thibonnet, J.; Bérillon, L.; Dehmel, F.; Rottländer, M.; Knochel, P.* "Preparation of New Polyfunctional Magnesiated Heterocycles Using a Chlorine-, Bromine- or Iodine-Magnesium Exchange" J. Org. Chem. 2000, 65, 4618-4634.
- 210. Thibonnet, J.; Knochel, P.* "Preparation of Functionalized Alkenylmagnesium Bromides via a Bromine-Magnesium Exchange" Tetrahedron Lett. 2000, 41, 3319-3322. .
- 211. Millot, N.; Piazza, C.; Avolio, S.; Knochel, P.* "Aminomethylation of Functionalized Organozinc Reagents and Grignard Reagents Using Immonium Trifluoroacetates" Synthesis 2000, 941-948.
- 212. Bromm, L.O.; Laaziri, H.; Lhermitte, F.; Harms, K; Knochel, P.* "Highly Regio- and Stereoselective Thermal Migration of Organoboranes in Acyclic Molecules" J. Am. Chem. Soc. 2000, 122, 10218-10219.
- 213. Betzemeier, B.; Cavazzini, M.; Quici, S.; Knochel, P.* "Copper Catalyzed Aerobic Oxidation of Alcohols under Fluorous Biphasic Conditions" Tetrahedron Lett. 2000, 40, 4343-4346.
- 214. Jensen, S.; Dohle, W.; Knochel, P.* "Improved Nickel-Catalyzed Cross-Coupling Reaction Conditions" Tetrahedron 2000, 56, 4197-4201.
- 215. Rodriguez, A. L.; Bunlaksananusorn, T.; Knochel, P.* "Potassium tert-Butoxide Catalyzed Addition of Carbonyl Derivatives to Styrenes" Org. Lett. 2000, 2, 3285-3287.
- 216. Jensen, A. E., Kneisel, F; Knochel, P.* "Ethyl 3-(p-cyanophenyl) propionate from ethyl 3-iodopropionate and p-cyanophenylzinc bromide" Org. Synth. 2002, 79, 35-42.
- 217. Dübner, F,; Knochel, P.* "Highly Enantioselective Copper Catalyzed Substitution of Allylic Chlorides with Diorganozincs" Tetrahedron Lett. 2000, 41, 9233-9237.
- 218. Delacroix, T.; Bérillon, L.; Cahiez, G.; Knochel, P.* "Preparation of Functionalized Arylmagnesium Reagents Bearing an ortho-Chloromethyl Group" J. Org. Chem. 2000, 65, 8108-8110.
- 219. Koradin, C.; Rodriguez, A.; Knochel, P.* "Cesium Catalyzed Addition of Nitriles to Alkynes" Synlett 2000, 1452-1454.
- 220. Sirieix, J.; Oßberger, M.; Betzemeier, B.; Knochel, P.* "Palladium Catalyzed Cross-Couplings of Organozincs in Ionic Liquids" Synlett 2000, 1613-1615.
- 221. Goldfuss, B.; Knochel, P.*; Bromm, L. O.; Knapp, K. "C-H Aktivierung durch direkte Boran-Kohlenwasserstoff Dehydrierung: Kinetische und Thermodynamische Aspekte" Angew. Chem. 2000, 112, 4302-4305; Angew. Chem. Int. Ed. 2000, 39, 4136-4139.
- 222. Varghese, J. P.; Knochel, P.*; Marek, I. "New Allene Synthesis via Carbocupration-Zinc Carbenoid Homologation and ß-Elimination Sequence" Org. Lett. 2000, 2, 2849-2852.
- 223. Piazza, C.; Millot, N.; Knochel, P.* "New Preparation of Benzylic Zinc Reagents via a Fragmentation Reaction" J. Organomet. Chem. 2001, 624, 88-95.
- 224. Demay, S.; Volant, F.; Knochel, P.* "New C2-Symmetrical 1,2-Diphospanes for the Efficient Rhodium-Catalyzed Asymmetric Hydroboration of Styrene Derivatives" Angew Chemie Int. Ed. 2001, 40, 1235-1238; Angew. Chem. 2001, 113, 1272-1275.
- 225. Hupe, E.; Knochel, P.* "Stereoselective Synthesis of Secondary Organozinc Reagents and their Reaction with Heteroatomic Electrophiles" Org. Lett. 2001, 3, 127-130.
- 226. Varchi, G.; Jensen, A. E.; Dohle, W.; Ricci, A.; Cahiez, G.; Knochel, P.* "Preparation of Functionalized Magnesiated Aniline Derivatives" Synlett 2001, 477-480.
- 227. Ireland, T.; Tappe, K.; Grossheimann, G.; Knochel, P.* "Synthesis of a new class of chiral 1,5-diphosphino ferrocene ligands and their use in enantioselective hydrogenations" Chem. Eur. J. 2001, 8, 843-852.
- 228. Bunlaksananusorn, T.; Rodriguez, A. L.; Knochel, P.* "tert-BuOK-Catalyzed Addition of Ketones and Nitriles to Vinylic Silanes, Phosphines and Thio Derivatives" Chem. Comm. 2001, 8, 745-746.
- 229. Demay, S.; Kotschy, A.; Knochel, P.* "Enantioselective Preparation of a Novel Chiral 1,2-Diamine" Synthesis 2001, 6, 863-866.
- 230. Bonnet, V.; Mongin, F.; Trécourt, F.; Quéguiner, G.; Knochel, P.* "Preparation of Polyfunctional Pyridines by a Palladium (0) Catalyzed Cross-Coupling of Functionalized Aryl and Heteroaryl Grignard Reagents" Tetrahedron Lett. 2001, 42, 5717-5720.
- 231. Demay, S.; Lotz, M.; Polborn, K.; Knochel, P.* "Preparation of a Rigid Bicyclic Diphosphine by Radical Cyclization" Tetrahedron: Asymmetry 2001, 12, 909-914.
- 232. Hupe, E.; Knochel, P.* "Formal Enantioselective Michael-Addition with Umpolung of the Reactivity" Angew. Chem. Int. Ed. 2001, 40, 3022-3025.
- 233. Varela Carrete, J., Pena, D.; Goldfuss, B.; Polborn, K.; Knochel, P.* "Remote C-H Activation of Phenyl Substituted Alkenes by BH3•THF: Mechanism, and Applications" Org. Lett. 2001, 15, 2395-2398.
- 234. Boucley, C.; Cahiez, G.; Carini, S.; Comes-Franchini, M.; Knochel, P.; Pollicino, S.; Ricci, A. "Stereoselective Addition of Organomanganese Reagents to Chiral Acylsilanes and Aldehydes" J. Organomet. Chem. 2001, 624, 223-228.
- 235. Knochel; P.*; Hupe, E.; Dohle, W., Lindsay, D. M., Bonnet, V., Queguiner, G., Boudier, A., Kopp, F., Demay, S., Seidel, N., Calaza, M. I., Vu, V. A., Sapountzis, I., Bunlaksananusom, T. "Functionalized Main Group Organometallics for Organic Synthesis" Pure Appl. Chem. 2002, 74, 11-17.
- 236. Dohle, W.; Lindsay, D. M.; Knochel, P.* "Copper-Mediated Cross-Coupling of Functionalized Alkyl and Benzylic Halides" Org. Lett. 2001, 3, 2871-2873.
- 237. Jensen, A. E.; Knochel, P.* "Nickel Catalyzed Cross-Coupling between Functionalized Primary or Secondary Alkylzinc Halides and Primary Alkyl Halides" J. Org. Chem. 2002, 67, 79-85.
- 238. Shibli, A.; Varghese, J. P.; Knochel, P.*; Marek, I. "Improved Preparation of Secondary Zinc Iodides by 1,2-Migration of sp3 Carbenoids" Synlett 2001, 6, 818-820.
- 239. Dohle, W.; Kopp, F.; Cahiez, G.; Knochel, P.* "Fe (III)-Catalyzed Cross-Coupling Between Functionalized Arylmagnesium Compounds and Alkenyl Halides" Synlett 2001, 1901-1904.
- 240. Sapountzis, I.; Dohle, W.; Knochel, P.* "Stereoselective Preparation of Highly Functionalized (E)-3-Magnesiated Enoates by an Iodine-Magnesium Exchange Reaction" Chem. Commun. 2001, 2068-2069.
- 241. Vu, V. A.; Bérillon, L.; Knochel, P.* "New Functionalized Alkenylmagnesium Reagents Bearing an Oxygen Function in the β–Position. Preparation and Reaction of 5-Magnesiated-1,3-Dioxin-4-one Derivatives" Tetrahedron Lett. 2001, 42, 6847-6850.
- 242. Hupe, E.; Calaza, I.; Knochel, P.* "Extending the Scope of Substrate Controlled Diastereoselective Hydroborations Using a Boron-Zinc Exchange Reaction" Tetrahedron Lett. 2001, 42, 8929-8932.
- 243. Jensen, A. E.; Knochel, P.* "Preparation of 2-Arylated 1,4-Phenylenediamines by Palladium-Catalyzed Cross-Coupling Reactions" J. Organomet. Chem. 2002, 653, 122-128.
- 244. Vu, V. A.; Marek, I.; Polborn, K.; Knochel, P.* "Preparation of new functionalized cyclopropylmagnesium reagents" Angewandte Chem. Int. Ed. 2002, 41, 351-352.
- 245. Jensen, A. E.; Dohle, W.; Sapountzis, I.; Lindsay, D. M.; Vu, V. A.; Knochel, P.* "Practical Synthetic Procedures: Preparation and Reactions of Functionalized Arylmagnesium Reagents" Synthesis 2002, 565-569.
- 246. Lindsay, D. M.; Dohle, W.; Jensen, A. E., Kopp, F.; Knochel, P.* "Polyfunctional Heterocycles using Highly Functionalized Aminated Arylmagnesium Reagents as Versatile Scaffolds" Org. Lett. 2002, 4 , 1819-1822.
- 247. Ragagnin, G.; Betzemeier, B.; Quici, S.; Knochel, P.* "Copper-catalysed aerobic oxidation of alcohols using fluorous biphasic catalysis" Tetrahedron Symposium in print, 2002, 58, 3985-3991.
- 248. Sapountzis, I.: Knochel, P.* "General Preparation of Functionalized o-Nitroarylmagnesium Halides via an Iodine-Magnesium Exchange" Angew. Chem. Int. Ed. 2002, 41, 1610-1711.
- 249. Bonnet, V.; Mongin, F.; Trecourt, F.; Queguiner, G.; Knochel, P.* "Syntheses of Substituted Pyridines, Quinolines and Diazines via Palladium (0)-catalyzed Cross-coupling of Aryl Grignard Reagents" Tetrahedron 2002, 58, 4429-4438.
- 250. Bonnet, V.; Mongin, F.; Trecourt, F.; Breton, G.; Knochel, P*; Queguiner,G.* "Cross-coupling Reactions between 3-Pyridylmagnesium Chlorides and Halo Substrates" Synlett 2002, 1008-1010.
- 251. Koradin, C.; Knochel, P.* "Enantioselective Synthesis of Propargylamines by a Copper Catalyzed Addition of Alkynes to Enamines" Angew. Chem. Int. Ed. 2002, 41, 2535-2538; Angew. Chem. 2002, 114, 2651-2654.
- 252. Thibonnet, J.; Vu, Viet Anh; Bérillon, L.; Knochel. P.* "Alkenylmagnesium Reagents via a Halide-Magnesium Exchange" Tetrahedron 2002, 58, 4787-4799.
- 253. Hupe, E.; Calaza, I.M.; Knochel, P.* "One-Pot Chemoselective Functionalization of Arylsilanes via Cascade Metal Metal Exchange Reactions" ChemComm 2002, 1390-1391.
- 254. Hupe, E.; Marek, I.; Knochel, P.* "Diastereoselective Reduction of Alkenylboronic Esters as a New Method for Controlling the Stereochemistry of up to Three Adjacent Centers in Cyclic and Acyclic Molecules" Org. Lett 2002, 2861-2863.
- 255. Varchi, G., Kofink, C., Lindsay, D.M., Ricci, A., Knochel, P.* "Direct Preparation of Polyfunctional Amino-Substituted Arylmagnesium via an Iodine-Magnesium Exchange Reaction" Chem. Commun. 2003, 396-397.
- 256. Kneisel, F. F., Monguchi, Y., Knapp, K. M., Zipse, H., Knochel, P.* "Stereoselective Cyclization Reactions Mediated by Functionalized Organomagnesium Reagents and Catalyzed by Cobalt or Copper Salts" Tetrahedron Lett 2002, 43, 4875-4879.
- 257. Patti, A.; Lotz, M.; Knochel, P.* "Synthesis of α,β-disubstituted ferrocenes via a ferrocenylepoxide internmediate. Preparation and catalytic activity of a new chiral ferrocenyloxazoline" Tetrahedron: Asymmetry 2002, 12, 3375-3380.
- 258. Hupe, E., Knochel, P.*, Szabo, K. J. "Mechanism of the Stereoselective Alkyl Group Exchange between Alkylboranes and Alkylzinc Compounds. Quest for Novel Types of Boron-Metal-Exchange Reactions" Organometallics 2002, 21, 2203-2207.
- 259. Piazza, C., Knochel, P.* "New Sterically Hindereed Lithium Dialkylcuprates for the Generation of Highly Functionalized Mixed Cuprates via a Halogen-Copper Exchange" Angew. Chem. Int. Ed. 2002, 41, 3263-3265; Angew. Chem. 2002, 114, 3397-3399.
- 260. Bunlaksananusorn, T.; Knochel, P.* "t-BuOK-Catalyzed Addition of Phosphines to Functionalized Alkenes: A Convenient Synthesis of Polyfunctional PhosphineDerivatives" Tetrahedron Lett 2002, 43, 5817-5819.
- 261. Ragagnin, G.; Betzemeier, B.; Quici, S.; Knochel, P.* "Copper-catalysed aerobic oxidation of alcohols using fluorous biphasic catalysis" Tetrahedron 2002, 3985-3991.
- 262. Lotz, M.; Polborn, K.; Knochel, P.* "New Ferrocenyl Ligands with broad Applications in Asymmetric Catalysis" Angew. Chem. Int. Ed. 2002, 41, 4708-4711..
- 263. Gommermann, N.; Koradin, C.; Knochel, P.* "Synthesis of Polyfunctional Unsaturated Amines by the Addition of Functionalized Organomagnesium Reagents to Unsaturated Imminium Ions" Synthesis 2002, 2143-2149.
- 264. Lotz, M.; Kramer; G.; Knochel, P.* "Facile Axial Chirality Control by Using A Precursor with Central Chirality. Application to the Preparation of new Axially Chiral Diphosphine Complexes for asymmetric Catalysis" Chem. Commun. 2002, 2546-2547.
- 265. Koradin, C.; Dohle, W.; Rodriguez, A. L.; Schmid, B.; Knochel, P.* "Synthesis of Polyfunctional Indoles and Related Heterocycles Mediated by Cesium and Potassium Bases" Tetrahedron 2003, 59, 1571-1587.
- 266. Sapountzis, I, Knochel, P.* "A New General Preparation of Polyfunctional Diarylamines by the Addition of Functionalized Arylmagnesium Compounds to Nitroarenes" J. Am. Chem. Soc. 2002, 124, 9390-9391.
- 267. Kneisel, F.F., Knochel, P.* "Synthesis and Reactivity of Aryl- and Heteroaryl-Magnesium Reagents Bearing Keto Groups" Synlett 2002, 1799-1802.
- 268. Klötzing, R., Lotz, M., Knochel, P.* "New P,N-ferrocenyl ligands for the rhodium-catalyzed allylic alkylation" Tetrahedron: Asymmetry 2003, 14, 255-264.
- 269. Staubitz, A., Dohle, W., Knochel, P.* "Expiditious Functionalization of Quinolines in Position 2 and 8 via Polyfunctionalized Aryl- and Heteroaryl-magnesium Intermediates" Synthesis 2003, 233-242.
- 70. Hupe, E.; Denisenko, D.; Knochel, P.* "Stereoselective Migration of Sterically Hindered Organoboranes in Cyclic and Acyclic Systems. A Stereoselective Allylic C-H Activation Reaction" Chem. Eur. J. 2003, 9, 9187-9198.
- 271. Varghese, J.P., Zouev, I.; Aufavre, L.; Knochel, P.*; Marek, I.* "Carbocupration/Zinc Carbenoid Homologation and b-Elimination Reactions for a New Synthesis of Allenes-Application to the Enantioselective Synthesis of Chiral Allenes by Deracemization of sp3-Organometallic Derivatives" Eur. J. Org. Chem. 2002, 4151-4158.
- 272. Hupe, E.; Calaza, I. M.; Knochel, P.* "Substrate Controlled Highly Diastereoselective Synthesis of Primary and Secondary Diorganozinc Reagents via a Hydroboration/ Boron-Zinc Exchange Sequence" Chem. Eur. J. 2003, 9, 2789-2796.
- 273. Harrington-Frost, N.; Leuser, H.; Calaza, I. M.; Kneisel, F. F.; Knochel, P.* "Highly Stereoselective Anti SN2’-Substitutions of Z-Allylic Pentafluorobenzoates with Polyfunctionalized Zinc-Copper Reagents" Org. Lett. 2003, 5, 2111-2114.
- 274. Koradin, C.; Gommermann, N.; Polborn, K.; Knochel, P.* "Synthesis of Enantiomerically Enriched Propargylamines by Copper Catalyzed Addition of Alkynes to Enamines" Chem. Eur. J. 2003, 9, 2797-2811.
- 275. Calaza, M. I.; Hupe, E.; Knochel, P* "Highly Anti-Selective SN2’-Substitution of Chiral Cyclic 2-Iodo-Allylic Alcohol Derivatives with Mixed Zinc-Copper Reagents" Org. Lett. 2003, 5, 1059-1061.
- 276. Yang, X.; Rotter, T.; Piazza, C., Knochel, P.* "Successive Iodine-Magnesium or –Copper Exchange Reactions for the Selective Functionalization of Polyhalogenated Aromatics" Org. Lett. 2003, 5, 1229-1231.
- 277. Kopp, F.; Sapountzis, I.; Knochel, P.* "Preparation of Polyfunctionalized Amines by the Addition of Functionalized Organomagnesium Reagents to Nitrosoarenes" Synlett 2003, 885-887.
- 278. Knapp, K.M.; Goldfuss, B.; Knochel, P.* "Stereoselective Synthesis of 1,4-diols by a BH3-THF mediated Rearrangement of 1,2-Disubstituted Cyclobutenes" Chem. Eur. J. 2003, 9, 5259-5265.
- 279. Dohle, W.; Staubitz, A.; Knochel, P.* "Mild Synthesis of Polyfunctional Benzimidazoles and Indoles by the Reduction of Functionalized Nitroarenes with Phenylmagnesium Chloride" Chem. Eur. J. 2003, 9, 5323-5331.
- 280. Bunlaksananusorn, T. Knochel, P.* "New P,N-Ligands for the Performance of Asymmetric Ir- and Pd- Catalyzed Reactions" Angew. Chem. Int. Ed. 2003, 42, 3941-3943.
- 281. Gommermann, N., Koradin, C.; Knochel P.* "A New Enantioselective Copper(I)-Catalyzed Three-Component Reaction for the Preparation of Propargylamines" Angew. Chem. 2003, 115, 5941-5944; Angew. Chem. Int. Ed. 2003, 42, 5763-5766
- 282. Korn, T.; Cahiez, G., Knochel P.* "New Cobalt-Catalyzed Cross-Coupling Reactions of Heterocyclic Chlorides with Aryl and Heteroaryl Magnesium Halides" Synlett 2003, 1892-1894.
- 283. Vu, V.-A.; Knochel P.* "Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Carbenoids" Synthesis 2003, 1797-1802.
- 284. Tappe, K..; Knochel P.* "New Efficient Synthesis of Taniaphos-Ligands. Application in Ruthenium- and Rhodium-Catalyzed Enantioselective Hydrogenations" Tetrahedron: Asymmetry 2004, 15, 91-102.
- 285. Sapountzis, I.; Knochel, P.* "A New Method for the Selective Amination of 1,3- and 1,4-Dinitrobenzenes and Protected Nitroanilines Leading to Polyfunctional 1,3- and 1,4- Disubstituted Anilines" Synlett 2004, 955-958.
- 286. Yang, X.; Knochel, P.* "Preparation and Reactions of Polyfunctionalized Magnesium Arylcuprates by an I/Cu-Exchange" Synlett 2004, 81-84.
- 287. Fleming, F. F.*; Zhang, Z.; Knochel, P.* "Metalled Nitriles: Halogen-Metal Exchange with alpha-Halonitriles" Org. Lett. 2004,
- 288. Sapountzis, I.; Knochel, P.* "New General Amination Method Using the Addition of Polyfunctional Arylmagnesium Reagents to Functionalized Arylazo Tosylates" Angew. Chem. Int. Ed. 2004, 43, 897-900.
- 289. Liron, F.; Knochel, P.* "Stereoselective [2,3] Sigmatropic Rearrangement of Acyclic Allylic Phosphinites" Chem. Commun. 2004, 304-305.
- 290. Kneisel, F.F.; Dochnahl, M.; Knochel, P.* "Nucleophilic Catalysis of the Iodine-Zinc Exchange Reaction. A New Preparation of Highly Functionalized Diarylzincs" Angew. Chem. Int. Ed. 2004, 43, 1017-1021.
- 291. Bunlaksananusorn, T.; Luna, A. P.; Bonin, M.; Micouin, L.; Knochel, P.* "New Applications of Camphor-Derived P,N-Ligands for Asymmetric Pd- and Ir-Catalyzed Reactions" Synlett 2003, 2240.
- 292. Heller, B.; Sundermann, B.; Fischer, C.; You, J.; Chen, W.; Drexler, H.-J.; Knochel, P.*; Bonrath, W.; Gutnov, A. "Facile and Racemization-free Conversion of Chiral Nitriles into Pyridine Derivatives" J.Org.Chem. 2003, 68, 9221-9225.
- 293. Ragagnin, G.; Knochel, P.* "Aerobic Ru-Catalyzed Epoxidations in Fluorous Biphase System using New Fluorous Benzimidazolic Ligands" Synlett 2004, 951-954.
- 294. Calaza, M. I.; Yang, X.; Soorukram, D.; Knochel, P.* "Stereoselective SN2-Substitutions using Polyfunctional Lithium Arylcuprates Prepared by an Iodine-Copper Exchange" Org. Lett. 2004, 6, 529-531.
- 295. Duplais, C.; Bures, F.; Sapountzis, I.; Korn, T.J.; Cahiez, G.; Knochel, P.* "A New Iron-Catalyzed Arylation of Aryl Cyanides – An Efficient Preparation of Polyfunctionalized Diaryl Ketones" Angew. Chem. 2004, 43, 2968-2970.
- 296. Bunlaksananusorn, T. and Knochel, P.* "t-BuOK-Mediated Hydrophosphination of Functionalized Alkenes: A Novel Synthesis of P,N-Ligands and P,P-Ligands" J. Org. Chem. 2004, 69, 4595-4601.
- 297. Sapountzis, I.; Dube, H; Knochel, P.* "Synthesis of Nitro-Substituted Polyfunctional Biphenyls by Negishi Cross-Coupling of o-Nitroarylzinc Reagents" Adv. Synth. Catal. 2004, 346, 709-712
- 298. Yang, X..; Althammer, A.; Knochel, P.* "Selective Functionalization in Position 2 and 3 of Indoles via a Selective Iodine-Copper Exchange Reaction" Org. Lett. 2004, 6, 1665-1667
- 299. Dube, H., Gommermann, N.; Knochel, P.* "Synthesis of Chiral Aminopyrimidines Using an Enantioselective Three-Component Reaction" Synthesis 2004, 2015-2025.
- 300. Krasovskiy, A.; Knochel, P.* "A LiCl-Catalyzed Br/Mg-Exchange Reaction for the Preparation of Functionalized Aryl and Heteroaryl Magnesium Compounds" Angew. Chem. Int. Ed. 2004, 43, 3333-3336.
- 301. Varela, J.A., Pena, D., Goldfuss, B.; Denisenko, D.; Kulhanek, J.; Polborn, K.; Knochel, P.* "Diastereoselective Remote C-H Activation via Hydroboration" Chem. Eur. J. 2004, 10, 4252-4264.
- 302. Gavryushin,. A, Polborn, K.; Knochel, P.* "Novel chiral diphosphine ligands with a pinene core obtained via allylphosphinite-allylphosphine oxide rearrangement" Tetrahedron: Asymmetry 2004, 15, 2279-2288.
- 303. Soorukram, D.; Knochel, P.* "Enantioselective Synthesis of alpha-Ionone Derivatives using an Anti-SN2’-Substitution of Functionalized Zinc Organometallics" Org. Lett. 2004, 6, 2409-2411..
- 304. Sapountzis, I.; Lin, W.; Fischer, M.; Knochel, P.* "Preparation of Polyfunctional Arynes via 2-Magnesiated Aryl Arylsulfonates" Angew. Chem. Int. Ed. 2004, 43, 4364-4366.
- 305. Yang, X.; Knochel, P.* "Preparation and Acylation of Polyfunctional Copper Derivatives of 3-Iodoindazoles Leading to Polyfunctional 3-Acylindazoles" Synlett 2004, 2303-2306
- 306. Kopp, F., Krasovskiy, A.; Knochel, P.* "Convenient magnesiation of aromatic and heterocyclic rings bearing a hydroxyl group in the presence of LiCl" Chem. Commun. 2004, 2288-2289.
- 307. Gommermann, N.; Knochel, P.* "Practical Highly Enantioselective Synthesis of Terminal Propargylamines. An Expeditious Synthesis of (S)-(+)-Coniine" Chem. Commun. 2004, 2324-2325.
- 308. Sapountzis, I.; Dube, H.; Lewis, R.; Knochel, P.* "Synthesis of Functionalized Nitroarylmagnesium Halides via an Iodine-Magnesium Exchange" J. Org. Chem. 2005, 70, 2445-2454.
- 309. Ren, H., Krasovskiy, A.; Knochel, P.* "Stereoselective Preparation of Functionalized Acyclic Alkenylmagnesium Reagents Using i-PrMgCl" Org. Lett. 2004, 6, 4215-4217.
- 310. Sapountzis, I; Lin, W.; Kofink, C. C.; Despotopoulou, C.; Knochel, P.* "Iron-Catalyzed Aryl-Aryl Cross-Couplings Using Magnesium-Derived Copper Reagents" Angew. Chem. Int. Ed. 2004, 44, 1654-1657.
- 311. Kloetzing, R. J.; Knochel, P.* "Ferrocenyl-QUINAP: A Planar Chiral P,N-Ligand for Palladium-Catalyzed Allylic Substitution Reactions" Tetrahedron: Asymmetry 2005, 16, submitted
- 312. Ren, H., Krasovskiy, A.; Knochel, P.* "Preparation of Cyclic Alkenylmagnesium Reagents via an Iodine/Magnesium Exchange" Chem. Commun. 2005, 543-545.
- 313. Krasovskiy, A.; Gavryushin, A.; Knochel, P.* "A General Thiolation of Zinc and Magnesium Organometallics Using Tetramethylthiuran Disulfide" Synlett 2005, in press.
- 314. Baron, O.; Knochel, P.* "Preparation and Selective Reactions of Mixed Bimetallic Aromatic and Heterocyclic Reagents of Boron and Magnesium" Angew. Chem. Int. Ed. 2005, 44, 3133-3135.
- 315. Korn, T. J.; Knochel* "Cobalt (II)-Catalyzed Cross-Coupling Between Polyfunctional Arylcopper Reagents and Aryl Bromides or Chlorides" Angew. Chem. Int. Ed. 2005, 44, 2947-2951.
- 316. Korn, T. J.; Knochel* "A Direct Preparation of Functionalized Aryl and Heteroaryl Disulfides from Functionalized Zinc Organometallics by Using Sulfur Monochloride (S2Cl2 )" Synlett 2005, 1185-1187.
- 317. Lin, W.; Sapountzis, I; Knochel, P.* "Preparation of Functionalized Aryl Magnesium Reagents by the Addition of Magnesium Aryl Thiolates and Amides to Arynes" Angew. Chem. Int. Ed. 2005, 44, 4258-4261.
- 318. Gong, L.-Z..; Knochel, P.* "Preparation of Highly Functionalized Heterocyclic Zinc Organometallics via a Li(acac)-Catalysis of the I/Zn-Exchange Reaction" Synlett 2005, 267-270.
- 319. Leuser, H.; Perrone, S.; Liron, F.; Kneisel, F. F.; Knochel, P.* "Highly Enantioselective of Alcohols and Amines Attached to a Tertiary Center via Copper-Mediated Diastereoselective Allylic SN2´-Substitutions" Angew. Chem. Int. Ed. 2005, 44, 4627-4631.
- 320. Liu, C.-Y.; Knochel, P.* "Preparation of Polyfunctional Arylmagnesium Reagents Bearing a Triazene Moiety. A new Carbazole Synthesis" Org. Lett. 2005, 7, 2543-2546.
- 321. Fleming, F. F., Zhang, Z.; Liu, W., Knochel, P.* "Metalated Nitriles: Organolithium, -manesium, and –copper Exchange of alpha-Halonitriles" J. Org. Chem. 2005, 70, 2200-2205.
- 322. Harrington-Frost, N.; Leuser, H.; Calaza, I. M.; Kneisel, F. F.; Knochel, P.* “Highly Stereoselective Anti SN2’-Substitutions of Z-Allylic Pentafluorobenzoates with Polyfunctionalized Zinc-Copper Reagents†Org. Lett. 2003, 5, 2111-2114.
- 323. Koradin, C.; Gommermann, N.; Polborn, K.; Knochel, P.* “Synthesis of Enantiomerically Enriched Propargylamines by Copper Catalyzed Addition of Alkynes to Enamines†Chem. Eur. J. 2003, 9, 2797-2811.
- 324. Calaza, M. I.; Hupe, E.; Knochel, P* “Highly Anti-Selective SN2’-Substitution of Chiral Cyclic 2-Iodo-Allylic Alcohol Derivatives with Mixed Zinc-Copper Reagents†Org. Lett. 2003, 5, 1059-1061.
- 325. Yang, X.; Rotter, T.; Piazza, C., Knochel, P.* “Successive Iodine-Magnesium or –Copper Exchange Reactions for the Selective Functionalization of Polyhalogenated Aromatics†Org. Lett. 2003, 5, 1229-1231.
- 326. Kopp, F.; Sapountzis, I.; Knochel, P.* „ Preparation of Polyfunctional Amines by the Addition of Functionalized Organomagnesium Reagents to Nitrosoarenes“ Synlett 2003, 885-887.
- 327. Knapp, K. M.; Goldfuss, B.; Knochel, P.* „Stereoselective Synthesis of 1,4-Diols by a BH3-THF mediated Rearrangement of 1,2-Disubstituted Cyclobutenes“ Chem. Eur. J. 2003, 9, 5259-5265.
- 328. Dohle, W.; Staubitz, A.; Knochel, P.* „Mild Synthesis of Polyfunctional Benzimidazoles and Indoles by the Reduction of Functionalized Nitroarenes with Phenylmagnesium Chloride“ Chem. Eur. J. 2003, 9, 5323-5331.
- 329. Bunlaksananusorn, T.; Polborn, K.; Knochel, P.* “New P,N-Ligands for the Performance of Asymmetric Ir- and Pd- Catalyzed Reactions†Angew. Chem. Int. Ed. 2003, 42, 3941-3943.
- 330. Gommermann, N., Koradin, C.; Knochel P.* “A New Enantioselective Copper(I)-Catalyzed Three-Component Reaction for the Preparation of Propargylamines†Angew. Chem 2003, 115, 5941-5944; Angew. Chem. Int. Ed. 2003, 42, 5763-5766.
- 331. Korn, T.; Cahiez, G., Knochel P.* “New Cobalt-Catalyzed Cross-Coupling Reactions of Heterocyclic Chlorides with Aryl and Heteroaryl Magnesium Halides†Synlett 2003, 1892-1894.
- 332. Vu, V.-A.; Marek, I.; Knochel P.* “Stereoselective Preparation of Functionalized Unsaturated Lactones and Esters via Functionalized Magnesium Carbenoids†Synthesis 2003, 1797-1802.
- 333. Knochel, P.*; Hupe, E.; Houte, H. „Les composes organozinciques et organomagnesiens polyfonctionnels: De nouveaux reactifs pour la synthese de molecules organiques complexes†L’Actualité Chimique 2003, avril-mai, 12-16
- 334. Knochel, P.,* Dohle, W.; Gommermann, N.; Kneisel, F. F.; Kopp, F.; Korn, T. Sapountzis, I.; Vu, V.A. „Highly Functionalized Magnesium Organometallics Prepared via a Halogen-Magnesium Exchange“ Angew. Chem. Int. Ed. 2003, 42, 4302-4320.
- 335. Hupe, E.; Calaza, M. I.; Knochel, P.* "Synthesis and Reaction of Secondary and Primary Diorganozinc Reagents Using a Boron-Zinc Exchange. A Useful Method for the Stereoselective Formation of New Carbon-Carbon Bonds" J. Organomet. Chem. 2003, 680, 136-142.
- 336. Bunlaksananusorn, T.; Luna, A. P.; Bonin, M.; Micouin, L.; Knochel, P.* "New Applications of Camphor-Derived P,N-Ligands for Asymmetric Pd- and Ir-Catalyzed Reactions" Synlett 2003, 2240-2242.
- 337. Heller, B.; Sundermann, B.; Fischer, C.; You, J.; Chen, W.; Drexler, H.-J.; Knochel, P.*; Bonrath, W.; Gutnov, A. "Facile and Racemization-free Conversion of Chiral Nitriles into Pyridine Derivatives" J. Org. Chem. 2003, 68, 9221-9225.
- 338. Gommermann, N.; Knochel, P.* "Practical Highly Enantioselective Synthesis of Terminal Propargylamines. An Expeditious Synthesis of (S)-(+)-Coniine" Chem. Commun. 2004, 2324-2325.
- 339. Knochel, P.* "Organozinc Reagents" Science of Synthesis 2004, 3, 5-90.
- 340. Knochel, P.*; Sapountzis, I.; Gommermann, N. "Carbon-Carbon Bond-Forming Reactions Mediated by Organomagnesium Reagents" in Metal-Catalyzed Cross-Coupling Reactions (2nd Edition) 2004, 2, 671-698.
- 341. Knochel, P.*; Calaza, M. I.; Hupe, E. "Carbon-Carbon Bond-Forming Reactions Mediated by Organozinc Reagents" in Metal-Catalyzed Cross-Coupling Reactions (2nd Edition) 2004, 2, 619-670.
- 342. Tappe, K.; Knochel P.* "New Efficient Synthesis of Taniaphos-Ligands. Application in Ruthenium- and Rhodium-Catalyzed Enantioselective Hydrogenations" Tetrahedron: Asymmetry 2004, 15, 91-102.
- 343. Sapountzis, I.; Knochel, P.* "A New Method for the Selective Amination of 1,3- and 1,4-Dinitrobenzenes and Protected Nitroanilines Leading to Polyfunctional 1,3- and 1,4- Disubstituted Anilines" Synlett 2004, 955-958.
- 344. Yang, X.; Knochel, P.* "Preparation and Reactions of Polyfunctional Magnesium Arylcuprates by an I/Cu-Exchange" Synlett 2004, 81-84.
- 345. Fleming, F. F.*; Zhang, Z.; Knochel, P.* "Metallated Nitriles: Halogen-Metal Exchange with alpha-Halonitriles" Org. Lett. 2004, 6, 501-503.
- 346. Sapountzis, I.; Knochel, P.* "New General Amination Method Using the Addition of Polyfunctional Arylmagnesium Reagents to Functionalized Arylazo Tosylates" Angew. Chem. Int. Ed. 2004, 43, 897-900.
- 347. Liron, F.; Knochel, P.* "Stereoselective [2,3] Sigmatropic Rearrangement of Acyclic Allylic Phosphinites" Chem. Commun. 2004, 304-305.
- 348. Kneisel, F. F.; Dochnahl, M.; Knochel, P.* "Nucleophilic Catalysis of the Iodine-Zinc Exchange Reaction. A New Preparation of Highly Functionalized Diarylzincs" Angew. Chem. Int. Ed. 2004, 43, 1017-1021.
- 349. Ragagnin, G.; Knochel, P.* "Aerobic Ru-Catalyzed Epoxidations in Fluorous Biphase System using New Fluorous Benzimidazolic Ligands" Synlett 2004, 951-954.
- 350. Calaza, M. I.; Yang, X.; Soorukram, D.; Knochel, P.* "Stereoselective SN2-Substitutions using Polyfunctional Lithium Arylcuprates Prepared by an Iodine-Copper Exchange" Org. Lett. 2004, 6, 529-531.
- 351. Duplais, C.; Bures, F.; Sapountzis, I.; Korn, T. J.; Cahiez, G.; Knochel, P.* "A New Iron-Catalyzed Arylation of Aroyl Cyanides – An Efficient Preparation of Polyfunctionalized Diaryl Ketones" Angew. Chem.Int. Ed. 2004, 43, 2968-2970.
- 352. Bunlaksananusorn, T.; Knochel, P.* “t-BuOK-Mediated Hydrophosphination of Functionalized Alkenes: A Novel Synthesis of P,N-Ligands and P,P-Ligands†J. Org. Chem. 2004, 69, 4595-4601.
- 353. Sapountzis, I.; Dube, H; Knochel, P.* "Synthesis of Nitro-Substituted Polyfunctional Biphenyls by Negishi Cross-Coupling of o-Nitroarylzinc Reagents" Adv. Synth. Catal. 2004, 346, 709-712
- 354. Yang, X.; Althammer, A.; Knochel, P.* "Selective Functionalization in Position 2 and 3 of Indoles via a Selective Iodine-Copper Exchange Reaction" Org. Lett. 2004, 6, 1665-1667
- 355. Dube, H., Gommermann, N.; Knochel, P.* "Synthesis of Chiral Aminopyrimidines Using an Enantioselective Three-Component Reaction" Synthesis 2004, 2015-2025.
- 356. Krasovskiy, A.; Knochel, P.* "A LiCl-Catalyzed Br/Mg-Exchange Reaction for the Preparation of Functionalized Aryl and Heteroaryl Magnesium Compounds" Angew. Chem. Int. Ed. 2004, 43, 3333-3336.
- 357. Varela, J. A., Pena, D., Goldfuss, B.; Denisenko, D.; Kulhanek, J.; Polborn, K.; Knochel, P.* "Diastereoselective Remote C-H Activation via Hydroboration" Chem. Eur. J. 2004, 10, 4252-4264.
- 358. Gavryushin, A; Polborn, K.; Knochel, P.* "Novel chiral diphosphine ligands with a pinene core obtained via allylphosphinite-allylphosphine oxide rearrangement" Tetrahedron: Asymmetry 2004, 15, 2279-2288.
- 359. Soorukram, D.; Knochel, P.* "Enantioselective Synthesis of alpha-Ionone Derivatives using an Anti-SN2’-Substitution of Functionalized Zinc Organometallics" Org. Lett. 2004, 6, 2409-2411.
- 360. Sapountzis, I.; Lin, W.; Fischer, M.; Knochel, P.* "Preparation of Polyfunctional Arynes via 2-Magnesiated Aryl Arylsulfonates" Angew. Chem. Int. Ed. 2004, 43, 4364-4366.
- 361. Yang, X.; Knochel, P.* "Preparation and Acylation of Polyfunctional Copper Derivatives of 3-Iodoindazoles Leading to Polyfunctional 3-Acylindazoles" Synlett. 2004, 2303-2306
- 362. Kopp, F., Krasovskiy, A.; Knochel, P.* "Convenient Magnesiation of Aromatic and Heterocyclic Rings Bearing a Hydroxyl Group in the Presence of LiCl" Chem. Commun. 2004, 2288-2289.
- 363. Ren, H., Krasovskiy, A.; Knochel, P.* "Stereoselective Preparation of Functionalized Acyclic Alkenylmagnesium Reagents Using i-PrMgCl" Org. Lett. 2004, 6, 4215-4217.
- 364. Knochel, P.*; Yang, X.; Gommermann, N. "Polyfunctional Organocopper Reagents for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 9.
- 365. Sapountzis, I.; Lin, W.; Kofink, C. C.; Despotopoulou, C.; Knochel, P.* "Iron-Catalyzed Aryl-Aryl Cross-Couplings Using Magnesium-Derived Copper Reagents" Angew. Chem.Int. Ed. 2005, 44, 1654-1658.
- 366. Sapountzis, I.; Dube, H.; Lewis, R.; Knochel, P.* "Synthesis of Functionalized Nitroarylmagnesium Halides via an Iodine-Magnesium Exchange" J. Org. Chem. 2005, 70, 2445-2454.
- 367. Ren, H., Krasovskiy, A.; Knochel, P.* "Preparation of Cyclic Alkenylmagnesium Reagents via an Iodine/Magnesium Exchange" Chem. Commun. 2005, 543-545.
- 368. Krasovskiy, A.; Gavryushin, A.; Knochel, P.* "A General Thiolation of Zinc and Magnesium Organometallics Using Tetramethylthiuran Disulfide" Synlett 2005, 2691-2693.
- 369. Baron, O.; Knochel, P.* "Preparation and Selective Reactions of Mixed Bimetallic Aromatic and Heterocyclic Reagents of Boron and Magnesium" Angew. Chem. Int. Ed. 2005, 44, 3133-3135.
- 370. Korn, T. J.; Knochel, P.* "Cobalt (II)-Catalyzed Cross-Coupling Between Polyfunctional Arylcopper Reagents and Aryl Bromides or Chlorides" Angew. Chem. Int. Ed. 2005, 44, 2947-2951.
- 371. Korn, T. J.; Knochel, P.* "A Direct Preparation of Functionalized Aryl and Heteroaryl Disulfides from Functionalized Zinc Organometallics by Using Sulfur Monochloride (S2Cl2 )" Synlett 2005, 1185-1187.
- 372. Lin, W.; Sapountzis, I.; Knochel, P.* "Preparation of Functionalized Aryl Magnesium Reagents by the Addition of Magnesium Aryl Thiolates and Amides to Arynes" Angew. Chem. Int. Ed. 2005, 44, 4258-4261.
- 373. Gong, L.-Z.; Knochel, P.* "Preparation of Highly Functionalized Heterocyclic Zinc Organometallics via a Li(acac)-Catalysis of the I/Zn-Exchange Reaction" Synlett 2005, 267-270.
- 374. Leuser, H.; Perrone, S.; Liron, F.; Kneisel, F. F.; Knochel, P.* "Highly Enantioselective of Alcohols and Amines Attached to a Tertiary Center via Copper-Mediated Diastereoselective Allylic SN2´-Substitutions" Angew. Chem. Int. Ed. Engl. 2005, 44, 4627-4631.
- 375. Liu, C.-Y.; Knochel, P.* "Preparation of Polyfunctional Arylmagnesium Reagents Bearing a Triazene Moiety. A new Carbazole Synthesis" Org. Lett. 2005, 7, 2543-2546.
- 376. Fleming, F. F., Zhang, Z.; Liu, W., Knochel, P.* "Metalated Nitriles: Organolithium, -magnesium, and –copper Exchange of α-Halonitriles" J. Org. Chem. 2005, 70, 2200-2205.
- 377. Kneisel, F. F.; Leuser, H. Knochel, P.* "Preparation and Reactions of Highly Functionalized Bis-Arylzinc Reagents Using a Li(acac)-Catalyzed Iodine-Zinc Exchange" Synthesis 2005, 2625-2629.
- 378. Kopp, F.; Sklute, G.; Polborn, K.; Marek, I.; Knochel, P.* "Stereoselective Functionalization of Cyclopropane Derivatives Using Bromine/Magnesium and Sulfoxide/Magnesium Exchange Reactions" Org. Lett. 2005, 7, 3789-3791.
- 379. Gavryushin, A.; Kofink, C. C.; Manolikakes, G.; Knochel, P.* "Efficient Cross-Coupling of Functionalized Arylzinc Halides Catalyzed by a Nickel Chloride-Diethyl Phosphite System" Org. Lett. 2005, 7, 4871-4874.
- 380. Yasuike, S.; Kofink, C. C.; Kloetzing, R. J.; Gommermann, N.; Tappe, K.; Gavryushin, A.; Knochel, P.* "Synthesis of JOSIPHOS-type ligands via a diastereoselective three-component reaction and their application in asymmetric rhodium-catalyzed hydroboration" Tetrahedron:Asymmetry, 2005, 16, 3385-3393.
- 381. Gommermann, N.; Knochel, P.* "2-Phenylallyl as a Versatile Protecting Group for the Asymmetric One-Pot Three-Compoment Synthesis of Propargylamines" Chem. Commun. 2005, 4175-4177.
- 382. Gommermann, N.; Knochel, P.* "Preparation of functionalized primary chiral amines and amides via an enantioselective synthesis of propargylamines" Tetrahedron 2005, 61, 11418-11426.
- 383. Gommermann, N.; Knochel, P.* "Highly Enantioselective Synthesis of Propargylamines Using (Mesitylmethyl) benzylamine" Synlett 2005, 2799-2801.
- 384. Gommermann, N.; Gehrig, A.; Knochel, P.* "Enantioselective Synthesis of Chiral α-Aminoalkyl-1,2,3-triazoles Using a Three-Component Reaction" Synlett 2005, 2796-2798
- 385. Knochel, P.*; Krasovskiy, A.; Sapountzis, I. "Polyfunctional Magnesium Organometallics for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 4.
- 386. Knochel, P.*; Leuser, H.; Gong, L.-Z.; Perrone, S.; Kneisel, F. F. "Polyfunctional Zinc Organometalics for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 7.
- 387. Gommermann, N.; Knochel, P.* "Practical Highly Enantioselective Synthesis of Propargylamines via a Copper-Catalyzed One-Pot Three-Component Condensation Reaction" Chem. Eur. J. 2006, 12, 4380-4392.
- 388. Krasovskiy, A.; Straub, B.*; Knochel, P.* "Highly Efficient Reagents for the Br/Mg Exchange. Mechanisms, Preparation and Synthetic Applications" Angew. Chem. Int. Ed. 2006, 45, 159-162.
- 389. Stoll, A. H.; Krasovskiy, A.; Knochel, P.* "Preparation of Functionalized Benzylic Magnesium Reagents Using a New Sulfur-Magnesium Exchange Reaction" Angew. Chem. Int.Ed. 2006, 45, 606-609.
- 390. Krasovskiy, A.; Gavryushin, A.; Knochel, P.* "Higly stereoselective access to sulfur derivatives starting from zinc organometallics" Synlett, 2006, 792-794.
- 391. Krasovskiy, A.; Knochel, P.* "Convenient titration method of organometallic zinc, magnesium, and lanthanide reagents" Synthesis, 2006, 890-891.
- 392. Lin, W.; Ilgen, F.; Knochel, P.* "Preparation of highly functionalized arylmagnesium readents by the addition of magnesium phenyl selenide to arynes" Tetrahedron Lett., 2006, 47, 1941-1944.
- 393. Dunet, G.; Knochel, P.* "Iron- catalyzed cross-coupling between alkenyl and dienyl sulfonates and functionalized arylcooper reagents" Synlett, 2006, 407-410.
- 394. Kloetzing, R. J.; Thaler, T.; Knochel, P.* "Am improved Asymmetric Reformatsky Reaction Mediated by (-)-N,N-Dimethylaminoisoborneol" Org. Lett. 2006, 8, 1125-1128.
- 395. Ila, H.; Baron, O.; Wagner, A. J.; Knochel, P.* "Functionalized magnesium organometallics as versatile intermediates for the synthesis of polyfunctional heterocycles" Chem. Commun., 2006, 583-593.
- 396. Liu, C.-Y.; Ren; H.; Knochel, P.* "Magnesiated Unsaturated Silylated Cyanohygrins as Synthetic Equivalents of Aromatic and Heterocyclic Grignard Reagents Bearing a Ketone or a Aldehyde" Org. Lett. 2006, 8, 617-619.
- 397. Kloetzing, R.; Knochel, P.* "Ferrocenyl-QUINAP: a planar chiral P,N-ligand for palladium-catalized allylic substitution reactions" Tetrahedron: Asymmetry, 2006, 17, 116-123.
- 398. Ila, H.; Baron, O.; Wagner, A. J.; Knochel, P.* "Preparation and reactions of heteroaryl organomagnesium compounds" Chem. Lett., 2006, 35, 2-7.
- 399. Korn, T. J.; Schade, M. A.; Wirth, S.; Knochel, P.* "Cobalt (II)-Catalyzed Cross-Coupling between Polyfunctional Arylcopper Reagents and Aryl Fluorides or Tosylates" Org. Lett., 2006, 8, 725-728.
- 400. Krasovskiy, A.; Kopp, F.; Knochel, P.* "New Soluble Lanthanide Salts (LnCl3.2LiCl; Ln = La, Ce, Nd) for the improved Addition of Magnesium Organometallics to Carbonyl Derivatives" Angew. Chem. Int. Ed. Engl. 2006, 45, 497-500.
- 401. Ren, H.; Knochel, P.* “Regioselective Functionalization of Trisubstituted Pyridines Using a Bromine-Magnesium Exchange” Chem. Comm. 2006, 726-728.
- 402. Krasovskiy, A.; Krasovskaya, V.; Knochel, P.* „Mixed Mg/Li amides of the type R2NMgCl . LiCl as highly efficient bases for the regioselective generation of functionalized aryl and heteroaryl magnesium compounds” Angew. Chem. Int. Ed. Engl. 2006, 45, 2958-2961.
- 403. Yang, X.; Knochel, P.* „Selective functionalization of imidazoles via an iodine-copper exchange reaction” Chem. Comm. 2006, 2170-2172.
- 404. Boudet, N.; Knochel, P.* “Chemo- and Regioselective Functionalization of Uracil Derivatives. Applications to the Synthesis of Oxypurinol and Emivirine” Org. Lett. 2006, 8, 3737-3740.
- 405. Yang, X., Knochel, P.* “Stereoselective Preparation of Higly Functionalized (Z)-3-Copper Enoates by an Iodine-Copper Exchange Reaction” Synthesis 2006, 2167-2172.
- 406. Yang, X., Knochel, P.* “Direct Preparation of Copper organometallics Bearing an Aldehyde Function via an Iodine-Copper Exchange” Chem. Comm. 2006, 2486-2488.
- 407. Yang, X., Knochel, P.* “Preparation and Reactions of Functionalized Organocopper Reagents” Synthesis, 2006, 2618-2623.
- 408. Yang, X.; Knochel, P.* “Stereoselective Functionalization of β-iodo-ά,β-Unsaturated Ketones via an Iodine-Copper Exchange Reaction” Org. Lett. 2006, 8, 1941-1943.
- 409. Kofink, C. C.; Knochel, P.* “Synthesis of Functionalized Diarylmethanes via a Copper-Catalyzed Cross-Coupling of Arylmagnesium Reagents with Benzylic Phosphates” Org. Lett. 2006, 8, 4121-4124.
- 410. Sinha, P.; Kofink, C. C.; Knochel, P.* “Preparation of Aryl-Alkylamines via Electrophilic Amination of Functionalized Arylazo Tosylates with Alkylzinc Reagents” Org. Lett. 2006, 8, 3741-3744.
- 411. Krasovskiy, A.; Malakhov, V.; Gavryushin, A.; Knochel, P.* “Efficient Synthesis of Functionalized Organozinc Compounds by the Direct Insertion of Zinc into Organic Iodides and Bromides” Angew. Chem. Int. Ed. Engl. 2006, 45, 6040-6044.
- 412. Krasovskiy, A.; Tishkov, A.; del Amo, V.; Mayr, H.; Knochel, P.* “Transition-metal-free homocoupling of organomagnesium compounds” Angew. Chem. Int. Ed. Engl. 2006, 45, 5010-5014.
- 413. Gavryushin, A.; Kofink, C. C.; Manolikakes, G.; Knochel, P.* “An Efficient Negishi Cross-Coupling Reaction Catalyzed by Nickel(II) and Diethyl Phosphite” Tetrahedron 2006, 62, 7521-7533.
- 414. Soorukram, D.; Knochel, P.* “Copper-catalyzed Preparation of Ketones bearing a stereogenic center in α-position” Angew. Chem. Int. Ed. Engl. 2006, 45, 3686-3689.
- 415. Ren, H.; Knochel, P.* “Chemoselective Benzylic C-H Activations for the Preparation of Condenced N-heterocycles” Angew. Chem. Int. Ed. Engl. 2006, 45, 3462-3465.
- 416. Lin, W.; Baron, O.; Knochel, P.* “Highly Functionalized Benzene Syntheses by Directed Mono or Multiple Magnesiations with TMPMgCl.LiCl” Org. Lett. 2006, 8, 5673-5676.
- 417. Sinha, P., Knochel, P.* “Preparation of Polyfunctional Tertiary Amines via the Electrophilic Amination of Arylmagnesium Compounds Using N-Chloroamines” Synlett 2006, 3304-3308.
- 418. Del Amo, V.; Dubbaka, S. R.; Krasovskiy, A.; Knochel, P.* “General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates” Angew. Chem. Int. Ed. Engl. 2006, 45, 7838-7842.
- 419. 419. Korn, T. J.; Schade, M. A.; Cheemala, M. N.; Wirth, S.; Guevara, S. A.; Cahiez, G.; Knochel, Paul. “Cobalt-catalyzed cross-coupling reactions of heterocyclic chlorides with arylmagnesium halides and of polyfunctionalized arylcopper reagents with aryl bromides, chlorides, fluorides and tosylates.” Synthesis 2006, 3547-3574.
- 419-1. Knochel, P.*; Leuser, H.; Gong, L.-Z.; Perrone, S.; Kneisel, F. F. “Functionalized organozinc compounds” in Chemistry of Organozinc Compounds, Wiley Int. 2006, Pt. 1, 287-393, ISBN: 978-0-470-09337-5.
- 420. Krasnokutskaya, E. A.; Semenischeva, N. I.; Filimonov, V. D.; Knochel, P.* "A New, One-Step, Effective Protokol for the Iodination of Aromatic and Heterocyclic Compounds via Aprotic Diazotization of Amines" Synthesis, 2007, 81-84.
- 421. Soorukram, D.; Knochel, P.* “Formal Enantioselective Synthesis of (+)-Estrone” Org. Lett., 2007, 9, 1021-1023.
- 422. Soorukram, D.; Knochel, P.* “A Practical Synthesis of Optically Active α-Substituted Ketones in High Enantiomeric Excess” Synthesis 2007, 638-641.
- 423. Lin, W.; Chen, L.; Knochel, P.* “Preparation of functionalized 3,4-pyridynes via 2-magnesiated diaryl sulfonates” Tetrahedron 2007, 63, 2787-2797.
- 424. Ren, H.; Li, Z.; Knochel, P.* “Chemoselective C(sp3)-H Bond Activation for the Preparation of Condensed N-Heterocycles” Chem. Asian J. 2007, 2, 416-433.
- 425. Perrone, S.; Knochel, P.* “Highly Diastereoselective Preparation of (E)-Alkenylsilanes Bearing an α-Chiral Center.” Org. Lett. 2007, 9, 1041-1044.
- 426. Ren, H.; Dunet, G.; Mayer, P.; Knochel, P.* "Highly Diastereoselective Synthesis of Homoallylic Alcohols Bearing Adjacent Quaternary Centers Using Substituted Allylic Zinc Reagents" J. Am. Chem. Soc. 2007, 129, 5376-5377.
- 427. Kopp, F.; Knochel, P.* "Iodine-Magnesium Exchange on Unprotected Imidazoles in the Presence of LiCl" Synlett 2007, 0980-0982.
- 428. Kienle, M.; Dubbaka, S. R.; del Amo, V.; Knochel, P.* “Preparation of Tertiary Amines via the Oxidative Coupling Of Polyfunctional Aryl and Heteroaryl Amidocuprates" Synthesis 2007, 1272-1278.
- 429. Perrone, S.; Metzger, A.; Knochel, P.* "Chiral Allylic Cyanohydrins as Versatile Substrates for Diastereoselective Copper(I)-mediated SN2' Allylic Substitutions" Synlett 2007, 1047-1050.
- 430. Kopp, F.; Knochel, P.* "Functionalisation of Unprotected Uracil Derivatives Using the Halogen-Magnesium Exchange" Org. Lett. 2007, 9, 1639-1641.
- 431. Kopp, F.; Wunderlich, S.; Knochel, P.* "Halogen-magnesium exchange on unprotected aromatic and heteroaromatic carboxylic acids" Chem. Comm. 2007, 2075-2077.
- 432. Dunet, G.; Knochel, P.* "Highly Stereoselective Cobalt-Catalyzed Allylation of Functionalized Diarylzinc Reagents” Synlett 2007, 1383-1386.
- 433. Liron, F.; Knochel, P.* "Reactivity of stable neopentyl-Pd intermediates in the absence of nucleophile" Tetrahedron Lett. 2007, 48, 4943-4946.
- 434. Cheemala, M. N.; Knochel, P.* "New P,N-Ferrocenyl Ligands for the Asymmetric Ir-Catalyzed Hydrogenation of Imines" Org. Lett. 2007, 9, 3089-3092.
- 435. Kofink, C. C.; Blank, B.; Pagano, S.; Goetz, N.; Knochel, P.* "Iron-catalyzed aryl-aryl cross-coupling reaction tolerating amides and unprotected quinolinones" Chem. Comm. 2007, 1954-1956.
- 436. Liu, C.-Y.; Knochel, P.* „Preparation of Polyfunctional Aryl Triazenes via a Direct Insertion Reaction of Zn in the Presence of LiCl” Synlett 2007, 2081-2085.
- 437. Manolikakes, G.; Dastbaravardeh, N.; Knochel, P.* „Nickel-Catalyzed Cross-Coupling Reactions of Aryltitanium(IV) Alkoxides with Aryl Halides” Synlett 2007, 2077-2080.
- 438. Liu, C.-Y.; Gavryushin, A.; Knochel, P.* „Synthesis of functionalized o-, m-, and p-terphenyl derivatives by consecutive cross-coupling reactions of triazene-substituted arylboronic esters.” Chem. Asian J. 2007, 2, 1020-1030.
- 439. Liu, C.-Y.; Knochel, P.* „Preparation of Polyfunctional Aryl Azides from Aryl Triazenes. A New Synthesis of Ellipticine, 9-Methoxyellipticine, Isoellipticine, and 7-Carbethoxyisoellipticine” J. Org. Chem. 2007, 72, 7106-7115.
- 440. Wunderlich, S. H.; Knochel, P.* “(tmp)2Zn•2MgCl2•2LiCl: a chemoselective base for the directed zincation of sensitive arenes and heteroarenes” Angew. Chem. Int. Ed. 2007, 46, 7685-7688.
- 441. Clososki, G. C.; Rohbogner, C. J.; Knochel, P.* “Direct magnesiation of polyfunctionalized arenes and heteroarenes using (tmp)2Mg•2LiCl” Angew. Chem. Int. Ed. 2007, 46, 7681-7684.
- 442. Gommermann, N.; Knochel, P.* “N,N-Dibenzyl-N-[1-cyclohexyl-3-(trimethylsilyl)-2-propynyl]-amine from cyclohexanecarbaldehyde, trimethylsilylacetylene and dibenzylamine” Org. Synth. 2007, 84, 1-10.
- 443. Fleming, F. F.; Gudipati, S.; Vu, V. A.; Mycka, R. J.; Knochel, P.* “Grignard Reagents: Alkoxide-Directed Iodine-Magnesium Exchange at sp3 Centers” Org. Lett. 2007, 9, 4507-4509.
- 444. Boudet, N.; Sase, S.; Sinha, P.; Liu, C.-Y.; Krasovskiy, A.; Knochel, P.* “Directed Ortho Insertion (DoI): A New Approach to Functionalized Aryl and Heteroaryl Zinc Reagents” J. Am. Chem. Soc. 2007, 129, 12358-12359.
- 445. Kienle, M.; Dubbaka, S. R.; Brade, K.; Knochel, P.* “Modern amination reactions” Eur. J. Org. Chem. 2007, 25, 4166-4176.
- 446. Thaler, T.; Geittner, F.; Knochel, P.* „A Novel Synthetic Approach towards Chiral QUINAP via Diastereometric Sulfoxide Intermediates” Synlett 2007, 2655-2658.
- 447. Melzig, L.; Gavryushin, A.; Knochel, P.* „Direct Aminoalkylation of Arenes and Hetarenes via Ni-Catalyzed Negishi Cross-Coupling Reactions” Org. Lett. 2007, 9, 5529-5532.
- 448. Soorukram, D.; Boudet, N.; Malakhov, V.; Knochel, P.* “Preparation of polyfunctionalized 2,6-dimethoxypyrimidine derivatives via chemo- and regioselective direct zinc insertion” Synthesis 2007, 3915-3922.
- 449. Cheemala, M. N.; Gayral, M.; Brown, J. M.; Rossen, K.; Knochel, P.* “New paracyclophane phosphine for highly enantioselective ruthenium-catalyzed hydrogenation of prochiral ketones” Synthesis 2007, 3877-3885.
- 450. Kolodney, G.; Sklute, G.; Perrone, S.; Knochel, P.*; Marek, I. “Diastereodivergent synthesis of enantiomerically pure homoallylic amine derivatives containing quaternary carbon stereocenters” Angew. Chem. Int. Ed. 2007, 46, 9291-9294.
- 451. Dubbaka, S. R.; Kienle, M.; Mayr, H.; Knochel, P.* “Copper (I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and Aryl magnesium reagents” Angew. Chem. Int. Ed. 2007, 46, 9093-9096.
- 452. Boudet, N.; Lachs, J. R.; Knochel, P.* “Multiple Regioselective Functionalizations of Quinolines via Magnesiations” Org. Lett. 2007, 9, 5525-5528.
- 453. Stoll, A. H.; Mayer, P.; Knochel, P.* “Preparation of Di-, Tri-, and Tetra-Substituted Functionalized Ferrocenes via Magnesium Organometallics” Organometallics 2007, 26, 6694-6697.
- 454. Shi, L.; Chu, Y.; Knochel, P.*; Mayr, H. “Relative rates of bromine-magnesium exchange reactions in substituted bromobenzene derivatives” Angew. Chem. Int. Ed. 2008, 47, 202-204.
- 455. Stoll, A. H.; Knochel, P.* “Preparation of Fully Substituted Anilines for the Synthesis of Functionalized Indoles” Org. Lett. 2008, 10, 113-116.
- 456. Manolikakes, G.; Gavryushin, A.; Knochel, P.* “An Efficient Silane-Promoted Nickel-Catalyzed Amination of Aryl and Heteroaryl Chlorides” J. Org. Chem. 2008, 73, 1429-1434.
- 457. Dunet, G.; Mayer, P.; Knochel, P.* “Highly Diastereoselective Addition of Cinnamylzinc Derivatives to α-Chiral Carbonyl Compounds” Org. Lett. 2008, 10, 117-120.
- 458. Abu Thaher, B.; Koch, P.; del Amo, V.; Knochel, P.; Laufer, S.* „A Convenient Synthesis of 1-(4-Fluorophenyl)-2-(4-pyridyl)cyclopentene from Cyclopentanone” Synthesis 2008, 225-228.
- 459. Druzhinin, S. I.; Dubbaka, S. R.; Knochel, P.*; Kovalenko, S. A.; Mayer, P.; Senyushkina, T.; Zachariasse, K. A. “Ultrafast Intramolecular Charge Transfer with Strongly Twisted Aminobenzonitriles: 4-(Di-tert-butylamino) benzonitrile and 3-(Di-tert-butylamino) benzonitrile” J. Phys. Chem. A 2008, 112, 2749-2761.
- 460. Rohbogner, C. J.; Clososki, G.; Knochel, P.* “A general method for meta- and para- functionalization of arenes using TMP2Mg • 2 LiCl” Angew. Chem. Int. Ed. 2008, 47, 1503-1507.
- 461. Metzger, A.; Schade, M. A.; Knochel, P.* “LiCl-Mediated Preparation of Highly Functionalized Benzylic Zinc Chlorides” Org. Lett. 2008, 10, 1107-1110.
- 462. Rauhut, C. B.; Vu, V. A.; Fleming, F. F.; Knochel, P.* “Preparation of Functionalized Alkylmagnesium Derivatives Using an I/Mg-Exchange” Org. Lett. 2008, 10, 1187-1189.
- 463. Ireland, T.; Tappe, K.; Grossheimann, G.; Knochel, P.* “Synthesis of a new class of chiral 1,5-diphosphanylferrocenyl ligands and their use in enantioselective hydrogenation” Chem. Eur. J. 2008, 14, 3509.
- 464. Tappe, K.; Knochel P.* “New Efficient Synthesis of Taniaphos-Ligands. Application in Ruthenium- and Rhodium-Catalyzed Enantioselective Hydrogenations” [Tetrahedron: Asymmetry 2004, 15, 91-102] Tetrahedron: Asymmetry 2008, 19, 891.
- 465. Despotopoulou, C.; Bauer, R. C.; Krasovskiy, A.; Mayer, P.; Stryker, J. M.; Knochel, P.* “Selective mono- and 1,2-difunctionalisation of cyclopentene derivatives via Mg and Cu intermediates” Chem. Eur. J. 2008, 14, 2499-2506.
- 466. Helm, M. D.; Mayer, P.; Knochel, P.* “Preparation of silyl substituted crotylzinc reagents and their highly diastereoselective addition to carbonyl compounds” Chem. Comm. 2008, 1916-1917.
- 467. Boudet, N.; Dubbaka, S. R.; Knochel, P.* “Oxidative Amination of Cuprated Pyrimidine and Purine Derivatives” Org. Lett. 2008, 10, 1715-1718.
- 468. Schade, M. A.; Metzger, A.; Hug, S.; Knochel, P.* “Nickel-catalyzed cross-coupling reactions of benzylic zinc reagents with aromatic bromides, chlorides and tosylates” Chem. Comm. 2008, 3046-3048.
- 469. Manolikakes, G.; Schade, M. A.; Munoz Hernandez, C.; Mayr, H.; Knochel, P.* “Negishi Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Hydrogen Atoms with Organozinc Reagents” Org. Lett. 2008, 10, 2765-2768.
- 470. Ireland, T; Grossheimann, G; Wieser-Jeunesse, C; Knochel, P.* “Ferrocenyl ligands with two phosphanyl substituents in the , positions for the transition metal catalyzed asymmetric hydrogenation of functionalized double bonds” [Erratum to document cited in CA132:122132]. Angew. Chem. Int. Ed. 2008, 47, 3666.
- 471. Piller, F. M.; Appukkuttan, P.; Gavryushin, A.; Helm, M.; Knochel, P.* „Convenient Preparation of Polyfunctional Aryl Magnesium Reagents by a Direct Magnesium Insertion in the Presence of LiCl” Angew. Chem. Int. Ed. 2008, 47, 6802-6806.
- 472. Mosrin, M.; Knochel, P.* „Regio- and Chemoselective Multiple Functionalization of Pyrimidine Derivatives by Selective Magnesiations using TMPMgCl LiCl” Org. Lett. 2008, 10, 2497-2500.
- 473. Sase, S.; Jaric, M.; Metzger, A.; Malakhov, V.; Knochel, P.* “One-Pot Negishi Cross-Coupling Reactions of In Situ Generated Zinc Reagents with Aryl Chlorides, Bromides, and Triflates” J. Org. Chem. 2008, 73, 7380-7382.
- 474. Rauhut, C. B.; Melzig, L.; Knochel, P.* „Meta- and Para-Difunctionalization of Arenes via a Sulfoxide-Magnesium Exchange Reaction” Org. Lett. 2008, 10, 3891-3894.
- 475. Metzger, A.; Schade, M. A.; Manolikakes, G.; Knochel, P.* “A General Preparation of Polyfunctional Benzylic Zinc Organometallic Compounds” Chem. Asian J. 2008, 3, 1678-1691.
- 476. Manolikakes, G.; Munoz Hernandez, C.; Schade, M. A.; Metzger, A.; Knochel, P.* “Palladium- and Nickel-Catalyzed Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Protons with Organozinc Reagents” J. Org. Chem. 2008, 73, 8422-8436.
- 477. Wunderlich, S.; Knochel, P.* “High Temperature Metalation of Functionalized Aromatics and Heteroaromatics using (tmp)2Zn 2MgCl2 2LiCl and Microwave Irradiation” Org. Lett. 2008, 10, 4705-4707.
- 478. Mosrin, M.; Boudet, N.; Knochel, P.* “Regio- and chemoselective magnesiation of protected uracils and thiouracils using TMPMgCl LiCl and TMP2Mg 2LiCl” Org. Biomol. Chem. 2008, 6, 3237-3239.
- 479. Chen, Y.-H.; Knochel, P.* “Preparation of Aryl and heteroaryl indium(III) reagents by the direct insertion of indium in the presence of LiCl” Angew. Chem. Int. Ed. 2008, 47, 7648-7651.
- 480. Metzger, A.; Piller, F. M.; Knochel, P.* “Polyfunctional benzylic zinc chlorides by the direct insertion of magnesium into benzylic chlorides in the presence of LiCl and ZnCl2” Chem. Comm. 2008, 5824-5826.
- 481. Mosrin, M.; Petrera, M.; Knochel, P.* “Multiple Regio- and Chemoselective Functionalizations of Pyrimidine Derivatives Using TMPMgCl•LiCl and TMP2Mg•2LiCl” Synthesis 2008, 3697-3702.
- 482. Wunderlich, S. H.; Knochel, P.* “Efficient mono- and bis-functionalization of 3,6-dichloropyridazine using (tmp)2Zn 2MgCl2 2LiCl“ Chem. Comm. 2008, 6387-6389.
- 483. Rauhut, C. B.; Cervino, C.; Krasovskiy, A.; Knochel, P.* “Stereoselective Preparation of Cyclopropylmagnesium Reagents via a Br-Mg Exchange Using i-PrMgCl•LiCl in the Presence of Dioxane” Synlett 2009, 67-70.
- 484. Piller, F. M.; Knochel, P.* “Regio- and Chemoselective Synthesis of Fully Substituted Thiophenes” Org. Lett. 2009, 11, 445-448.
- 485. Wunderlich, S H.; Knochel, P.* “Aluminum bases for the highly chemoselective preparation of aryl and heteroaryl aluminum compounds” Angew. Chem. Int. Ed. 2009, 48, 1501-1504.
- 486. Mosrin, M.; Knochel, P.* “Regio- and chemoselective metalation of chloropyrimidine derivatives with TMPMgCl LiCl and TMP2Zn 2MgCl2 2LiCl” Chem. Eur. J. 2009, 15, 1468-1477.
- 487. Manolikakes, G.; Dong, Z.; Mayr, H.; Li, J.; Knochel, P.* “Negishi cross-couplings compatible with unprotected amide functions” Chem. Eur. J. 2009, 15, 1324-1328.
- 488. Manolikakes, G.; Knochel, P.* “Radical catalysis of Kumada cross-coupling reactions using functionalized Grignard reagents” Angew. Chem. Int. Ed. 2009, 48, 205-209.
- 489. Thaler, T.; Knochel, P.* “Copper-catalyzed asymmetric Michael addition of magnesium, zinc, and aluminum organometallic reagents: efficient synthesis of chiral molecules” Angew. Chem. Int. Ed. 2009, 48, 645-648.
- 490. Dong, Z.; Clososki, G. C.; Wunderlich, S. H.; Unsinn, A.; Li, J.; Knochel, P.* “Direct zincation of functionalized aromatics and heterocycles by using a magnesium base in the presence of ZnCl2” Chem. Eur. J. 2009, 15, 457-468.
- 491. Dong, Z.; Manolikakes, G.; Li, J.; Knochel, P.* „Palladium-Catalyzed Cross-Couplings of Unsaturated Halides Bearing Relatively Acidic Hydrogen Atoms with Organozinc Reagents” Synthesis 2009, 681-686.
- 492. Melzig, L.; Rauhut, C. B.; Knochel, P.* „Meta- and Para-Difunctionalization of Arenes via an Ortho-Magnesiation and a Subsequent Sulfoxide-Magnesium Exchange” Synthesis 2009, 1041-1048.
- 493. Mosrin, M.; Knochel, P.* „TMPZnCl LiCl: A New Active Selective Base for the Directed Zincation of Sensitive Aromatics and Heteroaromatics” Org. Lett. 2009, 11, 1837-1840.
- 494. Shi, L.; Chu, Y.; Knochel, P.*; Mayr, H. „Kinetics of Bromine-Magnesium Exchange Reactions in Substituted Bromobenzenes” J. Org. Chem. 2009, 74, 2760-2764.
- 495. Rohbogner, C. J.; Wunderlich, S. H.; Clososki, G. C.; Knochel, P.* “New mixed Li/Mg and Li/Mg/Zn amides for the chemoselective metallation of arenes and heteroarenes” Eur. J. Org. Chem. 2009, 1781-1795.
- 496. Chen, Y.-H.; Sun, M.; Knochel, P.* “LiCl-mediated preparation of functionalized benzylic indium(III) halides and highly chemoselective palladium-catalyzed cross-coupling in a protic cosolvent” Angew. Chem. Int. Ed. 2009, 48, 2236-2239.
- 497. Wunderlich, S. H.; Knochel, P.* “Aluminum bases for the highly chemoselective preparation of aryl and heteroaryl aluminum compounds” Angew. Chem. Int. Ed. 2009, 48, 1501-1504.
- 498. Metzger, A.; Gavryushin, A.; Knochel, P.* “LaCl3 2LiCl-catalyzed addition of Grignard reagents to ketones” Synlett 2009, 1433-1436.
- 499. Melzig, L.; Rauhut, C B.; Knochel, P.* “2,3-Functionalization of furans, benzofurans and thiophenes via magnesiation and sulfoxide-magnesium exchange” Chem. Comm. 2009, 24, 3536-3538.
- 500. Gao, H.; Knochel, P.* “New preparation and reactions of arylaluminum reagents using barbier conditions” Synlett, 2009, 1321-1325.
- 501. Despotopoulou, C.; Klier, L.; Knochel, P.* “Synthesis of Fully Substituted Pyrazoles via Regio- and Chemoselective Metalations” Org. Lett. 2009, 11, 3326-3329.
- 502. Mosrin, M.; Bresser, T.; Knochel, P.* “Regio- and Chemoselective Multiple Functionalization of Chloropyrazine Derivatives. Application to the Synthesis of Coelenterazine” Org. Lett. 2009, 11, 3406-3409.
- 503. Shi, L.; Chu, Y.; Knochel, P.*; Mayr, H. “Kinetics of Bromine-Magnesium Exchange Reactions in Heteroaryl Bromides” Org. Lett. 2009, 11, 3502-3505.
- 504. Piller, F. M.; Metzger, A.; Schade, M. A.; Haag, B. A.; Gavryushin, A.; Knochel, P.* „Preparation of Polyfunctional Arylmagnesium, Arylzinc, and Benzylic Zinc Reagents by Using Magnesium in the Presence of LiCl” Chem. Eur. J. 2009, 15, 7192-7202.
- 505. Metzger, A.; Melzig, L.; Despotopoulou, C.; Knochel, P.* „Pd-Catalyzed Cross-Coupling of Functionalized Organozinc Reagents with Thiomethyl-Substituted Heterocycles” Org. Lett. 2009, 11, 4228-4231.
- 506. Haag, B.; Peng, Z.; Knochel, P.* “Preparation of Polyfunctional Indazoles and Heteroarylazo Compounds Using Highly Functionalized Zinc Reagents” Org. Lett. 2009, 11, 4270-4273.
- 507. Thaler, T.; Ren, H.; Gommermann, N.; Clososki, G.; C.; Rohbogner, C. J.; Wunderlich, S. H.; Knochel, P.* “New catalytic Cu-, Pd- and stoichiometric Mg-, Zn-mediated bond activations” Activating Unreactive Substrates (Monograph), 2009, 359-377.
- 508. Mosrin, M.; Monzon, G.; Bresser, T.; Knochel, P.* “High temperature zincation of functionalized aromatics and heteroaromatics using TMPZnCl? LiCl and microwave irradiation” Chem. Comm., 2009, 37, 5615-5617.
- 509. Wunderlich, S. H.; Kienle, M.; Knochel, P. „Directed Manganation of Functionalized Arenes and Heterocycles Using tmp2Mn? 2 MgCl2? 4 LiCl” Angew. Chem. Int. Ed. 2009, 48, 7256-7260.
- 510. Kienle, M.; Dunst, C.; Knochel, P.* „Oxidative Amination of Heteroaromatic Zinc Reagents Mediated by PhI(OAc)2” Org. Lett. 2009, 11, 5158-5161.
- 511. Despotopoulou, C.; Gignoux, C.; McConnell, D.; Knochel, P.* “Functionalization of 4,5-Dihydrobenzo[g]indazoles Using Magnesium- or Zinc-Heterocyclic Intermediates” Synthesis 2009, 3661-3671.
- 512. Knochel, P. “A flash of magnesium” Nature Chemistry 2009, 1, 740.
- 513. Gommermann, N.; Knochel, P.*; Rech, J. C.; Ellman, J. A. „N,N-Dibenzyl-N-[1-cyclohexyl-3-(trimethylsilyl)-2-propynyl]amine from cyclohexanecarbaldehyde, trimethylsilylacetylene and dibenzylamine” Org. Syntheses 2009, Collective (Vol. 11), 189-196.
- 514. Wunderlich, S. H.; Knochel, P*. „Preparation of Functionalized Aryl Iron(II) Compounds and a Nickel-Catalyzed Cross-Coupling with Alkyl Halides” Angew. Chem. Int. Ed. 2009, 48, 9717-9720.
- 515. Rohbogner, C. J.; Wagner, A. J.; Clososki, G. C.; Knochel, P.* “Magnesiation of weakly activated arenes using tmp2Mg? 2LiCl: synthesis of tert-butyl ethyl phthalate” Org. Synth. 2009, 86 374-384.
- 516. Dong, Z.-B.; Manolikakes, G.; Shi, L.; Knochel, P.*; Mayr, H. “Structure-Reactivity Relationships in Negishi Cross-Coupling Reactions” Chem. Eur. J. 2010, 16, 248-253.
- 517. Thaler, T.; Haag, B.; Gavryushin, A.; Schober, K.; Hartmann, E.; Gschwind, R. M.; Zipse, H.; Mayer, P.; Knochel, P.* “Highly diastereoselective Csp3-Csp2 Negishi cross-coupling with 1,2-, 1,3- and 1,4-substituted cycloalkylzinc compounds” Nature Chemistry 2010, 2, 125-130.
- 518. Wunderlich, S. H.; Rohbogner, C. J.; Unsinn, A.; Knochel, P.* “Scaleable Preparation of Functionalized Organometallics via Directed Ortho Metalation Using Mg- and Zn-Amide Bases” Org. Process Res. Dev. 2010, 14, 339-345.
- 519. Monzon, G.; Knochel, P.* “Directed ortho- and meta-magnesiation or zincation of polyfunctional aryl nonaflates” Synlett 2010, 304-308.
- 520. Melzig, L.; Metzger, A.; Knochel, P.* „Room Temperature Cross-Coupling of Highly Functionalized Organozinc Reagents with Thiomethylated N-Heterocycles by Nickel Catalysis” J. Org. Chem. 2010, 75, 2131-2133.
- 521. Rohbogner, C. J.; Diene, C. R.; Korn, T. J.; Knochel, P.* „A Cobalt-Catalyzed Sulfonate/Copper Exchange for the Preparation of Highly Functionalized Electron-Deficient Aryl Copper Reagents” Angew. Chem. Int. Ed. 2010, 49, 1874-1877.
- 522. Wunderlich, S. H.; Knochel, P.* „Atom-Economical Preparation of Aryl- and Heteroaryl-Lanthanum Reagents by Directed ortho-Metalation by Using tmp3[La]” Chem. Eur. J. 2010, 16, 3304-3307.
- 523. Bluemke, T.; Chen, Y.-H.; Peng, Z.; Knochel, P.* „Preparation of functionalized organoaluminiums by direct insertion of aluminium to unsaturated halides” Nature Chemistry 2010, 2, 313-318.
- 524. Crestey F.; Knochel, P.* “Regioselective Functionalization of Chlorophthalazine Derivatives” Synthesis 2010, 1097-1106.
- 525. Yamada, S.; Gavryushin, A.; Knochel, P.* „Convenient Electrophilic Fluorination of Functionalized Aryl and Heteroaryl Magnesium Reagents” Angew. Chem. Int. Ed. 2010, 49, 2215-2218.
- 526. Metzger, A.; Argyo, C.; Knochel, P.* “Large-scale preparation of polyfunctional benzylic zinc reagents by direct insertion of zinc dust into benzylic chlorides in the presence of lithium chloride” Synthesis 2010, 882-891.
- 527. Rohbogner, C. J.; Wirth, S.; Knochel, * “Phosphorodiamidate-Directed Metalation of N-Heterocycles using Mg- and Zn-TMP Bases” Org. Lett. 2010, 12, 1984-1987.
- 528. Kienle, M.; Knochel, P.* “i-PrI Acceleration of Negishi Cross-Coupling Reactions” Org. Lett. 2010, 12, 2702-2705.
- 529. Bluemke, T. D.; Piller, F. M.; Knochel, P.* “Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl2 and LiCl” Chem. Comm., 2010, 46, 4082-4084.
- 530. Wunderlich, S. H.; Kienle, M.; Knochel, P.* “Corrigendum: Directed Manganation of Functionalized Arenes and Heterocycles Using tmp2Mn? 2 MgCl2 ? 4 LiCl” Angew. Chem. Int. Ed. 2010, 49, 4157.
- 531. Piller, F. M.; Bresser, T.; Fischer, M. K. R.; Knochel, P.* “Preparation of Functionalized Cyclic Enol Phosphates by Halogen-Magnesium Exchange and Directed Deprotonation Reactions” J. Org. Chem. 2010, 75, 4365-4375.
- 532. Bresser, T.; Mosrin, M.; Monzon, G.; Knochel, P.* “Regio- and Chemoselective Zincation of Sensitive and Moderately Activated Aromatics and Heteroaromatics Using TMPZnCl • LiCl” J. Org. Chem. 2010, 75, 4686-4695.
- 533. Dunst, C.; Kienle, M.; Knochel, P.* „Preparation of Heterocyclic Amines via a Copper(I)-Mediated Oxidative Cross-Coupling of Organozinc Reagents with Lithium Amides” Synthesis 2010, 2313-2318.
- 534. Metzger, A.; Bernhardt, S.; Manolikakes, G.; Knochel, P.* “MgCl2-Accelerated Addition of Functionalized Organozinc Reagents to Aldehydes, Ketones, and Carbon Dioxide” Angew. Chem. Int. Ed. 2010, 49, 4665-4668.
- 535. Kienle, M.; Unsinn, A.; Knochel, P.* “Synthesis of Dibenzothiophenes and Related Classes of Heterocycles by Using Functionalized Dithiocarbamates” Angew. Chem. Int. Ed. 2010, 49, 4751-4754.
- 536. Jaric, M.; Haag, B. A.; Unsinn, A.; Karaghiosoff, K.; Knochel, P.* “Highly Selective Metalations of Pyridines and Related Heterocycles Using New Frustrated Lewis Pairs or tmp-Zinc and tmp-Magnesium Bases with BF3? OEt2” Angew. Chem. Int. Ed. 2010, 49, 5451-5455.
- 537. Melzig, L.; Stemper, J.; Knochel, P.* “A novel palladium-catalyzed cross-coupling of thiomethylated alkynes with functionalized organozinc reagents” Synthesis 2010, 2085-2091.
- 538. Schade, M. A.; Manolikakes, G.; Knochel, P.* “Preparation of Primary Amides from Functionalized Organozinc Halides” Org. Lett. 2010, 12, 3648-3650.
- 539. Wunderlich, S. H.; Bresser, T.; Dunst, C.; Monzon, G.; Knochel, P.* „Efficient Preparation of Polyfunctional Organometallics via Directed ortho-Metallation” Synthesis 2010, 2670-2678.
- 540. Yamada, S.; Knochel, P.* “Large-Scale Preparation of Aromatic Fluorides via Electrophilic Fluorination with Functionalized Aryl- or Heteroarylmagnesium Reagents” Synthesis 2010, 2490-2494.
- 541. Metzger, A.; Melzig, L.; Knochel, P.* “Scaled-up transition-metal-catalyzed cross-coupling reactions of thioether-substituted N-heterocycles with organozinc reagents” Synthesis 2010, 2853-2858.
- 542. Schade, M. A.; Fleckenstein, J. E.; Knochel, P.*; Koszinowski, K. “Charged Tags as Probes for Analyzing Organometallic Intermediates and Monitoring Cross-Coupling Reactions by Electrospray-Ionization Mass Spectrometry” J. Org. Chem. 2010, 75, 6848-6857.
- 543. Guo, L-N.; Gao, H.; Mayer, P.; Knochel, P.* “Preparation of Organoaluminum Reagents from Propargylic Bromides and Aluminum Activated by PbCl2 and Their Regio- and Diastereoselective Addition to Carbonyl Derivatives” Chem. Eur. J. 2010, 16, 9829-9834
- 544. Bresser, T.; Monzon, G.; Mosrin, M.; Knochel, P.* “Scaleable Preparation of Sensitive Functionalized Aromatics and Heteroaromatics via Directed Metalation Using tmpZnCl • LiCl” Org. Proc. Res. Dev., 2010, in press.
- 545. Jeganmohan, M.; Knochel, P.* “tmp4Zr: An Atom-Economical Base for the Metalation of Functionalized Arenes and Heteroarenes” Angew. Chem. Int. Ed. 2010, 49, 8520-8524.
- 546. Peng, Z.; Bluemke, T. D.; Mayer, P.; Knochel, P.* “Diastereoselective Synthesis of Homoallylic Alcohols with Adjacent Tertiary and Quaternary Centers by Using Functionalized Allylic Aluminum Reagents” Angew. Chem. Int. Ed. 2010, 49, 8516-8519.
- 547. Peng, Z.; Haag, B. A.; Knochel, P.* “Preparation of 2-Magnesiated 1,3,5-Triazines via an Iodine-Magnesium Exchange” Org. Lett. 2010, in press.
- 548. Lotz, M.; Schuecker, R.; Mereiter, K.; Knochel, P.* “Synthesis of Exclusively Centrostereogenic 1,3-Bidentate Ferrocenyldiphosphane Ligands and Their Use in Enantioselective Hydrogenations” Organometallics, 2010, in press.
- 549. Brueckl, T.; Thoma, I.; Wagner, A. J.; Knochel, P.*; Carell, T. “Efficient Synthesis of Deazaguanosine-Derived tRNA Nucleosides PreQ0, PreQ1, and Archaeosine Using the Turbo-Grignard Method” Eur. J. Org. Chem. 2010, 34, 6517-6519.
- 550. Haag, B. A.; Zhang, Z.-G.; Li, J.-S.; Knochel, P.* “Fischer Indole Synthesis with Organozinc Reagents” Angew. Chem. Int. Ed. 2010, 49, 9513-9516.
- 551. Knochel, P.*; Thaler, T.; Diene, C. „Pd-, Ni-, Fe-, and Co-Catalyzed Cross-Couplings Using Functionalized Zn-, Mg-, Fe-, and In-Organometallics” Isr. J. Chem. 2010, 50, 547-557.
- 552. Bernhardt, S.; Metzger, A.; Knochel, P.* “Direct addition of functionalized organozinc reagents to carbon dioxide, ketones, and aldehydes in the presence of MgCl2” Synthesis 2010, 3802-3810.
- 553. Kunz, T.; Knochel, P.* “Selective Multiple Magnesiations of the Thieno[3,2]-thiophene Scaffold.” Chem. Eur. J. 2011, 17, 866-872.
- 554. Zimdars, S.; du Jourdin, X. M.; Crestey, F.; Carell, T.; Knochel, P.* “Trifunctionalization of the Purine Scaffold Using Mg and Zn Organometallic Intermediates” Org. Lett. 2011, 13, 792-795.
- 555. Kienle, M.; Wagner, A. J.; Dunst, C.; Knochel, P.* ”Preparation of Heterocyclic Amines by an Oxidative Amination of Zinc Organometallics Mediated by CuI: A New Oxidative Cycloamination for the Preparation of Annulated Indole Derivatives.” Chem. Asian J. 2011, 6, 517-523.
- 556. Dogru, M.; Sonnauer, A.; Gavryushin, A.; Knochel, P.*; Bein, T. “A Covalent Organic Framework with 4 nm open pores.” Chem. Comm. 2011, 47, 1707-1709.
- 557. Zhang, Z.-G.; Haag, B. A.; Li, J-S.; Knochel, P.* „Efficient preparation of polyfunctional indoles via a zinc organometallic variation of the Fisher indole synthesis” Synthesis 2011, 23-29.
- 558. Seel, S.; Thaler, T.; Takatsu, K.; Zhang, C.; Zipse, H.; Straub, B. F.; Mayer, P.; Knochel, P.* „Highly Diastereoselective Arylations of Substituted Piperidines” J. Am. Chem. Soc. 2011, 133, 4774-4777.
- 559. Duez, S.; Bernhardt, S.; Heppekausen, J.; Fleming, F. F.; Knochel, P.* „Pd-Catalyzed ?-Arylation of Nitriles and Esters and ?-Arylation of Unsaturated Nitriles with TMPZnCl•LiCl” Org. Lett. 2011, 13, 1690-1693.
- 560. Melzig, L.; Metzger, A.; Knochel, P.* „Pd- and Ni-Catalyzed Cross-Coupling Reactions of Functionalized Organozinc Reagents with Unsaturated Thioethers” Chem. Eur. J. 2011, 17, 2948-2956.
- 561. Thaler, T.; Guo, L.-N.; Mayer, P.; Knochel, P.* “Highly Diastereoselective C(sp3–C(sp) Cross-Coupling Reactions between 1,3- and 1,4-Substituted Cyclohexylzinc Reagents and Bromoalkynes through Remote Stereocontrol” Angew. Chem. Int. Ed. 2011, 50, 2174-2177.
- 562. Bresser, T.; Knochel, P.* “Selective Magnesiation or Zincation of Highly Functionalized Alkenes and Cycloalkenes Using 2,2,6,6-Tetramethylpiperidyl Bases” Angew. Chem. Int. Ed. 2011, 50, 1914-1917.
- 563. Steib, A. K.; Thaler, T.; Komeyama, K.; Mayer, P.; Knochel, P.* „Highly Diastereoselective Iron-Mediated C(sp2–C(sp3) Cross-Coupling Reactions between Aryl Grignard Reagents and Cyclic Iodohydrine Derivatives” Angew. Chem. Int. Ed. 2011, 50, 3303-3307.
- 564. Schade, M. A.; Yamada, S.; Knochel, P.* “Synthesis of Polyfunctional Allenes by Succesive Copper-Mediated Substitutions” Chem. Eur. J. 2011, 17, 4232-4237.
- 565. Jaric, M.; Haag, B. A.; Manolikakes, S.; Knochel, P.* “Selective and Multiple Functionalization of pyridines and Alkaloids via Mg- and Zn-Organometllic Intermediates” Org. Lett. 2011, 13, 2306-2309.
- 566. Melzig, L.; Rauhut, C. B.; Naredi-Rainer, N.; Knochel, P.* “Disfunctionalisation of Arenes and Heteroarenes by Directed Metallation and Sulfoxide-Magnesium Exchange” Chem. Eur. J. 2011, 17, 5362-5372.
- 567. Zimdars, S.; Langhals, H.; Knochel, P.* „Functionalization of the Benzo[c][1,2,5]thiadiazole Scaffold vianMg-, Zn- and Mn-Intermediates” Synthesis 2011, 1302-1308.
- 568. Peng, Z.; Knochel, P.* “Preparation of Functionalized Organomanganese(II) Reagents by Direct Insertion of Manganese to Aromatic and Benzylic Halides” Org. Lett. 2011, 13, 3198-3201.
- 569. Thaler, T.; Guo, L.-N.; Steib, A. K.; Raducan, M.; Karaghiosoff, K.; Mayer, P.; Knochel, P.* “Sulfoxide-Alkene Hybrids: A New Class of Chiral Ligands for the Hayashi-Miyaura Reaction” Org. Lett. 2011, 13, 3182-3185.
- 570. Melzig, L.; Diene, C. R.; Rohbogner, C. J.; Knochel, P.* “Preparation of Polyfunctional Zinc Organometallics Using an Fe- or Co-Catalyzed Cl/Zn-Exchange” Org. Lett. 2011, 13, 3174-3177.
- 571. Duez, S.; Steib, A. K.; Manolikakes, S. M.; Knochel, P.* “Lewis Acid Promoted Benzylic Cross-Couplings of Pyridines with Aryl Bromides” Angew. Chem. Int. Ed. 2011, 50, 7686-7690.
- 572. Haag, B. A.; Saemann, C.; Jana, A.; Knochel, P.* “Practical One-Pot Preparation of Magnesium Di(hetero)aryl- and Magnesium Dialkenylboronates for Suzuki-Miyaura Cross-Coupling Reactions” Angew. Chem. Int. Ed. 2011, 50, 7290-7294.
- 573. Dunst, C.; Knochel, P.* “Regioselective Functionalization of the Thiazole Scaffold using TMPMgCl•LiCl and TMP2Zn•2MgCl2•2LiCl” J. Org. Chem. 2011, 76, 6972-6978.
- 574. Melzig, L.; Dennenwaldt, T.; Gavryushin, A.; Knochel, P.* “Direct Aminoalkylation of Arenes, Heteroarenes, and Alkenes via Ni-Catalyzed Negishi Cross-Coupling Reactions” J. Org. Chem. 2011, 76, 8891-8901.
- 575. Bernhardt, S.; Manolikakes, G.; Kunz, T.; Knochel, P.* “Preparation of Solid Salt-Stabilized Functionalized Organozinc Compounds and their Application to Cross-Coupling and Carbonyl Addition Reactions” Angew. Chem. Int. Ed. 2011, 50, 9205-9209.
- 576. Farina, V.; Lemaire, S.; Houpis, I.; Digard, E.; Gozlan, C.; Wang, Y.; Diene, C.; Gavryushin, A.; Knochel, P.* “New C-glycosylation methodology” Abstracts of Papers, 242nd ACS National Meeting & Exposition, Denver, CO, US, Aug. 28 – Sept. 1, 2011, ORGN-188.
- 577. Piller, F. M.; Knochel, P.* “Regio- and chemoselective synthesis of fully substituted furans” Synthesis 2011, 1751-1758.
- 578. Haag, B.; Mosrin, M.; Hiriyakkanavar, I.; Malakhov, V.; Knochel, P.* “Regio- and Chemoselective Metalation of Arenes and Heteroarenes Using Hindered Metal Amide Bases” Angew. Chem. Int. Ed. 2011, 50, 9794-9824.
- 579. Knochel, P.*; Schade, M. A.; Bernhardt, S.; Manolikakes, G.; Metzger, A.; Piller, F. M.; Rohbogner, C. J.; Mosrin, M. “Functionalization of heterocyclic compounds using polyfunctional magnesium and zinc reagents” Beilstein J. Org. Chem. 2011, 7, 1261-1277, No. 147.
- 580. Knochel, P.*; Diene, C. “Preparation of functionalized Zn- and Mg-organometallics. Application to the performance of diastereoselective cross-couplings” Compt. Rend. Chim. 2011, 14, 842-850.
- 581. Bluemke, T. D.; Groll, K.; Karaghiosoff, K.; Knochel, P.* “New preparation of benzylic aluminum and zinc organometallics by direct insertion of aluminum powder” Org. Lett. 2011, 6440-6443.
- 582. Dienstmaier, J. F.; Gigler, A. M.; Goetz, A. J.; Knochel, P.; Bein, T.; Lyapin, A.; Reichlmaier, S.; Heckl, W. M.; Lackinger, M. “Synthesis of Well-Ordered COF Monolayers: Surface Growth of Nanocrystalline Precursors versus Direct On-Surface Polycondensation” ACS Nano 2011, 5, 9737-9745.
- 583. Guo, L.-N.; Gao, H.; Mayer, P.; Knochel, P.* “Corrigendum: Preparation of Organoaluminum Reagents from Propargylic Bromides and Aluminum Activated by PbCl2 and Their Regio- and Diastereoselective Addition to Carbonyl Derivatives” Chem. Eur. J. 2011, 17, 12536.
- 584. Li, Y.; Keilbach, A.; Kienle, M.; Goto, Y.; Inagaki, S.; Knochel, P.*; Bein, T. “Hierarchically structured biphenylene-bridged periodic mesoporous organosilica” J. Mater. Chem. 2011, 21, 17338-17344.
- 585. Dunst, C.; Knochel, P.* “Selective Mg insertion into substituted mono- and dichloro arenes in the presence of LiCl: a new preparation of boscalid” Synlett 2011, 14, 2064-2068.
- 586. Dunst, C.; Metzger, A.; Zaburdaeva, E. A.; Knochel, P.* “Stereoselective Synthesis of Polyfunctional Tetrasubstituted Alkenyl Sulfides via a Carbocupration of Alkynyl Sulfides with Aryl and Benzylic Diorganozincs” Synthesis 2011, 3453-3462.
- 587. Knochel, P.* “Allyltrimethylsilylzinc chloride” Edited by Fuchs, P. L. From “Handbook of Reagents for Organic Synthesis: Reagents for Silicon-Mediated” Org. Synthesis 2011, 24-25.
- 588. Knochel, P.* “Tracking two chemistry nobel prize winners. Improved metalorganic intermediates for cross-coupling reactions” GIT Labor-Fachzeitschrift 2011, 55(11), 799-801.
- 589. Brodmann, T.; Koos, P.; Metzger, A.; Knochel, P.*; Ley, S. V. “Continuous Preparation of Arylmagnesium Reagents in Flow with Inline IR Monitoring” Org. Proc. Res. & Dev. 2012, 16, 1102-1113.
- 590. Kunz, T.; Knochel, P.* “Synthesis of Functionalized Benzo[b]thiophenes by the Intramolecular Copper-Catalyzed Carbomagnesiation of Alkynyl(aryl)thioethers” Angew. Chem. Int. Ed. 2012, 51, 1958-1961.
- 591. Shi, L.; Chu, Y.; Knochel, P.*; Mayr, H. “Leaving Group Dependence of the Rates of Halogen-Magnesium Exchange Reactions” Org. Lett. 2012, 14, 2602-2605.
- 592. Duez, S.; Steib, A. K.; Knochel, P.* “Benzylic Arylation of 2-Methyl-5-membered Heterocycles Using TMP-Bases” Org. Lett. 2012, 14, 1951-1953.
- 593. Lemaire, S.; Houpis, I. N.; Xiao, T.; Li, J.; Digard, E.; Gozlan, C.; Liu, R.; Gavryushin, A.; Diène, C.; Wang, Y.; Farina, V.; Knochel, P.* “Stereoselective C-Glycosylation Reactions with Arylzinc Reagents” Org. Lett. 2012, 14(6), 1480-1483.
- 594. Unsinn, A.; Knochel, P.* “Regioselective zincation of indazoles using TMP2Zn and Negishi cross-coupling with aryl and heteroaryl iodides” Chem. Comm. 2012, 48, 2680-2682.
- 595. Berionni, G.; Maji, B.; Knochel, P.*; Mayr, H. “Nucleophilicity parameters for designing transition metal-free C-C bond forming reactions of organoboron compounds” Chem. Science 2012, 3, 878-882.
- 596. Frischmuth, A.; Unsinn, A.; Groll, K.; Stadtmüller, H.; Knochel, P.* „Preparations and Reactions of SF5 Substituted Aryl nd Heteroaryl Derivatives via Mg and Zn Organometallics“ Chem. Eur. J. 2012, 18, 10234-10238.
- 597. Malysheva, Y. B.; Combes, S.; Allegro, D.; Peyrot, V.; Knochel, P.; Gavryushin, A. E.; Fedorov, A. Y. “Synthesis and biological evaluation of novel anticancer bivalent colchicine-tubulizine hybrids” Bioorg. Med. Chem. 2012, 20, 4271-4278.
- 598. Dienstmaier, J. F.; Medina, D. D.; Dogru, M.; Knochel, P.; Bein, T.; Heckl, W. M.; Lackinger, M. „Isoreticular Two-Dimensional Covalent Organic Frameworks Synthesized by On-Surface Condensation of Diboronic Acids“ ACS Nano, 2012, 6, 7234-7242.
- 599. Malysheva, Y. B.; Combes, S.; Fedorov, A. Y.; Knochel, P.; Gavryushin, A. E. “New Method of Synthesis and Biological Evaluation of Some Combretastatin A-4 Analogues” Synlett 2012, 23, 1205-1208.
- 600. Klier, L.; Bresser, T.; Nigst, T. A.; Karaghiosoff, K.; Knochel, P.* “Lewis Acid-Triggered Selective Zincation of Chromones, Quinolones, and Thiochromones: Application to the Preparation of Natural Flavones and Isoflavones” J. Am. Chem. Soc. 2012, 134, 13584-13587.
- 601. Mycka, R. J.; Duez, S.; Bernhardt, S.; Heppekausen, J.; Knochel, P.; Fleming, F. F. “Cyclohexylcarbonitriles: Diastereoselective Arylations with TMPZnCl•LiCl” J. Org. Chem. 2012, 77, 7671-7676.
- 602. Stathakis, C. I.; Bernhardt, S.; Quint, V.; Knochel, P.* „Improved Air-Stable Solid Aromatic and Heterocyclic Zinc Reagents by Highly Selective Metalations for Negishi Cross-Couplings” Angew. Chem. Int. Ed. 2012, 51, 9428-9432.
- 603. Blümke, T. D.; Klatt, T.; Koszinowski, K.; Knochel, P.* “InCl3-Catalyzed Synthesis of 1,2-Dimetallic Compounds by Direct Insertion of Aluminum or Zinc Powder” Angew. Chem. Int. Ed. 2012, 51, 9926-9930.
- 604. Kuzmina, O. M.; Steib, A. K.; Flubacher, D.; Knochel, P.* “Iron-Catalyzed Cross-Coupling of N-Heterocyclic Chlorides and Bromides with Arylmagnesium Reagents” Org. Lett. 2012, 14, 4818-4821.
- 605. Monzón, G.; Tirotta, I.; Yuji, N.; Knochel, P. “The ortho and meta Magnesiation of Functionalized Anilines and Amino-Substituted Pyridines and Pyrazines at Room Temperature” Angew. Chem Int. Ed., 2012, 51, 10624–10627.
- 606. Knochel, P. “Water in Organic Synthesis” Workbench Edition (Sience of Synthesis); Shu Kobayashi, Ed. Synthesis 2012, 44, 2474.
- 607. Groll, K.; Blümke, T. D.; Unsinn, A.; Haas, D.; Knochel, P. “Direct Pd-Catalyzed Cross-Coupling of Functionalized Organoaluminum Reagents” Angew. Chem. Int. Ed. 2012, 51, 11157-11161.
- 608. Sämann, C.; Haag, B.; Knochel, P. „Highly Regioselective Preparation of Heteroaryl-Magnesium Reagents by Using a Br/Mg Exchange“ Chem. Eur. J. 2012, 18, 16145-16152.
- 609. Dogru, M.; Handloser, M.; Auras, F.; Kunz, T.; Medina, D.; Hartschuh, A.; Knochel, P.*; Bein, T.* „A Photoconductive Thienothiophene-Based Covalent Organic Framework Showing Charge Transfer Towards Included Fullerene“ Angew. Chem. Int. Ed. 2013, 52, 2920-2924.
- 610. Monzon, G.; Tirotta, I.; Knochel, P.* “Corrigendum: The ortho and meta Magnesiation of Functionalized Anilines and Amino-Substituted Pyridines and Pyrazines at Room Temperature“ Angew. Chem. Int. Ed. 2012, 51, 11662.
- 611. Langhals, H.; Knochel, P.; Walter, A.; Zimdars, S. “Benzothiadiazoloperylenes and Benzoxadiazoloperylenes: Amorphous Functional Materials” Synthesis 2012, 44, 3465-3477.
- 612. Unsinn, A.; Dunst, C.; Knochel, P. „Stereoselective synthesis of tetrasubstituted alkenes via a sequential cabocupration and a new sulfur-lithium exchange“ Beilstein J. Org. Chem. 2012, 8, 2202-2206.
- 613. Bernhardt, S.; Shen, Z.-L.; Knochel, P.* “Preparation of Functionalized Organoindium Reagents by Means of Magnesium Insertion into Organic Halides in the Presence of InCl3 at Room Temperature“ Chem. Eur. J. 2013, 19, 828-833
- 614. Seel, S.; Dagousset, G.; Thaler, T.; Frischmuth, A.; Karaghiosoff, K.; Zipse, H.; Knochel, P.* „Preparation of Stereodefined Secondary Alkyllithium Compounds“ Chem. Eur. J. 2013, 19, 4614-4622.
- 615. Dogru, M.; Sonnauer, A.: Zimdars, S.: Döblinger, M.; Knochel, P.; Bein, T.* „Facile synthesis of a mesoporous benzothiadiazole-COF based on a transesterification process“ CrystEngComm 2013, 15, 1500-1502.
- 616. Manolikakes, S. M.; Jaric, M.; Karaghiosoff, K.; Knochel, P.* „Metalated N-heterocyclic reagents prepared by the frustrated Lewis pair TMPMgCl•BF3 and their addition to aromatic aldehydes and activated ketones” Chem. Comm. 2013, 49, 2124-2126.
- 617. Unsinn, A.; Ford, M. J.; Knochel, P.* „New Preparation of TMPZnCl•LiCl by Zn Insertion into TMPCI. Application to the Functionalization of Dibromodiazines” Org. Lett. 2013, 15, 1128-1131.
- 618. Stathakis, C. I.; Manolikakes, S. M.; Knochel, P.* “TMPZnOPiv•LiCl: A New Base for the Preparation of Air-Stable Solid Zinc Pivalates of Sensitive Aromatics and Heteroaromatics” Org. Lett. 2013, 15, 1302-1305.
- 619. Unsinn, A.; Wunderlich, S. H.; Knochel, P.* „Accelerated Zincations for an Efficient and Mild Functionalization of Aromatics and Heterocycles“ Adv. Synt. & Cat. 2013, 355, 989-995.
- 620. Quan, C.; Mollat du Jourdin, X.; Knochel, P.* “Transition-Metal-Free BF3-Mediated Regioselective Direct Alkylation and Arylation of Functionalized Pyridines Using Grignard or Organozinc Reagents” J. Am. Chem. Soc. 2013, 135, 4958-4961.
- 621. Kuzmina, O. M.; Steib, A. K.; Markiewicz, J. T.; Flubacher, D.; Knochel, P.* “Ligand-Accelerated Iron-and Cobalt-Catalyzed Cross-Coupling Reactions between N-Heteroaryl Halides and Aryl Magnesium Reagents” Angew. Chem. Int. Ed. 2013, 52, 4945-4949.
- 622. Berionni, G.; Morozova, V.; Heininger, M.; Mayer, P.; Knochel, P.; Mayr, H.* “Electrophilic Aromatic Substitutions of Aryltrifluoroborates with Retention of the BF3-Group: Quantification of the Activating and Directing Effects of the Trifluoroborate Group” J. Am. Chem. Soc. 2013, 135, 6317-6324.
- 623. Sämann, C.; Schade, M.A.; Yamada, S; Knochel, P.* “Functionalized Alkenylzinc Reagents Bearing Carbonyl Groups: Preparation by Direct Metal Insertion and Reaction with Electrophiles” Angew. Chem. Int. Ed. 2013, 52, 9495-9499.
- 624. Unsinn, A.; Rohbogner, C. J.; Knochel, P.* “Directed Magnesiation of Polyhaloaromatics using the Tetramethylpiperidylmagnesium Reagents TMP2Mg•2LiCl and TMPMgCl•LiCl” Adv. Syn. & Cat. 2013, 355, 1553-1560.
- 625. Groll, K.; Manolikakes, S. M.; Mollat du Jourdin, X.; Jaric, M.; Bredihhin, A.; Karaghiosoff, K.; Carell, T.; Knochel, P.* “Regioselective Metalations of Pyrimidines and Pyrazines by Using Frustrated Lewis Pairs of BF3•OEt2 and Hindered Magnesium- and Zinc-Amide Bases” Angew. Chem. Int. Ed. 2013, 52, 6776-6780.
- 626. Klatt, T.; Groll, K.; Knochel, P.* “Generation of functionalized aryl and heteroaryl aluminum reagents by halogen-lithium exchange” Chem. Comm. 2013, 49, 6953-6955.
- 627. Barl, N. M.; Sansiaume-Dagousset, E.; Karaghiosoff, K.; Knochel, P.* „Full Functionalization of the 7-Azaindole Scaffold by Selective Metalation and Sulfoxide/Magnesium Exchange” Angew. Chem. Int. Ed. 2013, 52, 10093-10096.
- 628. Manolikakes, S. M.; Barl, N. M.; Saemann, C.; Knochel, P.* “Regioselective functionalization of pyridines using a directed metalation or a halogen/metal exchange” Zeitschrift fuer Naturforschung, B: A Journal of Chemical Sciences 2013, 68, 411-422.
- 629. Frischmuth, A.; Knochel, P.* „Preparation of Functionalized Indoles and Azaindoles by the Intramolecular Copper-Mediated Carbomagnesiation of Ynamides” Angew. Chem. Int. Ed. 2013, 52, 10084-10088.
- 630. Sämann, C.; Knochel, P.* “A Convenient Synthesis of ?-Substituted ?,?-Unsaturated Ketones and Esters via the Direct Addition of substituted Allylic Zinc Reagents Prepared by Direct Insertion“ Synthesis 2013, 45, 1870-1876.
- 631. Druzhinin, S. I.; Dubbaka, S. R.; Knochel, P.; Kovalenko, S. A.; Mayer, P.; Senyushkina, T.; Zachariasse, K. A. Correction to “Ultrafast Intramolecular Charge Transfer with Strongly Twisted Aminobenzonitriles: 4-(Di-tert-butylamino)benzonitrile and 3-(Di-tert-butylamino)benzonitrile” J. Phys. Chem. A 2008, 112, 2749-2761.
- 632. Unsinn, A.; Wunderlich, S. H.; Jana, A.; Karaghiosoff, K.; Knochel, P.* “A Convenient Alumination of Functionalized Aromatics by Using the Frustrated Lewis Pair Et3Al and TMPMgCl•LiCl” Chem. Eur. J. 2013, 19, 14687-14696.
- 633. Steib, A. K.; Kuzmina, O. M.; Fernandez, S.; Flubacher, D.; Knochel, P.* „Efficient Chromium(II)-Catalyzed Cross-Coupling Reactions between Csp2 Centers“ J. Am. Chem. Soc. 2013, 135, 15346-15349.
- 634. Benhaim, C.; Lemaire, S.; Gaekens, T.; Govaerts, T.; Houpis, I. N.; Reniers, P.; Looy, A. V.; Vermeulen, W. A. A.; Bernhardt, S.; Diène, C.; Knochel, P.* „Synthesis of (4’R)-azido-(2’R)-2‘-deoxy-2‘-C-methyluridine and its esters by direct iodide displacement“ Synlett 2013, 24, 1697-1701.
- 635. Hiriyakkanavar, I.; Markiewicz, J. T.; Malakhov, V.; Knochel, P.* “Metalated indoles, indazoles, benzimidazoles, and azaindoles and their synthetic applications” Synthesis 2013, 45, 2343-2371.
- 636. Knochel, P. “Organomagnesium and organozinc chemistry” in “Organometallics in Synthesis” Ed.: Schlosser, M. Wiley –VCH Verlag, Weinheim, 2013, 223-372.
- 637. Haas, D.; Mosrin, M.; Knochel, P.* „Regioselective Functionalization of the Oxazole Scaffold Using TMP-Bases of Mg and Zn” Org. Lett. 2013, 15, 6162-6165.
- 638. Knochel, P.; Bluemke, T.; Groll, K. Chen, Y-H. “Preparation organoalanes for organic synthesis” in “Topics in Organometallic Chemistry” Springer-Verlag 2013, 41, 173-186.
- 639. Colombe, J. R.; Bernhardt, S.; Stathakis, C.; Buchwald, St. L.; Knochel, P.* „Synthesis of Solid 2-Pyridylzinc Reagents and Their Application in Negishi Reactions“ Org. Lett. 2013, 15, 5754-5757.
- 640. Crestey, F.; Zimdars, S.; Knochel, P*. „Regioselective functionalization of purine derivatives at positions 8 and 6 using hindered TMP-amide bases of Zn and Mg“ Synthesis 2013, 45, 3029-3037.
- 641. Dagousset, G.; Moriya, K.; Mose, R.; Berionni, G.; Karaghiosoff, K.; Knochel, P.* „Diastereoselective Synthesis of Open-Chain Secondary Alkyllithiums Compounds and Trapping Reactions with Electrophiles“ Angew. Chem. Int. Ed. 2014, 53, 1425-1429.
- 642. Didier, D.; Delaye, P.-O.; Simaan, M.; Island, B.; Eppe, G.; Eijsberg, H.; Kleiner, A.; Knochel, P.; Marek, I.* „Modulable and Highly Diastereoselective Carbometalations of Cyclopropenes” Chem. Eur. J. 2014, 20, 1038-1048.
- 643. Hernán-Gómez, A.; Herd, E.; Hevia, E.; Kennedy, A. R.; Knochel, P.*; Koszinovski, K.; Manolikakes, S.; Mulvey, R. E.*; Schnegelsberg, C. “Organozinc Pivalate Reagents: Segregation, Solubility, Stabilisation and Structural Insights” Angew. Chem. Int. Ed. 2014, 53, 2706-2710.
- 644. Sämann, C.; Coya, E.; Knochel, P.* „Full Functionalization of the Imidazole Scaffold by Selective Metalation and Sulfoxide/Magnesium Exchange“ Angew. Chem. Int. Ed. 2014, 53, 1430-1434.
- 645. Shen, Z.; Peng, Z.; Yang, C.; Helberg, J.; Mayer, P.; Marek, I.; Knochel, P.* „Highly Diastereoselective Preparation of Aldol Products Using New Functionalized Allylic Aluminum Reagents” Org. Lett. 2014, 16, 956-959.
- 646. Barl, N.; Werner, V.; Saemann, C.; Knochel, P.* “The halogen/magnesium-exchange using iPrMgCl•LiCl and related exchange reagents” Heterocycles 2014, 88, 827-844.
- 647. Moriya, K.; Knochel, P.* “Diastereoconvergent Negishi Cross-Coupling Using Functionalized Cyclohexylzinc Reagents” Org. Lett. 2014, 16, 924-927.
- 648. Klatt, T.; Roman, Daniela S.; Leon, T.; Knochel, P.* “TMP-Magnesium and TMP-Zinc Bases for the Regioselective Metalation of the Cinnoline Scaffold” Org. Lett. 2014, 16, 1232-1235.
- 649. Medina, D.; Werner, V.; Auras, F.; Tautz, R.; Dogru, M.; Schuster, J.; Linke, S.; Doblinger, M.; Feldmann, J.; Knochel, P.;* Bein, T. “Oriented Thin Films of a Benzodithiophene Covalent Organic Framework” ACS Nano 2014, ACS Nano 2014, 8, 4042-4052.
- 650. Knochel, P. “Award Address (Herbert C. Brown Award for Creative Research in Synthetic Methods sponsored by the Purdue Borane Research Fund and the Herbert C. Brown Award Endowment). Polyfunctional Zn- and Mg-organometallics in organic synthesis” Abstracts of Papers, 247th ACS National Meeting & Exposition, Dallas, TX, United States, March 16-20, 2014 (2014), ORGN-204.
- 651. Chen, Q.; Leon, T.; Knochel, P.* “Transition-Metal-Free BF3-Mediated Oxidative and Non-Oxidative Cross-Coupling of Pyridines” Angew. Chem. Int. Ed. 2014, in print.
- 652. Saemann, C.; Dhayalan, V.; Schreiner, P. R.; Knochel, P.* “Synthesis of Substituted Adamantylzinc Reagents Using a Mg-Insertion in the Presence of ZnCl2 and Further Functionalizations” Org. Lett. 2014, 16, 2418-2421.
- 653. Barl, N. M.; Sansiaume-Dagousset, E.; Monzon, G.; Wagner, A. J.; Knochel, P.* „Preparation and Reactions of Heteroarylmethylzinc Reagents” Org. Lett. 2014, 16, 2422-2425.
- 654. Klatt, T.; Markiewicz, J. T.; Saemann, C.; Knochel, P* „Strategies to Prepare and Use Functionalized Organometallic Reagents” J. Org. Chem. 2014, in print.
- 655. Werner, V.; Klatt, T.; Fujii, M.; Markiewicz, Jen.; Apeloig, Y.; Knochel, P.* „Preparation and Regioselective Metalation of Bis(trimethylsilyl)methyl-Substituted Aryl Derivatives” Chem. Eur. J. 2014, 20, 8338-8342.
- 656. Frischmuth, A.; Fernandez, M.; Barl, N. M.; Achrainer, F.; Zipse, H.; Berionni, G.; Mayr, H.; Karaghiosoff, K.; Knochel, P.* „New In Situ Trapping Metalations of Functionalized Arenes and Heteroarenes with TMPLi in the Presence of ZnCl2 and Other Metal Salts” Angew. Chem. Int. Ed. 2014, in print.
- 657. Petersen, T. P.; Becker, M. R.; Knochel, P.* „Continuous Flow Magnesiation of Functionalized Heterocycles and Acrylates with TMPMgCl•LiCl” Angew. Chem. Int. Ed. 2014, in print.
- 658. Kuzmina, O. M.; Knochel, P.* “Room-Temperature Chromium(II)-Catalyzed Direct Arylation of Pyridines, Aryl Oxazolines, and Imines Using Arylmagnesium Reagents” Org. Lett. 2014, in print.
- 659. Klatt, T.; Bluemke, T. D.; Ganiek, M. A.; Knochel, P.* “Synthesis of 1,2-dimetallic compounds via direct insertion of zinc powder in the presence of InCl3: synthesis of ortho-bis-functionalized aromatics” Synthesis 2014, 6, 290-294.
- 660. Manolikakes, S. M.; Ellwart, M.; Stathakis, C. I.; Knochel, P.* “Air-Stable Solid Aryl and Heteroaryl Organozinc Pivalates: Syntheses and Applications in Organic Synthesis” Chem. Eur. J. 2014, 20, 12289-12297.
- 661. Klier, L.; Diene, C. R.; Schickinger, M.; Metzger, A.; Wagner, A. J.; Karaghiosoff, K.; Marek, I.; Knochel, P.* „Isoxazole-Embedded Allylic Zinc Reagent for the Diastereoselective Preparation of Highly Functionalized Aldol-Type Derivatives Bearing a Stereocontrolled Quaternary Center” Chem. Eur. J. 2014, Ahead of Print.
- 662. Leon, T.; Quinio, P.; Chen, Q.; Knochel, P.* “BF3-mediated oxidative cross-coupling of pyridines with alkynyllithium reagents and further reductive functionalizations of the pyridine scaffold” Synthesis 2014, 10, 1374-1379.
- 663. Blanc, R.; Groll, K.; Bernhardt, S.; Stockmann, P. N.; Knochel, P.* “Efficient cross-coupling reactions of (pivaloyloxymethyl)zinc chloride” Synthesis 2014, 8, 1052-1058.
- 664. Kuzmina, O. M.; Knochel, P.* „Room-Temperature Chromium(II)-Catalyzed Direct Arylation of Pyridines, Aryl Oxazolines, and Imines Using Arylmagnesium Reagents” Org. Lett. 2014, 16, 5208-5211.
- 665. Nafe, J.; Herbert, S.; Auras, F.; Karaghiosoff, K.; Bein, T.; Knochel, P.* “Functionalization of Quinoxalines by Using TMP Bases: Preparation of Tetracyclic Heterocycles with High Photoluminescene Quantum Yields” Chem. Eur. J. 2014, Ahead of Print.
- 666. Dagousset, G.; Francois, C.; Leon, T.; Blanc, R.; Sansiaume-Dagousset, E.; Knochel, P.* “Preparation of Functionalized Lithium, Magnesium, Aluminum, Zinc, Manganese, and Indium Organometallics from Functionalized Organic Halides” Synthesis 2014, 46, 3133-3171.
- 667. Steib, A. K.; Kuzmina, O. M.; Fernandez, S.; Malhotra, S.; Knochel, P.* „Chemoselective Chromium(II)-Catalyzed Cross-Coupling Reactions of Dichlorinated Heteroaromatics with Functionalized Aryl Grignard Reagents” Chem. Eur. J. 2014, Ahead of Print.
- 668. Hammann, J. M.; Steib, A. K.; Knochel, P.* „Cobalt-Mediated Diastereoselective Cross-Coupling Reactions between Cyclic Halohydrins and Arylmagnesium Reagents” Org. Lett. 2014, 16, 6500-6503.
- 669. Knochel, P.*; Editor “Comprehensive Organic Synthesis: Second Edition: Volume 7: Oxidation” 933 pp., Book, 2014, ISBN: 978-0-08-097742-3, Elsevier B.V., Amsterdam, Neth.
- 670. Steib, A. K.; Kuzmina, O. M.; Fernandez, S.; Malhotra, S.; Knochel, P.* „Chemoselective Chromium(II)-Catalyzed Cross-Coupling Reactions of Dichlorinated Heteroaromatics with Functionalized Aryl Grignard Reagents” Chem. Eur. J. 2015, 21, 1961-1965.
- 671. Barl, N. M.; Malakhov, V.; Mathes, C.; Lustenberger, P.; Knochel, P.* „Palladium-Catalyzed Cross-Coupling between 7-Azaindoles and Reformatsky Reagents” Synthesis 2015, 47, 692-700.
- 672. Nafe, J.; Herbert, S.; Auras, F.; Karaghiosoff, K.; Bein, T.; Knochel, P.* “Functionalization of Quinoxalines by Using TMP Bases: Preparation of Tetracyclic Heterocycles with High Photoluminescene Quantum Yields” Chem. Eur. J. 2015, 23, 1102-1107.
- 673. Medina, D. D.; Rotter, J. M.; Hu, Y.; Dogru, M.; Werner, V.; Auras, F.; Markiewicz, J. T.; Knochel, P.*; Bein, T. „Room Temperature Synthesis of Covalent-Organic Framework Films through Vapor-Assisted Conversion” J. Am. Chem. Soc. 2015, 137, 1016-1019.
- 674. Dhayalan, V.; Saemann, C.; Knochel, P.* „Synthesis of polyfunctional secondary amines by the addition of functionalized zinc reagents to nitrosoarenes” Chem. Commun., 2015, 51, 3239-3242.
- 675. Quinio, P.; Benischke, A. D.; Moyeux, A.; Cahiez, G.; Knochel, P.* „New Preparation of Benzylic Manganese Chlorides by the Direct Insertion of Magnesium into Benzylic Chlorides in the Presence of MnCl2•2LiCl” Synlett 2015, 26, 514-518.
- 676. Moriya, K.; Didier, D.; Simon, M.; Hammann, J. M.; Berionni, G.; Karaghiosoff, K.; Zipse, H.; Mayr, H.; Knochel, P.* „Stereoselective Synthesis and Reactions of Secondary Alkyllithium Reagents Functionalized at the 3-Position” Angew. Chem. Int. Ed. 2015, 54, 2754-2757.
- 677. Quinio, P.; François, C.; Escribano C., A.; Steib, A. K.; Achrainer, F.; Zipse, H.; Karaghiosoff, K.; Knochel, P.* “Preparation of Tri- and Tetrasubstituted Allenes via Regioselective Lateral Metalation of Benzylic (Trimethylsilyl)alkynes Using TMPZnCl•LiCl” Org. Lett. 2015, 17, 1010-1013.
- 678. Steib, A. K.; Fernandez, S.; Kuzmina, O. M.; Corpet, M.; Gosmini, C.; Knochel, P.* „Chromium(II)-Catalyzed Amination of N-Heterocyclic Chlorides with Magnesium Amides” Synlett 2015, 26, 1049-1054.
- 679. Hammann, J. M.; Haas, D.; Steib, A. K.; Knochel, P.* „Highly Diastereoselective Cobalt-Mediated C(sp3)-C(sp2) Cross-Coupling Reactions of Cyclic Halohydrins with (Hetero)Aryl Grignard Reagents” Synthesis 2015, 47, 1461-1468.
- 680. Shen, Z.-L.; Knochel, P.* „C60-Catalyzed Preparation of Aryl and Heteroaryl Magnesium and Zinc Reagents Using Mg/LiCl” ACS Catal. 2015, 5, 2324-2328.
- 681. Haas, D.; Hofmayer, M- S.; Bresser, T.; Knochel, P.* „Zincation of 4,4-dimethyloxazoline using TMPZnCl•LiCl. A new preparation of 2-aryloxazolines“ Chem. Commun. 2015, 51, 6415-6417.
- 682. Hammann, J. M.; Haas, D.; Knochel, P.* „Cobalt-Catalyzed Negishi Cross-Coupling Reactions of (Hetero)Arylzinc Reagents with Primary and Secondary Alkyl Bromides and Iodides” Angew. Chem. Int. Ed. 2015, 54, 4478-4481.
- 683. Shen, Z.-L.; Knochel, P.* “Stereoselective Preparation of Polyfunctional Alkenylindium(III) Halides and Their Cross-Coupling with Unsaturated Halides” Chem. Eur. J. 2015, 21, 7061-7065.
- 684. Kuzmina, O. M.; Steib, A. K.; Moyeux, A.; Cahiez, G.; Knochel, P.* „Recent Advances in Iron-Catalyzed Csp2-Csp2 Cross-Couplings” Synthesis 2015, 47, 1696-1705.
- 685. Werner, V.; Ellwart, M.; Wagner, A. J.; Knochel, P.* „Preparation of Tertiary Amines by the Reaction of Iminium Ions Derived from Unsymmetrical Aminals with Zinc and Magnesium Organometallics” Org. Lett. 2015, 17, 2026-2029.
- 686. Klatt, T.; Werner, V.; Maximova, M. G.; Didier, D.; Apeloig, Y.; Knochel, P.* “Preparation and Regioselective Magnesiation or Lithiation of Bis(trimethylsilyl)methyl-Substituted Heteroaryls for the Generation of Highly Functionalized Heterocycles” Chem. Eur. J. 2015, 21, 7830-7834.
- 687. Kuzmina, O. M.; Steib, A. K.; Fernandez, S.; Boudot, W.; Markiewicz, J. T.; Knochel, P.* “Practical Iron- and Cobalt-Catalyzed Cross-Coupling Reactions between N-Heterocyclic Halides and Aryl or Heteroaryl Magnesium Reagents” Chem. Eur. J. 2015, 21, 8242-8249.
- 688. Knochel, P. “Natural Products in the Chemical Industry by Bernd Schafer” Synthesis 2015, 47, 1356.
- 689. Corral-Bautista, F.; Klier, L.; Knochel, P.*; Mayr, H. “From Carbanions to Organometallic Compounds: Quantification of Metal Ion Effects on Nucleophilic Reactivities” Angew. Chem. Int. Ed. 2015, in print.
- 690. Becker, M. R.; Knochel, P.* „Practical Continuous-Flow Trapping Metalations of Functionalized Arenes and Heteroarenes Using TMPLi in the Presence of Mg, Zn, Cu, or La Halides” Angew. Chem. Int. Ed. 2015, in print.
- 691. Shen, Z.-L.; Sommer, K.; Knochel, P.* “Expedient Preparation of Aryllithium and Arylzinc Reagents from Aryl Chlorides Using Lithium 4,4'-Di-tert-Butylbiphenylide and Zinc(II) Chloride” Synthesis 2015, in print.
- 692. Schluecker, T.; Dhayalan, V.; Langhals, H.; Saemann, C.; Knochel, P.* „Soluble Adamantyl-Substituted Oligothiophenes with Short Fluorescence Decay: An Approach for Ultrafast Optical Signal Processing” Asian J. Org. Chem. 2015, in print.
- 693. Haas, D.; Hammann, J. M.; Moyeux, A.; Cahiez, G.; Knochel, P.* „Oxidative Homocoupling of Diheteroaryl- or Diarylmanganese Reagents Generated via Directed Manganation Using TMP2Mn” Synlett 2015, in print.
- 694. Ellwart, M.; Knochel, P.* “Preparation of Solid, Substituted Allylic Zinc Reagents and Their Reactions with Electrophiles” Angew. Chem. Int. Ed. 2015, 54, 10662-10665.
- 695. Becker, M. R.; Ganiek, M. A.; Knochel, P.* “Practical and economic lithiations of functionalized arenes and heteroarenes using Cy2NLi in the presence of Mg, Zn or La halides in a continuous flow” Chem. Science 2015, 6, 6649-6653.
- 696. Moriya, K.; Simon, M.; Mose, R.; Karaghiosoff, K.; Knochel, P.* „Stereoselective retentive domino transmetalations of secondary alkyllithium compounds to functionalized secondary alkylcopper reagents” Angew. Chem. Int. Ed. 2015, 54, 10963-10967.
- 697. Dhayalan, Vasudevan; Knochel, P.* “Synthesis of polyfunctional secondary amines by the reaction of functionalized organomagnesium reagents with tertiary nitroalkanes” Synthesis 2015, 47, 3246-3256.
- 698. Quinio, P.; Roman, D. S.; Leon, T.; William, S.; Karaghiosoff, K.; Knochel, P.* “Transition-Metal-Free Cross-Coupling of Aryl and N-Heteroaryl Cyanides with Benzylic Zinc Reagents” Org. Lett. 2015, 17, 4396-4399.
- 699. Dhayalan, Vasudevan; Alcaniz, F. R.; Werner, V.; Karaghiosoff, K.; Knochel, P.* „Preparation of a New Spirobi[thieno[2,3-c]pyran] and Its Selective Mono- and Dimetalation: Application for the Preparation of Soluble Conjugated Oligothiophenes and Pyrene Derivatives” Synthesis 2015, Synthesis 2015, 47, 3972-3982.
- 700. Nafe, J.; Auras, F.; Karaghiosoff, K.; Bein, T.; Knochel, P.* “Selective Functionalization of Tetrathiafulvalene Using Mg- and Zn-TMP-Bases: Preparation of Mono-, Di-, Tri-, and Tetrasubstituted Derivatives” Org. Lett. 2015, 17, 5356-5359.
- 701. Moegling, J.; Benischke, A. D.; Hammann, J. M.; Veprek, N. A.; Zoller, F.; Rendenbach, B.; Hoffmann, A.; Sievers, H.; Schuster, M.; Knochel, P.*; Herres-Pawlis, S. “Bis(pyrazolyl)methane Copper Complexes as Robust and Efficient Catalysts for Sonogashira Couplings” Eur. J. Org. Chem. 2015, 7475–7483.
- 702. Druzhinin, S. I.; Galievsky, V. A.; Demeter, A.; Kovalenko, S. A.; Senyushkina, T. A.; Dubbaka, S. R.; Knochel, P.*; Mayer, P.; Grosse, C.; Stalke, D.; Zachariasse, K. A. “Two-State Intramolecular Charge Transfer (ICT) with 3,5-Dimethyl-4-(Dimethylamino)benzonitrile (MMD) and Its Meta-Isomer mMMD. Ground State Amino Twist Not Essential for ICT” J. Phys. Chem. A 2015, J. Phys. Chem. A 2015, 119, 11820-11836.
- 703. Moriya, K.; Simon, M.; Mose, R.; Karaghiosoff, K.; Knochel, P.* “Stereoselective retentive domino transmetalations of secondary alkyllithium compounds to functionalized secondary alkylcopper reagents [Erratum to document cited in CA163:373882]” Angew. Chem. Int. Ed. 2015, 54, 12537.
- 704. Ren, H.; Knochel, P.* “Chemoselective benzylic C-H activations for the preparation of condensed N-heterocycles [Erratum to document cited in CA145:188632]” Angew. Chem. Int. Ed. 2015, 54, 8584.
- 705. Ren, H.; Li, Z.; Knochel, P.* “Chemoselective C(sp3)-H Activations for the Preparation of Condensed N-Heterocycles” (CORRIGENDUM) Chem. Asian J. 2015, 10, 1812.
- 706. Snieckus, V.; Knochel, P.* “Cluster Preface: Resurgence of Synthetic Aromatic Chemistry” Synlett 2015, 26, 2782-2783.
- 707. Castello-Mico, Alicia; Herbert, Simon A.; Leon, Thierry; Bein, Thomas; Knochel, P.* “Functionalizations of Mixtures of Regioisomeric Aryllithium Compounds by Selective Trapping with Dichlorozirconocene” Angew. Chem. Int. Ed. 2016, 55, 401.
- 708. Greiner, R.; Blanc, R.; Petermayer, C.; Karaghiosoff, K.; Knochel, P.* “Preparation of Functionalized 2,7-Naphthyridines by Directed Lithiation with (2,2,6,6-Tetramethylpiperidyl)lithium and Their Regioselective Iron-Catalyzed Cross Couplings” Synlett 2016, 27, 231-236.
- 709. Nafe, J.; Knochel, P.* “Selective Metalation of 1,3-Dithiole-2-thiones: An Effective Preparation of New Symmetrically and Nonsymmetrically Tetraarylated Tetrathiafulvalenes” Synthesis 2016, 48, 103-114.
- 710. Benischke, A. D.; Ellwart, M.; Becker, M. R.; Knochel, P.* „Polyfunctional Zinc and Magnesium Organometallics for Organic Synthesis: Some Perspectives” Synthesis 2016, 48, 1101-1107.
- 711. Benischke, A. D.; Knoll, I.; Rerat, A.; Gosmini, C.; Knochel, P.* „A practical cobalt-catalyzed cross-coupling of benzylic zinc reagents with aryl and heteroaryl bromides or chlorides” Chem. Comm. 2016, 52, 3171-3174.
- 712. Haas, D.; Hammann, J. M.; Greiner, R.; Knochel, P.* “Recent Developments in Negishi Cross-Coupling Reactions” ACS Catal. 2016, 6, 1540-1552.
- 713. Ganiek, M. A.; Becker, M. R.; Ketels, M.; Knochel, P.* “Continuous Flow Magnesiation or Zincation of Acrylonitriles, Acrylates, and Nitroolefins. Application to the Synthesis of Butenolides” Org. Lett. 2016, 18, 828-831.
- 714. Benischke, A. D.; Breuillac, A. J. A.; Moyeux, A.; Cahiez, G.; Knochel, P.* “Iron-Catalyzed Cross-Coupling of Benzylic Manganese Chlorides with Aryl and Heteroaryl Halides” Synlett 2016, 27, 471-476.
- 715. Haas, D.; Hammann, J. M.; Lutter, F. H.; Knochel, P.* “Mild Cobalt-Catalyzed Negishi Cross-Couplings of (Hetero)arylzinc Reagents with (Hetero)aryl Halides” Angew. Chem., Int. Ed. 2016, 55, 3809-3812.
- 716. Klier, L.; Aranzamendi, E.; Ziegler, D.; Nickel, J.; Karaghiosoff, K.; Carell, T.; Knochel, P.* „Lewis Acid Triggered Regioselective Magnesiation and Zincation of Uracils, Uridines, and Cytidines” Org. Lett. 2016, 18, 1068-1071.
- 717. Barroso, S.; Lemaire, S.; Farina, V.; Steib, A. K.; Blanc, R.; Knochel, P.* “Cine Substitution with Arylzinc Reagents: Scope and Mechanistic Studies” J. Org. Chem. 2016, 81, 2804-2816.
- 718. Becker, M. R.; Knochel, P.* „High-Temperature Continuous-Flow Zincations of Functionalized Arenes and Heteroarenes Using (Cy2N)2Zn•2LiCl” Org. Lett. 2016, 18, 1462-1465.
- 719. Lohse, M. S.; Rotter, J. M.; Margraf, J. T.; Werner, V.; Becker, M.; Herbert, S.; Knochel, P.*; Clark, T.; Bein, T.; Medina, D. D. „From benzodithiophene to diethoxy-benzodithiophene covalent organic frameworks - structural investigations” CrystEngComm 2016, in print.
- 720. Shen, Z.-L.; Dhayalan, V.; Benischke, A. D.; Greiner, R.; Karaghiosoff, K.; Mayer, P.; Knochel, P.* „Polyfunctional Lithium, Magnesium, and Zinc Alkenyl Reagents as Building Blocks for the Synthesis of Complex Heterocycles” Angew. Chem., Int. Ed. 2016, in print.
- 721. Quinio, P.; Kohout, L.; Roman, D. S.; Gaar, J.; Karaghiosoff, K.; Knochel, P.* „Sc(OTf)3-Catalyzed Addition of Bromomagnesium 2-Vinyloxy Ethoxide to Various Aldehydes Leading to Protected Aldol Products” Synlett 2016, in print.
- 722. Moriya, K.; Schwaerzer, K.; Karaghiosoff, K.; Knochel, P.* „Stereoselective Synthesis of Secondary Alkyllithiums and Their Application to Stereoselective Cuprations or Intramolecular Carbolithiations for the Stereoselective Synthesis of Alkylidenecyclobutanes” Synthesis 2016, 48, 3141-3154.
-
723. Morozova, V.; Moriya, K.; Mayer, P.; Knochel, P.* “Stereoselective Synthesis and Retentive Trapping of α-Chiral Secondary Alkyllithiums Leading to Stereodefined α,β-Dimethyl Carboxylic Esters” Chem. Eur. J. 2016, 22, 9962-9965.
-
724. Fernandez, S.; Ganiek, M. A.; Karpacheva, M.; Hanusch, F. C.; Reuter, S.; Bein, T.; Auras, F.; Knochel, P.* „Synthesis and Reactivity of Triazaphenanthrenes” Org. Lett. 2016, 18, 3158-3161.
-
725. Ellwart, M.; Makarov, I. S.; Achrainer, F.; Zipse, H.; Knochel, P.* „Regioselective Transition-Metal-Free Allyl-Allyl Cross-Couplings” Angew. Chem. Int. Ed. 2016, 55, 10502-10506.
-
726. Benischke, A. D.; Leroux, M.; Knoll, I.; Knochel, P.* „Iron-Catalyzed Acylation of Polyfunctionalized Aryl- and Benzylzinc Halides with Acid Chlorides” Org. Lett. 2016, 18, 3626-3629.
-
727. Nickel, J.; Fernandez, M.; Klier, L.; Knochel, P.* „Synthesis of Pyrrolo[2,3-d]pyrimidines by Copper-Mediated Carbomagnesiations of N-Sulfonyl Ynamides and Application to the Preparation of Rigidin A and a 7-Azaserotonin Derivative” Chem. Eur. J. 2016, 22, 14397-14400.
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728. Hammann, J. M.; Haas, D.; Tüllmann, C.-P.; Karaghiosoff, K.; Knochel, P.* „Diastereoselective Cobalt-Mediated Cross-Couplings of Cycloalkyl Iodides with Alkynyl or (Hetero)Aryl Grignard Reagents” Org. Lett. 2016, 18, 4778−4781.
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729. Greshock, T. J.;* Moore, K. P.; McClain, R. T.; Bellomo, A.; Chung, C. K.; Dreher, S. D.; Kutchukian, P. S.; Peng, Z.; Davies, I. W.; Vachal, P.; Ellwart, M.; Manolikakes, S M.; Knochel, P.* and Nantermet, P. G. “Synthesis of Complex Druglike Molecules by the Use of Highly Functionalized Bench-Stable Organozinc Reagents” Angew. Chem. Int. Ed. 2016, 55, 13714-13718.
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730. Knochel, P. “Jean F. Normant (1936-2016)“ Angew. Chem. Int. Ed. 2016, 55, 13376.
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731. Haas, D.; Sustac-Roman, D.; Schwarz, S.; Knochel, P.* „Directed Zincation with TMPZnCl·LiCl and Further Functionalization of the Tropolone Scaffold” Org. Lett. 2016, 18, 6380-6383.
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732. Hofmayer, M. S.; Hammann, J. M.; Haas, D.; Knochel, P.* „Cobalt-Catalyzed C(sp2)-C(sp3) Cross-Coupling Reactions of Diarylmanganese Reagents with Secondary Alkyl Iodides” Org. Lett. 2016, 18, 6456-6459.
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733. Bellan, A. B.; Kuzmina, O. M.; Vetsova, V. A.; Knochel, P.* „Chromium-Catalyzed Cross-Coupling Reactions of Alkylmagnesium Reagents with Halo-Quinolines and Activated Aryl Chlorides” Synthesis 2017, 49, 188-194.
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734. Cai, Y.; Benischke, A. D.; Knochel, P.*; Gosmini, C. „Cobalt-Catalyzed Reductive Cross-Coupling Between Styryl and Benzyl Halides” Chem. Eur. J. 2017, 23, 250-253.
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735. Benischke, A. D.; Le Corre, G.; Knochel, P.* „Preparation of Polyfunctional Organozinc Halides by an InX3- and LiCl-Catalyzed Zinc Insertion to Aryl and Heteroaryl Iodides and Bromides” Chem. Eur. J. 2017, 23, 778-782.
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736. Hammann, Jeffrey M.; Lutter, Ferdinand H.; Haas, Diana; Knochel, P.* “A Robust and Broadly Applicable Cobalt-Catalyzed Cross-Coupling of Functionalized Bench-Stable Organozinc Pivalates with Unsaturated Halides” Angew. Chem. Int. Ed. 2017, 56, 1082-1086.
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737. Castello-Mico, A.; Nafe, J.; Higashida, K.; Karaghiosoff, K.; Gingras, M.; Knochel, P.* „ Selective Metalations of 1,4-Dithiins and Condensed Analogues Using TMP-Magnesium and -Zinc Bases” Org. Lett. 2017, 19, 360-363.
-
738. Balkenhohl, M.; Francois, C.; Sustac-Roman, D.; Quinio, P.; Knochel, P.* “Transition-Metal-Free Amination of Pyridine-2-sulfonyl Chloride and Related N-Heterocycles Using Magnesium Amides” Org. Lett. 2017, 19, 536-539.
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739. Knochel, P. „Preface - Burgenstock Junior Contributions” Synthesis 2017, 49, 775.
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740. Ketels, M.; Konrad, D. B.; Karaghiosoff, K.; Trauner, D.; Knochel, P.* „Selective Lithiation, Magnesiation, and Zincation of Unsymmetrical Azobenzenes Using Continuous Flow” Org. Lett. 2017, 19, 1666-1669.
-
741. Klier, L.; Ziegler, D. S.; Rahimoff, R.; Mosrin, M.; Knochel, P.* „Practical Large-Scale Regioselective Zincation of Chromone Using TMPZnCl·LiCl Triggered by the Presence or Absence of MgCl2” Org. Process Res. Dev. 2017, 21, 660-663.
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742. Chen, Y.-H.; Ellwart, M.; Toupalas, G.; Ebe, Y.; Knochel, P.* „Preparation and Application of Solid, Salt-Stabilized Zinc Amide Enolates with Enhanced Air and Moisture Stability” Angew. Chem. Int. Ed. 2017, 56, 4612-4616.
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743. Hofmayer, M. S.; Hammann, J. M.; Lutter, F. H.; Knochel, P.* „Large-Scale Cobalt-Catalyzed Cross-Couplings of Functionalized Bench-Stable Arylzinc Pivalates with (Hetero)Aryl and Alkenyl Halides” Synthesis 2017, in print.
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744. Rager, S.; Dogru, M.; Werner, V.; Gavryushin, A.; Goetz, M.; Engelke, H.; Medina, D. D.; Knochel, P.*; Bein, T. „Pore wall fluorescence labeling of covalent organic frameworks” CrystEngComm 2017, 19, 4886-4891.
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745. Hammann, J. M.; Hofmayer, M. S.; Lutter, F. H.; Thomas, L.; Knochel, P.* “Recent Advances in Cobalt-Catalyzed Csp2 and Csp3 Cross-Couplings” Synthesis 2017, 49, 3887-3894.
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746. Chen, Y.-H.; Ellwart, M.; Malakhov, V.; Knochel, P.* „Solid organozinc pivalates: a new class of zinc organometallics with greatly enhanced air- and moisture-stability” Synthesis 2017, 49, 3215-3223.
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747. Ketels, M.; Ziegler, D. S.; Knochel, P.* „Selective Zincation of 1,2-Dicyanobenzene and Related Benzonitriles in Continuous Flow Using In Situ Trapping Metalations” Synlett 2017, in print.
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748. Chen, Y.-H.; Tuellmann, C. P.; Ellwart, M.; Knochel, P.* „Preparation of Solid Polyfunctional Alkynylzinc Pivalates with Enhanced Air and Moisture Stability for Organic Synthesis” Angew. Chem. Int. Ed. 2017, 56, 9236-9239.
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749. Hammann, J. M.; Thomas, L.; Chen, Y.-H.; Haas, D.; Knochel, P.* „Cobalt-Catalyzed Cross-Couplings of Bench-Stable Alkynylzinc Pivalates with (Hetero)Aryl and Alkenyl Halides” Org. Lett. 2017, 19, 3847-3850.
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750. Nishii, Y.; Hirai, T.; Fernandez, S.; Knochel, P.*; Mashima, K. „Zinc-Catalyzed Esterification of N-β-Hydroxyethylamides: Removal of Directing Groups under Mild Conditions” Eur. J. Org. Chem. 2017, 5010-5014.
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7751. Ganiek, M. A.; Becker, M. R.; Berionni, G.; Zipse, H.; Knochel, P.* „Barbier Continuous Flow Preparation and Reactions of Carbamoyllithiums for Nucleophilic Amidation” Chem. Eur. J. 2017, 23, 10280-10284.
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752. Knochel, P.* “Preface - Special Issue Dedicated to Professor Herbert Mayr” Synthesis 2017, 49, I.
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753. Balkenhohl, Moritz; Greiner, Robert; Makarov, Ilya S.; Heinz, Benjamin; Karaghiosoff, Konstantin; Zipse, Hendrik; Knochel, P.* „Zn-, Mg-, and Li-TMP Bases for the Successive Regioselective Metalations of the 1,5-Naphthyridine Scaffold (TMP=2,2,6,6-Tetramethylpiperidyl)” Chem. Eur. J. 2017, 23, 13046-13050.
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754. Nishii, Y.; Hirai, T.; Fernandez, S.; Knochel, P.*; Mashima, K. „Cover Feature: Zinc-Catalyzed Esterification of N-β-Hydroxyethylamides: Removal of Directing Groups under Mild Conditions (Eur. J. Org. Chem. /2017)“ Eur. J. Org. Chem. 2017, 4995.
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755. Ellwart, M.; Hoefner, G.; Gerwien, A.; Wanner, K. T.; Knochel, P.* „Synthesis and Bioactivity of Novel N-Benzylic and N-Phenethylic Ephedrine Derivatives” Synthesis 2017, in print.
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756. Castello-Mico, A.; Knochel, P.* “Zincation and Magnesiation of Functionalized Silylated Cyanohydrins Using TMP-Bases” Synthesis 2017, in print.
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757. Makarov, I. S.; Brocklehurst, C. E.; Karaghiosoff, K.; Koch, G.; Knochel, P.* „Synthesis of Bicyclo[1.1.1]pentane Bioisosteres of Internal Alkynes and para-Disubstituted Benzenes from [1.1.1]Propellane” Angew. Chem. Int. Ed. 2017, 56, 12774-12777.
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758. Hofmayer, M. S.; Hammann, J. M.; Cahiez, G.; Knochel, P.* „Iron-Catalyzed C(sp2)-C(sp3) Cross-Coupling Reactions of Di(hetero)arylmanganese Reagents and Primary and Secondary Alkyl Halides” Synlett 2017, in print.
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759. Ketels, M.; Ganiek, M. A.; Weidmann, N.; Knochel, P.* „Synthesis of Polyfunctional Diorganomagnesium and Diorganozinc Reagents through In Situ Trapping Halogen-Lithium Exchange of Highly Functionalized (Hetero)aryl Halides in Continuous Flow” Angew. Chem. Int. Ed. 2017, 56, 12770-12773.
- 760. Greiner, R.; Ziegler, D. S.; Cibu, D.; Jakowetz, A. C.; Auras, F.; Bein, T.; Knochel, P.* „Preparation of Polyfunctional Naphthyridines by Cobalt-Catalyzed Cross-Couplings of Halogenated Naphthyridines with Magnesium and Zinc Organometallics” Org. Lett. 2017, 19, 6384-6387.
- 761. Ziegler, D. S.; Greiner, R.; Lumpe, H.; Kqiku, L.; Karaghiosoff, K.; Knochel, P.* „Directed Zincation or Magnesiation of the 2-Pyridone and 2,7-Naphthyridone Scaffold Using TMP Bases” Org. Lett. 2017, 19, 5760-5763.
- 762. Benischke, A. D.; Anthore-Dalion, L.; Berionni, G.; Knochel, P.* „Preparation of Functionalized Diaryl- and Diheteroaryllanthanum Reagents by Fast Halogen-Lanthanum Exchange” Angew. Chem. Int. Ed. 2017, 56, 16390-16394.
- 763. Knochel, P. “Zinc1” e-EROS Encyclopedia of Reagents for Organic Synthesis 2017, 1-18.
- 764. Chen, Yi-H.; Grassl, S.; Knochel, P.* “Cobalt-Catalyzed Electrophilic Amination of Aryl- and Heteroarylzinc Pivalates with N-Hydroxylamine Benzoates” Angew. Chem. Int. Ed. 2018, 57, 1108-1111.
- 765. Morozova, V.; Skotnitzki, J.; Moriya, K.; Karaghiosoff, K.; Knochel, P.* “Preparation of Optically Enriched Secondary Alkyllithium and Alkylcopper Reagents-Synthesis of (-)-Lardolure and Siphonarienal” Angew. Chem. Int. Ed. 2018, 57, 5516-5519.
- 766. Thomas, L.; Lutter, F. H.; Hofmayer, M. S.; Karaghiosoff, K.; Knochel, P.* “Cobalt-Catalyzed Diastereoselective Cross-Couplings between Alkynylzinc Pivalates and Functionalized Cyclic Iodides or Bromides” Org. Lett. 2018, 20, 2441-2444.
- 767. Skotnitzki, J.; Morozova, V.; Knochel, P.* “Diastereoselective Copper-Mediated Cross-Couplings between Stereodefined Secondary Alkylcoppers with Bromoalkynes” Org. Lett. 2018, 20, 2365-2368.
- 768. Ziegler, D. S.; Karaghiosoff, K.; Knochel, P.* „Generation of Aryl and Heteroaryl Magnesium Reagents in Toluene by Br/Mg or Cl/Mg Exchange” Angew. Chem. Int. Ed. 2018, 57, 6701-6704.
- 769. Balkenhohl, M.; Salgues, B.; Hirai, T.; Karaghiosoff, K.; Knochel, P.* „Regioselective Metalation and Functionalization of the Pyrazolo[1,5-a]pyridine Scaffold Using Mg- and Zn-TMP Bases” Org. Lett. 2018, 20, 3114-3118.
- 770. Simon, M.; Karaghiosoff, K.; Knochel, P.* „Diastereoselective Intramolecular Carbolithiations of Stereodefined Secondary Alkyllithiums Bearing a Remote Alkynylsilane” Org. Lett. 2018, 20, 3518-3521.
- 770. Benischke, A. D.; Anthore-Dalion, L.; Kohl, F.; Knochel, P.* „Synthesis of Polyfunctionalized Triaryllanthanum Reagents by Using Ph3La and Related Species as Exchange Reagents” Chem.Eur. J. 2018, 24, 11103-11109.
- 771. Weidmann, N.; Ketels, M.; Knochel, P.* „Sodiation of Arenes and Heteroarenes in Continuous Flow” Angew. Chem. Int. Ed. 2018, 57, 10748-10751.
- 772. Tuellmann, Carl Phillip; Chen, Yi-Hung; Schuster, Robin J.; Knochel, P.* „Preparation and Reactions of Mono- and Bis-Pivaloyloxyzinc Acetylides” Org. Lett. 2018, 20, 4601-4605.
- 773. Li, J.; Knochel, P.* “Cobalt-Catalyzed Cross-Couplings between Alkenyl Acetates and Aryl or Alkenyl Zinc Pivalates” Angew. Chem. Int. Ed. 2018, 57, 11436-11440.
- 774. Ziegler, D. S.; Klier, L.; Mueller, N.; Karaghiosoff, K.; Knochel, P.* „ Directed Zincation or Magnesiation of 2- and 4-Pyrones and Their Derivatives” Synthesis 2018, 50, 4383-4394.
- 775. Ellwart, M.; Chen, Y.-H.; Tuellmann, C. P.; Malakhov, V.; Knochel, P.* „Preparation of solid organozinc pivalates and their reaction in Pd-catalyzed cross-couplings” Org. Synth. 2018 , 95, 127-141.
- 776. Knochel, P.* “Preface - Special Issue Dedicated to Professor Scott E. Denmark in Honor of his 65th Birthday” Synthesis 2018, 50, 22.
- 777. Dong, Z.-B.; Balkenhohl, M.; Tan, E.; Knochel, P.* „Synthesis of Functionalized Diaryl Sulfides by Cobalt-Catalyzed Coupling between Arylzinc Pivalates and Diaryl Disulfides” Org. Lett. 2018, 20, 7581-7584.
- 778. Ganiek, M. A.; Ivanova, M. V.; Martin, B.; Knochel, P.* „Mild Homologation of Esters through Continuous Flow Chloroacetate Claisen Reactions” Angew. Chem. Int. Ed. 2018, 57, 17249-17253.
- 779. Balkenhohl, M.; Heinz, B.; Abegg, T.; Knochel, P.* „Amination of Phosphorodiamidate-Substituted Pyridines and Related N-Heterocycles with Magnesium Amides” Org. Lett. 2018, 20, 8057-8060.
- 780. Ziegler, D. S.; Wei, B.; Knochel, P.* „Improving the Halogen-Magnesium Exchange by using New Turbo-Grignard Reagents” Chem.Eur. J. 2018, 25, 2695 – 2703.
- 781. Hofmayer, M. S.; Lutter, F. H.; Grokenberger, L.; Hammann, J. M.; Knochel, P.* „Practical Ni-Catalyzed Cross-Coupling of Unsaturated Zinc Pivalates with Unsaturated Nonaflates and Triflates” Org. Lett. 2019, 21, 36-39.
- 782. Li, J.; Tan, E.; Keller, N.; Chen, Y.-H.; Zehetmaier, P. M.; Jakowetz, A- C.; Bein, T.; Knochel, P.* „Cobalt-Catalyzed Electrophilic Aminations with Anthranils: An Expedient Route to Condensed Quinolines” J. Am. Chem. Soc. 2019, 141, 98-103.
- 783. Grassl, S.; Chen, Y.-H.; Hamze, C.; Tuellmann, C. P.; Knochel, P.* „Late Stage Functionalization of Secondary Amines via a Cobalt-Catalyzed Electrophilic Amination of Organozinc Reagents” Org. Lett. 2019, 21, 494-497.
- 784. Skotnitzki, J.; Spessert, L.; Knochel, P.* „Regio- and Stereoselective Allylic Substitutions of Chiral Secondary Alkylcopper Reagents: Total Synthesis of (+)-Lasiol, (+)-13-Norfaranal, and (+)-Faranal” Angew. Chem. Int. Ed. 2019, 58, 1509-1514.
- 785. Bellan, A. B.; Knochel, P.* „Highly Regioselective Remote Lithiation of Functionalized 1,3-bis-Silylated Arenes” Angew. Chem. Int. Ed. 2019, 58, 1838-1841.
- 786. Grassl, S.; Hamze, C.; K., Koller, T. J.; Knochel, P.* “Copper-Catalyzed Electrophilic Thiolation of Organozinc Halides by Using N-Thiophthalimides Leading to Polyfunctional Thioethers” Chem.Eur. J. 2019, 25, 3752-3755.
- 787. Lemaire, S.; Diene, C.; Gavryushin, A.; Du Jourdin, X. M.; Paolini, L.; Jusseau, X.; Knochel, P.* „Preparation of 2'-Deoxy-2'-spirocyclopropylcytidine via an Alternative Cyclopropanation Reaction” J. Org. Chem. 2019, 84, 4910−4914.
- 788. Anthore-Dalion, L.; Benischke, A. D.; Wei, B.; Berionni, G.; Knochel, P.* „The Halogen-Samarium Exchange Reaction: Synthetic Applications and Kinetics” Angew. Chem. Int. Ed. 2019, 58, 4046-4050.
- 789. Balkenhohl, M.; Valsamidou, V.; Knochel, P.* “Amination of 2-pyridinesulfonic and 8-quinolinesulfonic acids with magnesium amides” Eur. J. Org. Chem. 2019, 31-32, 5165-5168.
- 790. Lutter, F. H.; Grassl, S.; Grokenberger, L.; Hofmayer, M. S.; Chen, Y.-H.; Knochel, P.* „Cobalt-Catalyzed Cross-Couplings and Electrophilic Aminations using Organozinc Pivalates” ChemCatChem 2019, 11, 5188-5197.
- 791. Li, J.; Knochel, P.* “Chromium-Catalyzed Cross-Couplings and Related Reactions” Synthesis 2019, 51, 2100-2106.
- 792. Schwaerzer, K.; Bellan, A.; Zoeschg, M.; Karaghiosoff, K.; Knochel, P.* „Magnesium Aldimines Prepared by Addition of Organomagnesium Halides to 2,4,6-Trichlorophenyl Isocyanide: Synthesis of 1,2-Dicarbonyl Derivatives” Chem. Eur. J. 2019, 25, 1–5.
- 793. Leroux, M.; Vorherr, T.; Lewis, I.; Schaefer, M.; Koch, G.; Karaghiosoff, K.; Knochel, P.* „Late-Stage Functionalization of Peptides and Cyclopeptides Using Organozinc Reagents” Angew. Chem. Int. Ed. 2019, 58, 8231 –8234.
- 794. Bouarfa, S.; Grassl, S.; Ivanova, M.; Langlais, T.; Bentabed-Ababsa, G.; Lassagne, F.; Erb, W.; Roisnel, T.; Dorcet, V.; Knochel, P.* “Copper- and Cobalt-Catalyzed Syntheses of Thiophene-Based Tertiary Amines” Eur. J. Org. Chem. 2019, 3244-3258.
- 795. Balkenhohl, M.; Jangra, H.; Lenz, T.; Ebeling, M.; Zipse, H.; Karaghiosoff, K.; Knochel, P.* „Lewis Acid Directed Regioselective Metalations of Pyridazine” Angew. Chem. Int. Ed. 2019, 58, 9244–9247.
- 796. Bellan, A. B.; Knochel, P.* “Steric-Hindrance Triggered Remote Lithiations of Bulky Silyl-Substituted Arenes” Synthesis 2019, 51, 3536-3544.
- 797. Lutter, F. H.; Grokenberger, L.; Hofmayer, M. S.; Knochel, P.* „Cobalt-catalyzed acylation-reactions of (hetero)arylzinc pivalates with thiopyridyl ester derivatives” Chem. Sci. 2019, 10, 8241-8245.
- 798. Balkenhohl, M.; Ziegler, D. S.; Desaintjean, A.; Bole, L. J.; Kennedy, A. R.; Hevia, E.; Knochel, P.* „Preparation of Polyfunctional Arylzinc Organometallics in Toluene by Halogen/Zinc Exchange Reactions” Angew. Chem. Int. Ed. 2019, 58, 12898-12902.
- 799. Heinz, B.; Balkenhohl, M.; Knochel, P.* „Thiolation of Pyridine-2-sulfonamides using Magnesium Thiolates” Synthesis 2019, 51, 4452-4462.
- 800. Wei, B.; Zhang, D.; Chen, Y.-H.; Lei, A.; Knochel, P.* „Preparation of Polyfunctional Biaryl Derivatives by Cyclolanthanation of 2-Bromobiaryls and Heterocyclic Analogues Using nBu2LaCl·4LiCl” Angew. Chem. Int. Ed. 2019, 58, 15631 –15635.
- 801. Skotnitzki, J.; Kremsmair, A.; Knochel, P.* „Stereoselective Preparation and Reactions of Chiral Secondary Alkyllithiums” Synthesis 2019, 52, 189-196.
- 802. Desaintjean, A.; Belrhomari, S.; Rousseau, L.; Lefevre, G.; Knochel, P.* “Iron-Catalyzed Cross-Coupling of Functionalized Benzylmanganese Halides with Alkenyl Iodides, Bromides, and Triflates” Org. Lett. 2019, 21, 8684−8688.
- 803. Li, J.; Ren, Q.; Cheng, X.; Karaghiosoff, K.; Knochel, P.* „Chromium(II)-Catalyzed Diastereoselective and Chemoselective Csp2-Csp3 Cross-Couplings Using Organomagnesium Reagents” J. Am. Chem. Soc. 2019, 141, 18127−18135.
- 804. Lutter, F. H.; Hofmayer, M. S.; Hammann, J. M.; Malakhov, V.; Knochel, P.* „Generation and trapping of functionalized aryl- and heteroarylmagnesium and -zinc compounds” Org. React. (Hoboken, NJ, United States) 2019, 100, 63-116.
- 805. Skotnitzki, J.; Kremsmair, A.; Keefer, D.; Gong, Y.; de Vivie-Riedle, R.; Knochel, P.* „Stereoselective Csp3-Csp2 Cross-Couplings of Chiral Secondary Alkylzinc Reagents with Alkenyl and Aryl Halides” Angew. Chem. Int. Ed. 2020, 59, 320-324.
- 806. Grassl, S.; Singer, J.; Knochel, P.* „Iron-Mediated Electrophilic Amination of Organozinc Halides using Organic Azides” Angew. Chem. Int. Ed. 2020, 59, 335-338.
- 807. Skotnitzki, J.; Kremsmair, A.; Kicin, B.; Saeb, R.; Ruf, V.; Knochel, P.* „Stereoselective anti-SN2'-Substitutions of Secondary Alkylcopper-Zinc Reagents with Allylic Epoxides: Total Synthesis of (3S,6R,7S)-Zingiberenol” Synthesis 2020, 52, 873-881.
- 808. Heinz, B.; Djukanovic, D.; Ganiek, M. A.; Martin, B.; Schenkel, B.; Knochel, P.* „Selective Acylation of Aryl- and Heteroarylmagnesium Reagents with Esters in Continuous Flow” Org. Lett. 2020, 22, 493-496.
- 809. Balkenhohl, M.; Knochel, P.* „Recent Advances of the Halogen-Zinc Exchange Reaction” Chem. Eur. J. 2020, 26, 3688-3697.
- 810. Hofmayer, M. S.; Sunagatullina, A.; Broesamlen, D.; Mauker, P.; Knochel, P.* “Stereoselective Cobalt-Catalyzed Cross-Coupling Reactions of Arylzinc Chlorides with α-Bromolactones and Related Derivatives” Org. Lett. 2020, 22, 1286-1289.
- 811. Grassl, S.; Knochel, P.* „Preparation of Tertiary Amines from Tris(2-cyanoethyl)amine Using Three Successive Cobalt-Catalyzed Electrophilic Aminations with Organozinc Halides” Org. Lett. 2020, 22, 1947-1950.
- 812. Schwaerzer, K.; Tuellmann, C. P.; Grassl, S.; Gorski, B.; Brocklehurst, C. E.; Knochel, P.* „Functionalization of 1,3,4-Oxadiazoles and 1,2,4-Triazoles via Selective Zincation or Magnesiation Using 2,2,6,6-Tetramethylpiperidyl Bases” Org. Lett. 2020, 22, 1899-1902.
- 813. Lutter, F. H.; Grokenberger, L.; Spiess, P.; Hammann, J. M.; Karaghiosoff, K.; Knochel, P.* „Cobalt-Catalyzed Cross-Coupling of Functionalized Alkylzinc Reagents with (Hetero)Aryl Halides” Angew. Chem. Int. Ed. 2020, 59, 5546-5550.
- 814. Tuellmann, C. P.; Steiner, S.; Knochel, P.* „Preparation and Reactions of (1H-Tetrazol-5-yl)zinc Pivalates” Synthesis 2020, 52, 2357-2363.
- 815. Rousseau, L.; Desaintjean, A.; Knochel, P.*; Lefevre, G. “Iron-catalyzed cross-coupling of Bis-(aryl)manganese nucleophiles with alkenyl halides: optimization and mechanistic investigations” Molecules 2020, 25, 723.
- 816. Lutter, F. H.; Grokenberger, L.; Benz, M.; Knochel, P.* „Cobalt-Catalyzed Csp3-Csp3 Cross-Coupling of Functionalized Alkylzinc Reagents with Alkyl Iodides” Org. Lett. 2020, 22, 3028-3032.
- 817. Harenberg, J. H.; Weidmann, N.; Knochel, P.* „Preparation of Functionalized Aryl, Heteroaryl, and Benzylic Potassium Organometallics Using Potassium Diisopropylamide in Continuous Flow” Angew. Chem. Int. Ed. 2020, 59, 12321–12325.
- 818. Skotnitzki, J.; Kremsmair, A.; Keefer, D.; Schueppel, F.; Le Cacher de Bonneville, B.; de Vivie-Riedle, R.; Knochel, P.* „Regio- and diastereoselective reactions of chiral secondary alkylcopper reagents with propargylic phosphates: preparation of chiral allenes” Chem. Sci., 2020, 11, 5328–5332.
- 819. Balkenhohl, M.; Jangra, H.; Makarov, I. S.; Yang, S.-M.; Zipse, H.; Knochel, P.* „A Predictive Model Towards Site-Selective Metalations of Functionalized Heterocycles, Arenes, Olefins, and Alkanes using TMPZnCl·LiCl” Angew. Chem. Int. Ed. 2020, 59, 14992-14999.
- 820. Nishimura, R. H. V.; Weidmann, N.; Knochel, P.* „Preparation of Diorganomagnesium Reagents by Halogen-Lithium Exchange of Functionalized Heteroaryl Halides and Subsequent in situ Trapping with MgCl2·LiCl in Continuous Flow” Synthesis 2020, 52, 3036–3046.
- 821. Leroux, M.; Huang, W.-Y.; Lemke, Y.; Koller, T. J.; Karaghiosoff, K.; Knochel, P.* „Pyrrole-Protected β-Aminoalkylzinc Reagents for the Enantioselective Synthesis of Amino-Derivatives” Chem. Eur. J. 2020, 26, 8951-8957.
- 822. Weidmann, N.; Harenberg, J. H.; Knochel, P.* „Continuous Flow Preparation of (Hetero)benzylic Lithiums via Iodine-Lithium Exchange Reaction under Barbier Conditions” Org. Lett. 2020, 22, 5895-5899.
- 823. Schwaerzer, K.; Zipse, H.; Karaghiosoff, K.; Knochel, P.* „Highly Regioselective Addition of Allylic and Various Zinc Enolates to [1.1.1]Propellane” Angew. Chem. Int. Ed. 2020, 59, 20235-20241.
- 824. Weidmann, N.; Nishimura, R. H. V.; Harenberg, J. H.; Knochel, P.* „Halogen-Lithium Exchange of Sensitive (Hetero)aromatic Halides under Barbier Conditions in a Continuous Flow Set-Up” Synthesis 2020, in print.
- 825. Kremsmair, A.; Skotnitzki, J.; Knochel, P.* „Diastereo- and Enantioselective Cross-Couplings of Secondary Alkylcopper Reagents with 3-Halogeno-Unsaturated Carbonyl Derivatives” Chem. Eur. J. 2020, 26, 11971-11973.
- 826. Lutter, F. H.; Grokenberger, L.; Perego, L. A.; Broggini, D.; Lemaire, S.; Wagschal, S.; Knochel, P.* „Regioselective functionalization of aryl azoles as powerful tool for the synthesis of pharmaceutically relevant targets” Nature Commun. 2020, 11, 1-8.
- 827. Harenberg, J. H.; Weidmann, N.; Knochel, P.* „Continuous-Flow Reactions Mediated by Main Group Organometallics” Synlett 2020, 31, 1880-1887.
- 828. Harenberg, J. H.; Weidmann, N.; Karaghiosoff, K.; Knochel, P.* „Continuous Flow Sodiation of Substituted Acrylonitriles, Alkenyl Sulfides and Acrylates” Angew. Chem. Int. Ed. 2020, in print.
- 829. Desaintjean, A.; Haupt, T.; Bole, L. J.; Judge, N. R.; Hevia, E.; Knochel, P.* „Regioselective Bromine/Magnesium Exchange for the Selective Functionalization of Polyhalogenated Arenes and Heterocycles” Angew. Chem. Int. Ed. 2020, in print.
Recent patents
- 1. Stuermer, R.; Laupichler, L.; Knochel, P.; Falk, L. “Preparation of optically active phosphine and their metal complexes and their use in asymmetric synthesis” Ger. Offen. 1996, DE 19516968 CAN 126:60177.
- 2. Knochel, P.; Lutz, C. “Method for selective alkylation of aldehydes by organozinc compounds” Ger. Offen. 1999, DE 19809341 CAN 131:144190.
- 3. Boymond, L.; Rottlaender, M.; Cahiez, G.; Knochel, P. “Method for the production of Grignard reagents” PCT Int. Appl. 1999, WO 9951609 CAN 131:257694.
- 4. Knochel, P.; Almena, P. J. J.; Drauz, K.; Klement, I. “Enantioselective hydrogenation of ketoesters, acrylates, and related compounds using C2 symmetric ferrocenylphosphine catalysts” Eur. Pat. Appl. 1999, EP 965574 CAN 132:35472
- 5. Aiscar, B. J. J.; Henkelmann, J.; Preiss, T.; Knochel, P.; Tzalis, D.; Koradin, C. „Process and cesium hydroxide monohydrate catalysts for the hydroamination of a-olefins with amines” Ger. Offen. 2000, DE 19924051 CAN 134:4751.
- 6. Knochel, P.; Duebner, F.; “Copper-catalyzed enantioselective allylic substitution reactions” PCT Int. Appl. 2000, WO 20000309 CAN 139:222063.
- 7. Koradin, C.; Aiscar, B. J. J.; Henkelmann, J.; Preiss, T.; Knochel, P.; Tzalis, D. „Process and catalyst for the preparation of hydroxyalkynes from the addition reaction of terminal alkynes with aldehydes or ketones” Eur. Pat. Appl. 2000, EP 1055656 CAN 134:17164.
- 8. Aiscar, B. J. J.; Henkelmann, J.; Preiss, T.; Knochel, P.; Tzalis, D.; Koradin, C. „Process for the preparation of alkenyl compounds“ Eur. Pat. Appl. 2000, EP 1055653 CAN 134:17163.
- 9. Knochel, P.; Ireland, T.; Grossheimann, G.; Drauz, Karlheinz; Klement, I. „Preparation of alkenylferrocenyldiphosphine ligands and their complexes as enantioselective hydrogenation catalysts” Ger. Offen. 2000, DE 19952348 CAN 133:58941
- 10. Jones, P.; Knochel, P. „Process for transferring a,b-unsaturated alkyl groups to electrophiles” Eur. Pat. Appl. 2000, EP 992474 CAN 132:264749
- 11. Boymond, L.; Rottlaender, M.; Cahiez, G.; Knochel, P. “Procedure for the stereo selective production of Grignard reagent and their use” Ger. Offen 2000, DE 19830599 CAN 132:64398
- 12. Bosch, B. E.; Monsees, A.; Dingerdissen, U.; Knochel, P.; Hupe, E. “Cycloaliphatic/aromatic diphosphines and use thereof in catalysis” PCT Int. Appl. 2002, WO 2002014330 CAN 136:200302.
- 13. Demay, S.; Kotschy, A.; Knochel, P.; Volant, F.; Lotz, M. “Preparation of chiral diphosphines via 2,3 –sigmatropic rearrangement for use in asymmetric transition metal catalysis.” Eur. Pat. Appl. 2002, EP 1182205 CAN 136:200304.
- 14. Henkelmann, J.; Thil, L.; Arndt, J.-D.; Knochel, P.; Koradin, C. “Procedure and catalysts for the production of monopropargyl amines from diaminomethanes and acetylenes” Ger. Offen. 2003, DE 10134160 CAN 138:106430
- 15. Bruchmann, B.; Haeberle, K.; Hoerner, K. D.; Treiber, R.; Renz, T.; Seyffer, H.; Meyer, B.; Wolf, L.; Knochel, P. “ Aqueous polyuretane dispersions produced in the presence of cesiun salts” Ger. Offen. 2003, DE 10161156 CAN 139:37313
- 16. Knochel, P.; Lotz, M.; Monsees, A.; Riermeier, T.; Kadyrov, R.; Almena, J. “Preparation of ferrocenyl phosphine ligands and their use in catalysis” PCT Int. Appl. 2003, WO 2003076451 CAN 139:261423
- 17. Knochel, P.; Lotz, M.; Monsees, A.; Riermeier, T.; Kadyrov, R.; Almena, J. “Preparation of phosphino ferrocenyl ligands as a cocatalyst for rhodium catalyzed asymmetric hydrogenation reactions” Ger. Offen. 2003, DE 10219490 CAN 139:365071.
- 18. Scholz, U.; Schlummer, B.; Knochel, P.; Bunlaksananusorn, T. „Preparation of chiral phosphine ligands and their transition metal complexes and their use as catalysts in asymmetric synthesis” PCT Int. Appl. 2004, WO 2004104014 CAN 142:23392.
- 19. A.; Riermeier, Monsees, T.; Almena, J.; Kadyrov, R.; Knochel, P.; Tappe, K.; Gommermann, N. “Improved process for preparation of inantiomerically-enriched ferrocenyl-based phosphine and diphosphine ligands by copper-catalized three-component coupling of ferrocenecarboxaldehydes, ?-alkynes and aminialcohols” Ger. Offen. 2005, DE 102004012438 CAN 143:326462
- 20. Knochel, P.; Krasovskiy, A. “Method of preparing organomagnesium compounds” Eur. Pat. Appl. 2005, EP 1582523 CAN 143:347288.
- 21. Knochel, P.; Bunlaksananusorn, T.; Gavryushin, A. “An improved process for preparation of chiral diphosphines with cyclopentane backbone as ligands for asymmetric transition metal-catalyzed hydroboration, hydrogenation and allylic substitution” Eur. Pat. Appl. 2005, EP 1595885 CAN 143:460277.
- 22. Knochel, P.; Bunlaksananusorn, T.; Gavryushin, A. “Chiral diphosphines with cyclic diterpene backbone as ligands for transition metal-catalyzed asymmetric hydrogenation, addition and substitution reactions and process for preparation thereof” Eur. Pat. Appl. 2005, EP 1595886 CAN 143:460278.
- 23. Knochel, P.; Bunlaksananusorn, T.; Gavryushin, A. “Chiral diphosphinoterpenes and transition metal complexes thereof” US Pat. Appl. Publ. 2005, US 2005267316 CAN 144:6923.
- 24. Knochel, P.; Sapountzis, I.; Korn, T.; Lin, W.; Kofink, C. „Iron- or cobalt-catalyzed carbon-carbon coupling reactions of arylenes, alkenes and alkynes with copper reagents“ Ger. Offen. 2006, DE 2004-102004049508 CAN 144:390561.
- 25. Knochel, P.; Gavriushin, Andrei; Manolikakes, G.; Kofink, C. C “Or iron-catalyzed carbon-carbon coupling reaction of arylenen, alkenes and alkines nickel” Ger. Offen. 2007, DE 102005043337 A1 20070315 AN 2007:284966.
- 26. Knochel, P.; Krasovskiy, A.; Kopp, F. ”Solutions of anhydrous lanthanide salts and its preparation.” Eur. Pat. Appl. 2007, EP 1759765 A1 20070307 AN 2007:247914.
- 27. Knochel, P.; Krasovskiy, A.; Krasovskaya, V. "Preparation and use of magnesium amides" PCT Int. Appl. 2007, WO 2007082911 A1 20070726 AN 2007:813869.
- 28. Knochel, P.; Gavryushin, A.; Malakhov, V.; Krasovskiy, A. “Improved process for preparation of organometallic compounds by direct metalation of organic derivs. with metals in presence of lithium salts” Ger. Offen. 2007, DE 102006015378 CAN 147:406953.
- 29. Knochel, P.; Mayr, H.; Krasovskiy, A.; Kienle, M.; Dubbaka, S. R.; Del Amo, V.; Tishkov, A. “Oxidative coupling of organometallic compounds using a quinone as redox reagent” PCT Int. Appl., 2007, WO 2007128601 A2 20071115 AN 2007:1303088.
- 30. Clososki, G. C.; Rohbogner, C. J.; Knochel, P. „Preparation and use of magnesium amides” PCT Int. Appl., 2008, WO 2008087057 A1 20080724 AN 2008:887903.
- 31. Knochel, P.; Wunderlich, S. „Bisamide-zinc bases“ PCT Int. Appl. 2008, WO 2008138946 A1 20081120 AN 2008:1402357.
- 32. Knochel, P.; Wunderlich, S. „Until amide zinc bases [Machine Translation]“ Ger. Offen. 2008, DE 102007022490 A1 20081120 AN 2008:1398637.
- 33. Knochel, P.; Wunderlich, S. „Process for preparation of diamidozinc bases as metalation reagents for aromatic and heterocyclic compounds” PCT Int. Appl. 2008, WO 2008138946 A1 20081120 CAN 149:569531 AN 2008:1402357.
- 34. Knochel, P.; Wunderlich, S. „Process for preparation of diamidozinc bases as metalation reagents for aromatic and heterocyclic compounds” Ger. Offen. 2008, DE 102007022490 A1 20081120 CAN 149:569530 AN 2008:1398637.
- 35. Knochel, Paul; Mosrin, M. “Preparation of zinc amides as selective bases for the directed zincation of aromatics and heteroaromatics” Ger. Offen. 2010, DE 102010007833 A1 20100819 CAN 153:334216 AN 2010:1040654.
- 36. Knochel, P.; Bluemke, T.; Chen, Yi-H. „Process for preparation of functionalized substituted biaryls and allylarenes by cross-coupling of aryl and allyl halides with arylaluminum compounds mediated by metal halides” PCT Int. Appl. 2011, WO 2011023791 A2 20110303; Ger. Offen. 2011, DE 102009028939 A1 20110303.
- 37. Langhals, H.; Knochel, P.; Walter, A.; Esterbeuer, A. J.; Zimdars, S. „Benzothiadiazoloperylene amorphous bichromophoric substances” Ger. Offen. 2011, DE 102009048848 A1 20110505.
- 38. Knochel, P.; Bernhardt, S.; Metzger, A. “Carboxylation of organozinc compounds in preparation of organic carboxylic acids” PCT Int. Appl. 2011, WO 2011113925 A2 20110922.
- 39. Knochel, P.; Bernhardt, S.; Manolokakes, G. “Organozinc complexes and processes for making and using the same” PCT Int. Appl. 2012, WO 2012085168 A1 20120628.
- 40. Knochel, P.; Haag, B. “Process for making organoboron compounds, products obtainable thereby, and their use” PCT Int. Appl. 2012, WO 2012085170 A2 20120628.
- 41. Knochel, P.; Haag, B. “Process for making organoboron compounds, products obtainable thereby, and their use” PCT Int. Appl. 2012, WO 2012085170 A2 20120628.
- 42. Langhals, H.; Knochel, P.; Schluecker, T.; Saemann, C.; Dhayalan, Vasudevan „Terminal substituted oligothiophenes and use thereof in optical signal transmission systems and/or as color pigments” PCT Int. Appl. 2015, WO 2015135867 A1 20150917.
- 43. Smits, H.; Knochel, P.; Klatt, T.; Becker, M. „Process for the preparation of halo-substituted benzenes” PCT Int. Appl. 2016, WO 2016058895 A1 2016042
- 44. Knochel, P.; Ellwart, M. „Organozinc reagents and processes for preparing and using the same” PCT Int. Appl. 2016, WO 2016146689 A1 2016092 Eur. Pat. Appl. 2016, EP 3070083 A1 20160921; PCT Int. Appl. 2016, WO 2016146689 A1 2016092
- 45. Knochel, P.; Becker, M. „Process for producing metalated aromatic and heteroaromatic compounds by deprotonation with lithium amides and transmetalation with metal salts in continuous flow conditions” PCT Int. Appl. 2016, WO 2016184652 A1 20161124.
- 46. Knochel, P.; Ellwart, M. „Organozinc reagents and processes for preparing and using the same” PCT Int. Appl. 2016, WO 2016146689 A1 20160922 (Eur. Pat. Appl. 2016, EP 3070083 A1 20160921).
- 47. Knochel, P.; Becker, M. “Preparation of organozinc composition” Eur. Pat. Appl. 2017, EP 3168224 A1 20170517.
- 48. Knochel, P.; Ziegler, D.; Simon, M. „Hydrocarbon-soluble halogen and thiolate/magnesium exchange reagents“ PCT Int. Appl. 2019, WO 2019063418 A1 20190404.
Books and Reviews
- 1. Knochel, P.*; Rozema, M. J.; Tucker, C.E.; Retherford, C.; Furlong, M.; AchyuthaRao, S. "The Chemistry of Polyfunctional Organozinc and Copper Reagents" Pure and Appl. Chem. 1992, 64, 361.
- 2. Knochel, P.* "Stereoselective Addition Reactions of Organozinc, Cadmium and Mercury Reagents" Ed. Trost, B. M. in Comprehensive Organic Synthesis, Vol.1, p. 211-230, Pergamon Press 1991.
- 3. Knochel, P.* "Carbometallation of Alkenes and Alkynes" Ed. Trost, B. M. in Comprehensive Organic Synthesis, Vol.4, p. 865-912, Pergamon Press 1991.
- 4. Knochel, P.*; Rozema, M. J.; Tucker, C.E.; "Preparation of Highly Functionalized Copper Reagents" in "Practical Approach Series in Chemistry-Organocopper Reagents" Taylor, R. J. K., Oxford University Press, 1993, 348.
- 5. Knochel, P.*; Singer, R. D. "Preparation and Reactions of Polyfunctional Organozinc Reagents for Organic Synthesis" Chem. Rev. 1993, 93, 2117-2188.
- 6. Knochel, P.* "Organozinc and Organocadmium Reagents in Organic Synthesis" Ed. Hegedus, L. S. in Comprehensive Organometallic Chemistry II, Vol.11, p. 159-190, Pergamon Press 1995.
- 7. Knochel, P.* "Universitätssausbildung am Forschungsstandort USA" Chemie Heute 1994/95, 32-34.
- 8. Knochel, P.* "Allyltrimethylsilylzinc Chloride" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 1, p. 136-137.
- 9. Knochel, P.* "Diethylzinc" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 3, p. 1861-1866.
- 10. Knochel, P.* "Diethylzinc-Bromoform-Oxygen" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 3, p. 1867.
- 11. Knochel, P.* "Ethyliodomethylzinc Iodide" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 4, p. 2473.
- 12. Knochel, P.* "Ethylzinc Iodide" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 4, p. 2532-2533.
- 13. Knochel, P.* "Iodomethylzinc Iodide" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 4, p. 2835-2836.
- 14. Knochel, P.* "Lithium Tri-t-butylzincate" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 5, p. 3176-3177.
- 15. Knochel, P.* "Lithium Trimethylzincate" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 5, p. 3185-3186.
- 16. Knochel, P.* "2-Nitro-3-Pivaloyloxy-1-Propene" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 6, p. 3756-3757.
- 17. Knochel, P.* "Phenylzinc Chloride" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 6, p. 4106-4107
- 18. Knochel, P.* "Titanocenemethylene-Zinc Halide Complex" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 7, p. 4106-4107.
- 19. Knochel, P.* "Zinc" Encyclopedia of Reagents for Organic Synthesis, Ed. Paquette, L. A. wiley and Sons, 1995, Vol. 8, p. 5525-5531.
- 20. Knochel, P.* and Jones, P. "Organozinc Reagents: A Practical Approach" (Ed.), 1999, Oxford Press
- 21. Knochel, P.* "Preparation and Applications of Functionalized Organozinc Reagents" Chapter in "Activated Metals" Ed. Fürstner A. Verlag Chemie, 1995, 191-236.
- 22. Knochel, P.*; Vettel, S.; Eisenberg, C. "Catalytic Asymmetric Synthesis of Chiral Secondary Polyfunctional Alcohols Using Diorganozincs" Applied Organomet. Chem. 1995, 9, 175-188.
- 23. Knochel, P.* "Stereoselective Reactions Mediated by Functionalized Diorganozincs" Synlett 1995, 393-403.
- 24. Knochel, P.* "New Preparations of Polyfunctional Dialkylzincs and Their Application in Asymmetric Synthesis" Organic Chemistry Edition of CHEMTRACTS in Org. Chem. 1995, 8, 205-221.
- 25. Knochel, P.* "Carbon-Carbon Bond Formation Mediated by Organozinc Reagents" in "Metal-Catalyzed Cross Coupling Reactions" edited by Stang, P. and Diederich, F., VCH Verlag, Weinheim, 1997, 387-419.
- 26. Knochel, P.* "The Preparation of 1,1-Bimetallics of Magnesium and Zinc" in "Handbook of Grignard Reagents" edited by Silverman, G. S. and Rakita, P. E., Marcel Dekker, Inc., New-York, Basel, Hong Kong, 1996, 633-644.
- 27. Knochel, P.*, Langer, F.; Longeau, A.; Rottländer, M.; Stüdemann, T. "New Coupling Reactions and Phosphorylations Using Organzinc Reagents" Chem. Ber. 1997, 130, 1021-1027.
- 28. Knochel, P.*; Almena, J.; Jones, P. "Organozinc Mediated Reactions" Tetrahedron 1998, 54, 8275-8319.
- 29. Knochel, P.* "New Preparations and Reactions of Organozinc Reagents" in Selective Reactions of Metal-Activated Molecules, third Symposium, Werner, H.; Schrein, P. Eds. Vieweg Verlag, 1998, 117-130.
- 30. Rottländer, M.; Boymond, L.; Bérillon, L.; Leprêtre, A.; Varchi, G.; Avolio, S.; Laaziri, H.; Quéguiner, G.; Ricci, A.; Cahiez, G.; Knochel, P.* "New Polyfunctional Magnesium Reagents for Organic Synthesis" Chem. Eur. J. 2000, 6, 767.
- 31. Betzemeier, B.; Knochel, P.* "Perfluorinated Solvents - a Novel Reaction Medium in Organic Chemistry" in Topics of Current Chemistry: New Solvent Systems, Springer Verlag 1999.
- 32. Negishi, E., Knochel, P.* "Palladium Catalyzed Carbozincation" Pd- Handbook 2000
- 33. Boudier, A.; Bromm, L.O.; Lotz, M.; Knochel, P.* "New Applications of Polyfunctional Organometallics in Organic Synthesis" Angew. Chem. Int. Ed. 2000, 39, 4414-4435.
- 34. Knochel; P.*; Boudier, A.; Bromm, L. O.; Hupe, E.; Knapp, K.; Varela, J.; Laaziri; H.; Lhermitte, F. "New Stereoselective Transformations Involving Organoboranes and Organozinc Compounds" Pure Appl. Chem. 2001, Vol. 72, No. 9, 1699-1703.
- 35. Betzemeier, B.; Knochel, P.* "Oxidation Reactions in Perfluorinated Solvents" Peroxide Chemistry, Wiley-VCH 2000, 8, 453-468.
- 36. Knochel, P.*; Millot, N.; Rodriguez, A.; Tucker, C. E.; "Preparations and Applications of Functionalized Organozinc Compounds" Organic Reactions 2001, 58, 417-731.
- 37. Knochel, P.*; Boudier, A.; Bromm, L. O.; Hupe, E.; Knapp, K.; Varela Carrete, J.; Rodriguez, A.; Koradin, C.; Bunlaksananusorn, T.; Laaziri, H.; Lhermitte, F. "Selective Transformations Mediated by Main Group Organometallics" Pure Appl. Chem. 2000, 72, 1699-1703.
- 38. Knochel, P.* "Organozinc Reagents" Science of Synthesis 2004, 3, 5-90.
- 39. Knochel, P.*; Betzemeier, B. "Transmetalation Reactions Leading to Organocopper Reagents" VCH Verlag, 2002, 45-78.
- 40. Knochel, P.*; Lotz, M. "Catalysts for the Fine Chemical Industry" Wiley VCH, 2000, in press.
- 41. Knochel, P.*; Hupe, E.; Houte, H. "Les composes organozinciques et organomagnesiens polyfonctionnels : De nouveaux reactifs pour la synthese de molecules organiques complexes" L’Actualite Chimique 2003, avril-mai, 12-16
- 42. Knochel,P.*, Dohle, W.; Gommermann, N.; Kneisel, F. F.; Kopp, F.; Korn, T. Sapountzis, I.; Vu, V.A. "Highly Functionalized Magnesium Organometallics Prepared via a Halogen-Magnesium Exchange" Angew. Chem. Int. Ed. 2003, 42, 4302-4320.
- 43. Hupe, E.; Calaza, M. I.; Knochel, P.* "Synthesis and Reaction of Secondary and Primary Diorganoznc Reagents Using a Boron-Zinc Exchange. A Useful Method for the Stereoselective Formation of New Carbon-Carbon Bonds" J. Organomet. Chem. 2003, 680, 136-142.
- 44. Knochel, P.*; Sapountzis, I.; Gommermann, N. "Carbon-carbon bond-forming reactions mediated by organomagnesium reagents" in Metal-Catalyzed Cross-Coupling Reactions (2nd Edition) 2004, 2 , 671-698.
- 45. Knochel, P.; Calaza, M. I.; Hupe, E. "Carbon-Carbon Bond-Forming Reactions Mediated by Organozinc Reagents" in Metal-Catalyzed Cross-Coupling Reactions< (2nd Edition) 2004, 2, 619-670.
- 46. Knochel, P.*; Krasovskiy, A.; Sapountzis, I. "Polyfunctional Magnesium Organometalics for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 4.
- 47. Knochel, P.*; Leuser, H.; Gong, L.-Z.; Perrone, S.; Kneisel, F. F. "Polyfunctional Zinc Organometalics for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 7.
- 48. Knochel, P.*; Yang, X.; Gommermann, N. "Polyfunctional Organocopper Reagents for Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 9.
- 49. Knochel, P.*; Ila, H.; Korn, T.; Baron, O. "Functionalized Organoborane Derivatives in Organic Synthesis" in Handbook of Functionalized Organometallics, Knochel, P. (Ed.), Wiley-VCH 2005, Chapter 3.
- 50. Ila, H.; Baron, O.; Wagner, A. J.; Knochel, P. "Preparation and Reactions of Heteroaryl Organomagnesium Compounds" Chem. Commun. 2005, in press.
- 51. Ila, H.; Baron, O.; Wagner, A. J.; Knochel, P. "Functionalized Magnesium Organometallics as Versatile Intermediates for the Synthesis of Polyfunctional Heterocycles" Chem. Commun. 2005, in press.
- 52. Knochel, P.*; Leuser, H.; Gong, L.-Z.; Perrone, S.; Kneisel, F. F. "Functionalized organozinc compounds" in The chemistry of organozinc compounds, Rappoport, Z. (Ed.); Marek, I. (Ed.), John Wiley & Sons, Ltd 2006, in press.